Galvannealed steel sheet and production method thereof
Provided is a galvannealed steel sheet having high strength and excellent deep drawability, and being further excellent in slab cracking resistance and secondary working embrittlement resistance. A base metal steel sheet of the galvannealed steel sheet has a chemical composition containing, in mass %: C: 0.0080% or less; Si: 0.7% or less; Mn: 1.0 to 2.5%; P: more than 0.030 to 0.048%; S: 0.025% or less; Al: 0.005 to 0.20%; N: 0.010% or less; Ti: 0.005 to 0.040%; Nb: 0.005 to 0.060%; and B: 0.0005 to 0.0030%, with the balance being Fe and impurities, satisfying Formula (1) to (4). A galvannealed layer contains 7 to 15 mass % of Fe. 25×P+4×Si≤3.6 (1) B−X1≥0.0005 (2) C−(12/93)×Nb−X2≥−0.0035 (3) 110×Si+48×Mn+550×P≥120 (4)
1. A galvannealed steel sheet comprising:
a base metal steel sheet having a chemical composition containing, in mass %:
C: 0.0080% or less;
Si: 0.7% or less;
Mn: 1.0 to 2.5%;
P: more than 0.030 to 0.048%;
S: 0.025% or less;
Al: 0.005 to 0.20%;
N: 0.010% or less;
Ti: 0.005 to 0.040%;
Nb: 0.005 to 0.060%; and
B: 0.0005 to 0.0030%, with the balance being Fe and impurities, the chemical composition satisfying Formula (1) to Formula (4); and
a galvannealed layer formed on a surface of the base metal steel sheet and containing 7 to 15 mass % of Fe, wherein
an average r value of the galvannealed steel sheet is 1.2 or more,
an in-plane anisotropy Δr value of the galvannealed steel sheet is −0.5 to 0.5, and
a tensile strength of the galvannealed steel sheet is 440 MPa or more:
25×P+4×Si≤3.6 (1)
B−X1≥0.0005 (2)
C−(12/93)×Nb−X2≥−0.0035 (3)
110×Si+48×Mn+550×P≥120 (4)
where for symbols of elements in Formulae, contents (mass %) of corresponding elements are substituted,
in addition, X1 in Formula (2) is defined as follows,
X1=(11/14)[N−(14/48)×Ti] when N−(14/48)×Ti>0, and
X1=0 when N−(14/48)×Ti≤0
in addition, X2 in Formula (3) is defined as follows,
X2=(12/48)[Ti−(48/14)×N] when Ti−(48/14)×N>0, and
X2=0 when Ti−(48/14)×N≤0.
2. The galvannealed steel sheet according to claim 1 , wherein
the chemical composition contains:
C: less than 0.0040%;
Ti: 0.005 to 0.035%; and
Nb: 0.005 to 0.035%.
3. The galvannealed steel sheet according to claim 1 , wherein
the chemical composition contains:
C: 0.0040 to 0.0080%;
Ti: 0.005 to 0.040%; and
Nb: 0.005 to 0.060%, and
a lower limit value of Formula (3) is −0.0002.
4. A production method of a galvannealed steel sheet according to claim 1 , the method comprising:
a step of producing a hot-rolled steel sheet by performing hot rolling on a slab having a chemical composition at a rolling finishing temperature of 800 to 950° C., and coiling the hot-rolled steel sheet at a coiling temperature of 600 to 760° C.;
a step of producing a cold-rolled steel sheet by performing cold rolling on the hot-rolled steel sheet;
a step of producing a base metal steel sheet by performing annealing treatment on the cold-rolled steel sheet;
a step of performing galvanizing treatment on the base metal steel sheet; and
a step of performing alloying treatment in which the galvanized base metal steel sheet is retained at an alloying treatment temperature of 470 to 620° C. for 10 to 40 seconds,
wherein the chemical composition of the slab contains, in mass %:
C: 0.0080% or less;
Si: 0.7% or less;
Mn: 1.0 to 2.5%;
P: more than 0.030 to 0.048%;
S: 0.025% or less;
Al: 0.005 to 0.20%;
N: 0.010% or less;
Ti: 0.005 to 0.040%;
Nb: 0.005 to 0.060%; and
B: 0.0005 to 0.0030%, with the balance being Fe and impurities, the chemical composition satisfying Formula (1) to Formula (4):
25×P+4×Si≤3.6 (1)
B−X1≥0.0005 (2)
C−(12/93)×Nb−X2≥−0.0035 (3)
110×Si+48×Mn+550×P≥120 (4)
where for symbols of elements in Formulae, contents (mass %) of corresponding elements are substituted,
in addition, X1 in Formula (2) is defined as follows,
X1=(11/14)[N−(14/48)×Ti] when N−(14/48)×Ti>0, and
X1=0 when N−(14/48)×Ti≤0
in addition, X2 in Formula (3) is defined as follows,
X2=(12/48)[Ti−(48/14)×N] when Ti−(48/14)×N>0, and
X2=0 when Ti−(48/14)×N≤0.
5. The production method of a galvannealed steel sheet according to claim 4 , further comprising:
a step of, after the step of producing the base metal steel sheet and before the step of performing the galvanizing treatment, performing Ni pre-plating treatment on the base metal steel sheet; and
a step of, after the step of performing the Ni pre-plating treatment and before the step of performing the galvanizing treatment, heating the base metal steel sheet having been subjected to the Ni pre-plating.
6. The production method of a galvannealed steel sheet according to claim 4 ,
wherein the chemical composition of the slab contains:
C: less than 0.0040%;
Ti: 0.005 to 0.035%; and
Nb: 0.005 to 0.035%.
7. The production method of a galvannealed steel sheet according to claim 6 , further comprising:
a step of, after the step of producing the base metal steel sheet and before the step of performing the galvanizing treatment, performing Ni pre-plating treatment on the base metal steel sheet; and
a step of, after the step of performing the Ni pre-plating treatment and before the step of performing the galvanizing treatment, heating the base metal steel sheet having been subjected to the Ni pre-plating.
8. The production method of a galvannealed steel sheet according to claim 4 ,
wherein the chemical composition of the slab contains:
C: 0.0040 to 0.0080%;
Ti: 0.005 to 0.040%; and
Nb: 0.005 to 0.060%, and
a lower limit value of Formula (3) is −0.0002.
9. The production method of a galvannealed steel sheet according to claim 8 , further comprising:
a step of, after the step of producing the base metal steel sheet and before the step of performing the galvanizing treatment, performing Ni pre-plating treatment on the base metal steel sheet; and
a step of, after the step of performing the Ni pre-plating treatment and before the step of performing the galvanizing treatment, heating the base metal steel sheet having been subjected to the Ni pre-plating.