Titanium composite material and titanium material for hot rolling
A titanium composite material 1 is provided that includes: an inner layer 5 consisting of a commercially pure titanium or a titanium alloy; an outer layer 3 formed on at least one surface of the inner layer 5 and having a chemical composition that is different from a chemical composition of the inner layer 5 ; and an intermediate layer formed between the inner layer 5 and the outer layer 3 and having a chemical composition that is different from the chemical composition of the inner layer 5 . The thickness of the outer layer 3 is 2 μm or more, and occupies no more than 40% of the overall thickness per side. The thickness of the intermediate layer is 0.5 μm or more. Despite being inexpensive, this titanium composite material has desired characteristics.
1. A titanium composite material, comprising:
an inner layer comprising a commercially pure titanium or a titanium alloy;
an outer layer formed on at least one rolling surface of the inner layer, the outer layer having a chemical composition that is different from a chemical composition of the inner layer; and
an intermediate layer formed between the inner layer and the outer layer, the intermediate layer having a chemical composition that is different from the chemical composition of the inner layer, the intermediate layer satisfying the following formula;
wherein:
the outer layer has a thickness of 2 μm or more, and a proportion of the outer layer with respect to the overall thickness is no more than 40% per side; and
a thickness of the intermediate layer is 0.5 μm or more;
0<C MID≤ 0.8×C AVE , wherein for the above formula, C MID means an amount of increased content from the inner layer, C AVE means an average of the increased content in the outer layer, and the amount of increased content means: in the case of an element that is not contained in the inner layer, the content thereof, and in the case of an element that is contained in the inner layer, the amount of increase in the content thereof from the inner layer.
2. The titanium composite material according to claim 1 , wherein a chemical composition of the outer layer is, by mass %:
platinum group elements: 0.01 to 0.25%,
rare earth element: 0 to 0.2%,
Co: 0 to 0.8%,
Ni: 0 to 0.6%, and
a balance: titanium and impurities.
3. The titanium composite material according to claim 2 , wherein:
the platinum group elements are Pd and/or Ru.
4. The titanium composite material according to claim 2 , wherein the chemical composition contains, by mass %:
rare earth element: 0.001 to 0.2%.
5. The titanium composite material according to claim 2 , wherein the chemical composition contains, by mass %:
Co: 0.05 to 0.8%, and/or
Ni: 0.05 to 0.6%.
6. The titanium composite material according to claim 2 , wherein a chemical composition of the commercially pure titanium is, by mass %:
C: 0.1% or less,
H: 0.015% or less,
O: 0.4% or less,
N: 0.07% or less,
Fe: 0.5% or less, and
a balance: Ti and impurities.
7. The titanium composite material according to claim 2 , wherein:
another outer layer is formed on a face other than a rolling surface of the inner layer, and
the other outer layer has a same chemical composition as the outer layer.
8. The titanium composite material according to claim 3 , wherein a chemical composition of the commercially pure titanium is, by mass %:
C: 0.1% or less,
H: 0.015% or less,
O: 0.4% or less,
N: 0.07% or less,
Fe: 0.5% or less, and
a balance: Ti and impurities.
9. The titanium composite material according to claim 4 , wherein a chemical composition of the commercially pure titanium is, by mass %:
C: 0.1% or less,
H: 0.015% or less,
O: 0.4% or less,
N: 0.07% or less,
Fe: 0.5% or less, and
a balance: Ti and impurities.
10. The titanium composite material according to claim 5 , wherein a chemical composition of the commercially pure titanium is, by mass %:
C: 0.1% or less,
H: 0.015% or less,
O: 0.4% or less,
N: 0.07% or less,
Fe: 0.5% or less, and
a balance: Ti and impurities.