Hot-dip galvanized steel sheet and hot-dip galvannealed steel sheet with excellent aging resistance properties and bake hardenability, and method for manufacturing same
Provided are a hot-dip galvanized steel sheet and a hot-dip galvannealed steel sheet with excellent aging-resistance properties and bake hardenability, and a method for manufacturing the same. The hot-dip galvanized steel sheet has a molten zinc plated layer on the surface of a base steel sheet, wherein the base steel sheet comprises: 0.002-0.012 wt % of carbon (C); 1.6-2.7 wt % of manganese (Mn); 0.03 wt % or less (excluding 0 wt %) of phosphorus (P); 0.01 wt % or less (excluding 0 wt %) of sulfur (S); 0.01 wt % or less (excluding 0 wt %) of nitrogen (N); 0.02-0.06 wt % of aluminum (sol.Al); 1.0 wt % or less (excluding 0 wt %) of chromium (Cr), with the remainder being iron and inevitable impurities; the base steel sheet satisfies the relation of 1.3≤Mn(wt %)/(1.15×Cr(wt %))≤20.5; Mneq defined by relational expression 1 satisfies 1.9≤Mneq≤3.9.
1. A hot-dip galvanized steel sheet having improved aging-resistance and bake hardenability, the steel sheet comprising:
a base steel sheet; and
a galvanized layer formed on the base steel sheet,
wherein the base steel sheet comprises:
by wt %, 0.002-0.012% of carbon (C);
1.6-2.7% of manganese (Mn);
0.03% or less (excluding 0%) of phosphorus (P);
0.01% or less (excluding 0%) of sulfur (S);
0.01% or less (excluding 0%) of nitrogen (N);
0.02-0.06% of aluminum (sol.Al);
1.0% or less (excluding 0%) of chromium (Cr), with a remainder of iron and inevitable impurities;
wherein the base steel sheet satisfies a relationship of 1.3≤Mn(wt %)/(1.15× Cr(wt %))≤20.5;
wherein the base steel sheet satisfies 1.9≤Mneq≤3.9, the Mneq being defined by the following Relational Expression 1:
Mn eq =Mn+2P+1.15Cr; [Relational Expression 1]
wherein the base steel sheet comprises a microstructure having an area ratio of 95% or more of a ferrite phase and a remainder of a martensite phase;
wherein the martensite phase satisfies the following Relational Expression 2:
P (%)={ Pgb /( Pg+Pgb )}×100≥90%, [Relational Expression 2]
where P(%) is an occupation ratio of martensite present in a ferrite grain boundary, Pgb is an occupation area of martensite present in the ferrite grain boundary, and Pg is an occupation area of martensite present within a ferrite grain; and
wherein the base steel sheet satisfies the following Relational Expression 3:
a−b≥ 0.3 wt %, [Relational Expression 3]
where a is an average Mn concentration (wt %) in the martensite phase at a ¼ thickness point of the base steel sheet, and b is an average Mn concentration (wt %) in a ferrite phase within 1 μm around the martensite phase at the ¼ thickness point of the base steel sheet.
2. The hot-dip galvanized steel sheet of claim 1 , wherein the base steel sheet further comprises: at least one of 0.003% or less (excluding 0%) of boron (B) and 0.2% or less (excluding 0%) of molybdenum (Mo).
3. The hot-dip galvanized steel sheet of claim 1 , wherein the martensite phase includes a fine martensite phase having an average diameter of 1 μm or less, the fine martensite phase having an area % of 2% or less (excluding 0%).
4. The hot-dip galvanized steel sheet of claim 1 , wherein the galvanized layer includes an alloying treated galvanized layer.
5. The hot-dip galvanized steel sheet of claim 1 , wherein the base steel sheet comprises: by wt %, 0.004-0.01% of carbon (C).
6. The hot-dip galvanized steel sheet of claim 1 , wherein the base steel sheet comprises: by wt %, 2.0-2.4% of manganese (Mn).