Stainless steel for fuel cell separator plate and manufacturing method therefor
Stainless steel for a fuel cell separator plate and a manufacturing method therefor are disclosed. The stainless steel for a fuel cell separator plate, according to one embodiment of the present invention, comprises: a stainless base material; and a passive film formed on the stainless base material, wherein a Cr/Fe atomic weight ratio in a 1 nm or less thickness region of the stainless base material, which is adjacent to an interface between the stainless and the passive film, is 0.45 or more. Therefore, by modifying the surface of the stainless steel for a fuel cell separator plate, a low interface contact resistance and a good corrosion resistance can be obtained, and a separate additional process such as precious metal coating can be removed, such that manufacturing costs are reduced and productivity can be improved.
1. A stainless steel for a fuel cell separator plate comprising:
a stainless base material and
a passive film formed on the stainless base material, wherein a content of Si atoms in the passive film is less than or equal to 0.1 at %, a Cr/Fe atomic weight ratio in the passive film is greater than or equal to 1.0, the passive film has an interfacial contact resistance of 10 mΩcm.sup 2 (100 N/cm 2 ) or less, and the passive film has a corrosion potential of 0.3 V SCE or more,
wherein the Cr/Fe atomic weight ratio at an interface between the stainless steel base material and the passive film is greater than or equal to 0.65,
wherein the interface between the stainless base material and the passive film refers to a point in the stainless steel at which a content of oxygen accounted for 50% with respect to a maximum content of oxygen as determined in an elemental distribution measured in a thickness direction of the stainless steel, and
wherein the stainless base material at a region starting from 0.5 nm from the interface between the stainless base material and the passive film to 1 nm from the interface between the stainless base material and the passive film after film modification has a Cr/Fe atomic weight ratio of 0.45 or more.
2. The stainless steel for a fuel cell separator plate of claim 1 , wherein the stainless steel for a fuel cell separator plate comprises C at greater than 0 to 0.02 wt %, N at greater than 0 to 0.02 wt %, Si at greater than 0 to 0.4 wt %, Mn at greater than 0 to 0.2 wt %, P at greater than 0 to 0.04 wt %, S at greater than 0 to 0.02 wt %, Cr at 25 to 34 wt %, Mo at 0 to less than 0.1 wt %, Cu at 0 to 1 wt %, Ni at 0 to less than 0.2 wt %, Ti at greater than 0 to 0.5 wt %, Nb at greater than 0 to 0.5 wt %, and the balance of Fe and other inevitable impurities.
3. The stainless steel for a fuel cell separator plate of claim 1 , wherein the passive film has a thickness of 3.5 nm or less (excluding 0).
4. A stainless steel for a fuel cell separator plate comprising:
a stainless base material and
a passive film formed on the stainless base material, wherein a content of Si atoms in the passive film is less than or equal to 0.1 at %, a Cr/Fe atomic weight ratio in the passive film is greater than or equal to 1.0, and the passive film has a corrosion potential of 0.3 V SCE or more,
wherein the Cr/Fe atomic weight ratio at an interface between the stainless steel base material and the passive film is greater than or equal to 0.65,
wherein the stainless base material at a region starting from 0.5 nm from the interface between the stainless base material and the passive film to 1 nm from the interface between the stainless base material and the passive film after film modification has the Cr/Fe atomic weight ratio of 0 . 45 or more, and
wherein the interface between the passive film and the stainless base material refers to a point in the stainless base material at which a content of oxygen accounted for 50% with respect to a maximum content of oxygen as determined in an elemental distribution measured in a thickness direction of the stainless steel, and
wherein the stainless steel for the fuel cell separator plate comprises C at greater than 0 to 0.02 wt %, N at greater than 0 to 0.02 wt %, Si at greater than 0 to 0.4 wt %, Mn at greater than 0 to 0.2 wt %, P at greater than 0 to 0.04 wt %, S at greater than 0 to 0.02 wt %, Cr at 25 to 34 wt %, Mo at 0 to less than 0.1 wt %, Cu at 0 to 1 wt %, Ni at 0 to less than 0.2 wt %, Ti at greater than 0 to 0.5 wt %, Nb at greater than 0 to 0.5 wt %, and the balance of Fe and other inevitable impurities.