Battery cell in which gelation electrolyte solution component is included in pore of separator configuring electrode assembly
View Patent ↗The present invention provides a battery cell including: an electrode assembly having a structure in which a separator is interposed between a cathode and an anode, wherein the separator is formed with a plurality of pores and the pores include a gelation electrolyte solution component.
1. A battery cell, comprising:
a battery case in which an electrode assembly and a liquefied electrolyte solution are sealed and wherein the electrode assembly is impregnated in the liquefied electrolyte solution,
wherein the electrode assembly has a structure in which a separator is in direct physical contact with a cathode and an anode, wherein the separator has a plurality of pores and the pores include a gelation electrolyte solution component.
2. The battery cell of claim 1 , wherein:
the pores formed in the separator have an average diameter of 0.01 μm to 100 μm.
3. The battery cell of claim 1 , wherein:
the separator has porosity of 40% to 90%.
4. The battery cell of claim 1 , wherein:
the gelation electrolyte solution component is formed by polymerizing or curing after the separator is impregnated in a mixed liquid including a liquefied electrolyte solution component in a liquefied monomer and/or oligomer state and an polymerization initiator so that the mixed liquid is inserted into the pores of the separator.
5. The battery cell of claim 4 , wherein:
the liquefied electrolyte solution component in the liquefied monomer and/or oligomer state is at least any one selected from the group consisting of a polyethylene derivative, a polyethylene oxide derivative, a polypropylene oxide derivative, a phosphate ester polymer, a poly agitation lysine, a polyester sulfide, a polyvinyl alcohol, a polyvinylidene fluoride, and a polymer including an ionic dissociation group.
6. The battery cell of claim 4 , wherein:
the liquefied electrolyte solution component includes at least any one selected from the group consisting of nitride, halide, and sulfate of Li.
7. The battery cell of claim 4 , wherein:
the polymerization initiator gelates the liquefied electrolyte solution component in the liquefied monomer and/or oligomer state by heat or light applied from the outside.
8. The battery cell of claim 4 , wherein:
the liquefied electrolyte solution component inserted into the pores of the separator is polymerized or cured for 1 hour to 20 hours in a temperature range of 40° C. to 90° C.
9. The battery cell of claim 4 , wherein:
the polymerization initiator includes at least any one selected from the group consisting of benzoyl peroxide (BPO), acetyl peroxide, dilauryl peroxide, di-tertbutylperoxide, cumyl hydroperoxide, hydrogen peroxide, 2,2-azobis (2-cyanobutane), 2,2-azobis (methylbutyronitrile), azobis (isobutyronitrile) (AIBN), and azobisdimethyl-valeronitrile (AMVN).
10. The battery cell of claim 4 , wherein:
a content of the polymerization initiator is 0.01 wt % to 5 wt % with respect to the liquefied electrolyte solution component in the liquefied monomer and/or oligomer state.
11. The battery cell of claim 1 , wherein:
the liquefied electrolyte solution includes at least any one selected from the group consisting of N-methyl-2-pyrrolidinone, propylene carbonate, ethylene carbonate, butylene carbonate, dimethyl carbonate, diethyl carbonate, gamma-butylolactone, 1,2-dimethoxyethane, tetrahydroxy franc, 2-methyltetrahydrofuran, dimethylsulfoxide, 1,3-dioxolane, formamide, dimethylformamide, dioxolane, acetonitrile, nitromethane, methyl formate, methyl acetate, triester phosphate, trimethoxymethane, dioxolane derivatives, sulfolane, methyl sulfolane, 1,3-dimethyl-2-imidazolidinone, propylene carbonate derivatives, tetrahydrofuran derivatives, ether, methyl pyrophosphate, and ethyl propionate.
12. The battery cell of claim 1 , wherein:
the battery cell is a lithium secondary battery.
13. A method for manufacturing the battery cell of claim 1 , comprising:
a) manufacturing an electrode assembly by interposing a separator between a cathode and an anode;
b) impregnating the electrode assembly manufactured in the step a) into a mixed liquid including an liquefied electrolyte solution component in the liquefied monomer and/or oligomer state and an polymerization initiator;
c) impregnating the electrode assembly in a battery case along with a liquefied electrolyte solution and then sealing the battery case; and
d) polymerizing or curing the liquefied electrolyte solution component in the monomer and/or oligomer state inserted into a pore of the separator.
14. The method of claim 13 , wherein:
the liquefied electrolyte solution component in the monomer and/or oligomer state inserted into the pores of the separator in step d) is polymerized or cured for 1 to 20 hours in the temperature range of 40° C. to 90° C.
15. A battery pack comprising the battery cell of claim 1 .
16. A device comprising the battery pack of claim 15 as a power supply.
17. The device of claim 16 , wherein:
the device a mobile phone, a tablet computer, a laptop computer, a power tool, a wearable electronic device, an electric vehicle, a hybrid electric vehicle, a plug-in hybrid electric vehicle, or a power storage device.
18. The battery cell of claim 4 , wherein:
the liquefied electrolyte solution component includes at least any one selected from the group consisting Li 3 N, LiI, Li 5 NI 2 , Li 3 N—LiI—LiOH, LiSiO 4 , LiSiO 4 —LiI—LiOH, Li 2 SiS 3 , Li 4 SiO 4 , Li 4 SiO 4 —LiI—LiOH, and Li 3 PO 4 —Li 2 S—SiS 2 .
19. The battery cell of claim 1 , wherein the plurality of pores include pores having an average diameter of greater than 10 μm to 100 μm.
20. The battery cell of claim 1 , wherein the gelation electrolyte solution component is entirely in the separator.