IP Library Granted Patent US 11,485,067
Granted Patent B2
US 11,485,067 · App. 15/748,082 · Granted Nov 1, 2022

Resin composition for modeling material, resin composition for supporting material, photofabrication product, and process for producing photofabrication product

Inventors: Katsuyuki Kitou (Osaka, JP); Taeko Izumo (Osaka, JP)
Assignees: MAXELL, LTD.; MIMAKI ENGINEERING CO., LTD.
B29C64/112B29C64/245B29C64/264B29C64/268B29C67/00B33Y70/00C08F290/06C08L33/08C08L33/10C08L33/24C08L71/02C08L75/06B33Y10/00B33Y80/00C08L2205/03
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Quick Facts
Patent No.
US 11,485,067
App. No.
15/748,082
Granted
Nov 1, 2022
Kind
B2
Abstract

A resin composition for a modeling material for use in shaping a modeling material ( 4 ) by an ink-jet photofabrication method, the resin composition comprising, based on 100 parts by weight of the whole resin composition, 19 to 49 parts by weight of a water-insoluble monofunctional ethylenically unsaturated monomer (A), 15 to 50 parts by weight of a di- or more-functional polyfunctional ethylenically unsaturated monomer (B), 10 to 45 parts by weight of an oligomer (C), and a photopolymerization initiator (D). By this resin composition for a modeling material, a photofabrication product having good dimensional accuracy can be obtained.

Claims (22)

1. A resin composition for a modeling material for use in shaping a modeling material by an ink-jet photofabrication method, the resin composition comprising, based on 100 parts by weight of the whole resin composition:

19 to 49 parts by weight of a water-insoluble monofunctional ethylenically unsaturated monomer (A), wherein the water-insoluble monofunctional ethylenically unsaturated monomer (A) comprises isobornyl (meth)acrylate;

15 to 50 parts by weight of a di- or more-functional polyfunctional ethylenically unsaturated monomer (B);

10 to 45 parts by weight of an oligomer (C), wherein the oligomer (C) is one or more selected from the group consisting of a urethane (meth)acrylate oligomer, an epoxy (meth)acrylate oligomer, and a polyester (meth)acrylate oligomer; and

5 to 15 parts by weight of a photopolymerization initiator (D).

2. The resin composition for a modeling material according to claim 1 , wherein the content of the (A) ingredient is 25 to 47 parts by weight, based on 100 parts by weight of the whole resin composition.

3. The resin composition for a modeling material according to claim 1 , wherein the content of the (B) ingredient is 20 to 45 parts by weight, based on 100 parts by weight of the whole resin composition.

4. The resin composition for a modeling material according to claim 1 , wherein the content of the (C) ingredient is 15 to 30 parts by weight, based on 100 parts by weight of the whole resin composition.

5. The resin composition for a modeling material according to claim 1 , wherein the resin composition further comprises a preservation stabilizer (F) at 0.05 to 3.0 parts by weight, based on 100 parts by weight of the whole resin composition.

6. A resin composition for a supporting material for use in shaping a supporting material by an ink-jet photofabrication method, the resin composition comprising, based on 100 parts by weight of the whole resin composition:

20 to 50 parts by weight of a water-soluble monofunctional ethylenically unsaturated monomer (G);

20 to 49 parts by weight of polyalkylene glycol (H) comprising an oxyethylene group and/or an oxypropylene group;

35 parts by weight or less of a water-soluble organic solvent (I); and

a photopolymerization initiator (D).

7. The resin composition for a supporting material according to claim 6 , wherein the content of the (G) ingredient is 25 to 45 parts by weight, based on 100 parts by weight of the whole resin composition.

8. The resin composition for a supporting material according to claim 6 , wherein the content of the (H) ingredient is 25 to 45 parts by weight, based on 100 parts by weight of the whole resin composition.

9. The resin composition for a supporting material according to claim 6 , wherein the content of the (D) ingredient is 5 to 20 parts by weight, based on 100 parts by weight of the whole resin composition.

10. The resin composition for a supporting material according to claim 6 , wherein the content of the (I) ingredient is 5 parts by weight or more, based on 100 parts by weight of the whole resin composition.

11. The resin composition for a supporting material according to claim 6 , wherein the resin composition further comprises a preservation stabilizer (F) at 0.05 to 3.0 parts by weight, based on 100 parts by weight of the whole resin composition.

12. A photofabrication product comprising a modeling material which is obtained by photocuring a resin composition for a modeling material according to claim 1 , by an ink-jet photofabrication method.

13. The resin composition for a modeling material according to claim 1 , wherein the resin composition has a viscosity of 70 mPa·s or less at 25° C.

14. The resin composition for a modeling material according to claim 1 , wherein the content of the (C) ingredient is 10 to 30 parts by weight, based on 100 parts by weight of the whole resin composition.

Assignments (2)
CHANGE OF NAME Recorded Dec 3, 2021
From: MAXELL HOLDINGS, LTD.
To: MAXELL, LTD.
Reel/Frame 058301/0318 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 26, 2018
From: KITOU, KATSUYUKI; IZUMO, TAEKO
To: MAXELL HOLDINGS, LTD.; MIMAKI ENGINEERING CO., LTD.
Reel/Frame 044743/0531 →
Priority Claims (1)
JP JP2015-149753 · Jul 29, 2015 · national
Continuity (1)
Related Publication 20190009453A1 · Jan 10, 2019