Method for producing paper
A method of producing paper and board by using at least one water-soluble amphoteric polymer is provided. The water-soluble amphoteric polymer is obtained by copolymerizing a monomer mixture containing a) at least one N-vinylcarboxamide, b) at least one monoethylenically unsaturated monomer having at least one free acid group or at least one acid group in salt form, c) optionally at least one monoethylenically unsaturated monomer other than components (a) and (b), and d) optionally at least one compound having two or more ethylenically unsaturated double bonds, and then partly or wholly hydrolyzing the —CO—R 1 groups of the polymer. The cationic monomer units and the anionic monomer units differ in their respective molar fractions, each based on the total number of moles of all monomer units, by not more than 10 mol % in absolute terms.
1. A method of producing paper and board, said method comprising
providing an aqueous slurry comprising a filler, at least one water-soluble amphoteric polymer and a microparticle,
admixing the aqueous slurry to a paper stock,
dewatering the paper stock by sheet formation in a wire section to obtain a paper sheet, until the paper sheet has a dry matter content of not less than 18 wt %,
and then pressing the paper sheet and drying,
wherein the water-soluble amphoteric polymer is obtained by a process comprising
copolymerizing a monomer mixture comprising
a) at least one N-vinylcarboxamide of formula
where R 1 and R 2 are each independently H or a C 1 to C 6 alkyl,
b) at least one monoethylenically unsaturated monomer having at least one free acid group or at least one acid group in salt form,
c) optionally at least one monoethylenically unsaturated monomer other than said components (a) and (b), and
d) optionally at least one compound having two or more ethylenically unsaturated double bonds,
and then partly or wholly hydrolyzing the —CO—R 1 groups of the polymer,
wherein cationic monomer units and anionic monomer units differ in respective molar fractions, each based on a total number of moles of all monomer units, by not more than 10 Mol % in absolute terms;
wherein the filler is calcium carbonate; and
wherein the microparticle is chosen from:
a copolymer formed from acrylamide and one or more anionic monomers; and/or
inorganic microparticles of bentonite, colloidal silica, and/or silicate.
2. The method according to claim 1 , wherein the monomer mixture consists of: based on a total weight of monomers in the monomer mixture,
a) 5 to 95 wt %, of least one N-vinylcarboxamide
b) 5 to 95 wt %, of the at least one monoethylenically unsaturated monomer having at least one free acid group or at least one acid group in salt form,
c) 0 to 90 wt % of the at least one monoethylenically unsaturated monomer other than said components (a) and (b), and
d) 0 to 5 wt % of the at least one compound having two or more ethylenically unsaturated double bonds.
3. The method according to claim 1 , wherein the water-soluble amphoteric polymer is obtained by copolymerizing
a) N-vinylformamide,
b) at least one monoethylenically unsaturated monomer selected from the group consisting of acrylic acid, methacrylic acid, an alkali metal salt of acrylic acid and/or methacrylic acid and an ammonium salt of acrylic acid and/or methacrylic acid, and
c) optionally other monoethylenically unsaturated monomers.
4. The method according to claim 1 , wherein the water-soluble amphoteric polymer comprises
(i) 1 to 98 mol % of vinylcarboxamide units,
(ii) (ii) 1 to 98 mol % of units of monoethylenically unsaturated sulfonic acids, phosphonic acids, phosphoric esters, derivatives thereof or units of monoethylenically unsaturated mono- and dicarboxylic acids, thereof and dicarboxylic anhydrides,
(iii) 1 to 98 mol % of vinylamine units and/or amidine units, and
(iv) (iv) up to 50 mol % of units of other monoethylenically unsaturated compounds.
5. The method according to claim 1 , wherein the water-soluble amphoteric polymer comprises
(i) 5 to 70 mol % of vinylcarboxamide units,
(ii) 5 to 45 mol % of units of acrylic acid, methacrylic acid, a salt of acrylic acid and/or a salt of methacrylic acid, and
(iii) 10 to 60 mol % of units form vinylamine units and optionally amidine units.
6. The method according to claim 1 , wherein a proportion of the microparticles in the aqueous slurry is 0.01-1 wt % based on the filler.
7. The method according to claim 1 , wherein a proportion of the water-soluble amphoteric polymer is 0.01-1 wt %, based on the filler.
8. The method according to claim 1 , wherein the aqueous slurry comprises water, 5-70 wt % of the filler based on the aqueous slurry, 0.001-1 wt % of the water-soluble amphoteric polymer based on the filler, and 0.01-1 wt % of the microparticles based on the filler.
9. The method according to claim 1 , wherein the sheet formation in the wire section is carried on until the paper sheet has a dry matter content of not less than 19 wt %.