Method of decreasing aldehyde content in a polymeric material

1. A method of decreasing aldehyde content in a polymeric material, the method comprises the step of contacting the polymeric material with a compound (A) which includes:

(I) a first fragment which comprises a moiety

and a moiety

NH  (B)

wherein the carbon atom of moiety (A) and the nitrogen atom of moiety (B) are separated by at least one and not more than two atoms;

(II) a second fragment which comprises a moiety

and a moiety

NH  (B)

wherein the carbon atom of moiety (A) and the nitrogen atom of moiety (B) are separated by at least one and not more than two atoms; and

(III) a third fragment which comprises a moiety

and a moiety

NH  (B).

2. A method according to claim 1 , wherein the carbon atom of moiety (A) and the nitrogen atom of moiety (B) are separated by two atoms which are both unsaturated carbon atoms.

3. A method of decreasing aldehyde content in a polymeric material, the method comprises the step of contacting the polymeric material with a compound (A) which includes:

(I) a first fragment which comprises a moiety

and a moiety

NH   (B)

wherein the carbon atom of moiety (A) and the nitrogen atom of moeity (B) are separated by at least one and not more than two atoms;

and a moiety

wherein R′ represents a substituent and n1 is 0 to 4;

wherein moiety (B) in said first fragment is NH 2 and/or the NH moiety bonded to the benzene moiety (C) is NH 2 ;

(II) a second fragment which comprises a moiety

and a moiety

NH   (B)

wherein the carbon atom of moiety (A) and the atom of moiety (B) are separated by at least one and not more than two atoms; and

(III) a third fragment which comprises a moiety

and a moiety

NH   (B).

4. A method according to claim 3 , wherein said second fragment comprises a moiety:

wherein R′ represents a substituent and n1 is 0 to 4; wherein moiety (B) of said second fragment is NH 2 and/or the NH moiety bonded to the benzene moiety is NH 2 ;

wherein said third fragment comprises a moiety:

wherein R′ represents a substituent and n1 is 0 to 4;

wherein moiety (B) of said third fragment is NH 2 and/or the NH moiety bonded to the benzene moiety is NH 2 .

5. A method according to claim 1 , wherein when compound (A) is not a polymer it has a molecular weight of at least 400 Daltons; or when compound (A) is a polymer it has a number average molecular weight (Mn) determined by GPC of at least 450 Daltons.

6. A method according to claim 1 , wherein said compound (A) is a liquid at 250° C.

7. A method according to claim 1 , wherein said first fragment, said second fragment and said third fragment are bonded to a main fragment of compound (A) via the nitrogen atoms of moiety CO.NH of respective moieties (A) of said first fragment, said second fragment and said third fragment.

8. A method according to claim 7 , wherein said main fragment has a molecular weight of more than the molecular weight of said first fragment.

9. A method according to claim 8 , wherein said main fragment consists of carbon and hydrogen atoms and only one other type of atom which is selected from oxygen and nitrogen atoms.

10. A method according to claim 8 , wherein said main fragment is saturated.

11. A method according to claim 7 , wherein said main fragment includes substantially no primary amine moieties except primary amine moieties which are separated from a carbonyl moiety by at least one and not more than two atoms.

12. A method according to claim 7 , wherein said main fragment includes:

(i) a moiety:

wherein R 2 and R 3 independently represent a hydrogen atom or an optionally-substituted alkyl group;

wherein R 4 , R 5 , R 6 and R 7 independently represent a hydrogen atom or an optionally-substituted alkyl group; (iii) atoms selected from carbon, hydrogen, oxygen and nitrogen atoms only; and/or

(iv) a moiety:

wherein R 8 , R 9 , R 10 and R 11 independently represent a hydrogen atom or an optionally-substituted, alkyl group.

13. A method according to claim 7 , wherein said main fragment includes a moiety:

wherein R 8 , R 9 , R 10 and R 11 independently represent a hydrogen atom or an optionally-substituted alkyl group.

14. A method according to claim 1 , wherein compound (A) includes first, second and third fragments which comprise a moiety

wherein a linking moiety L 2 is arranged between said first, second and third fragments to which said first, second and third fragments are bonded at spaced apart positions, wherein the linking moiety is bonded to the benzene moieties of moiety (AA).

15. A method according to claim 1 , wherein said polymeric material contacted in the method is selected from a polyester, a polyurethane and a polyolefin.

16. A method according to claim 1 , wherein said compound (A) is associated with an organic liquid carrier which is compatible with said polymeric material; wherein the wt % of compound (A) in said mixture is less than 60% wt %.

17. A method of making an article from a polymeric material, the method comprising:

(a) selecting a compound (A);

(b) contacting the polymeric material with said compound (A); and

(c) forming said polymeric material into an article;

wherein said article comprises a container or preform for a container;

wherein compound (A) includes:

(I) a first fragment which comprises a moiety

and a moiety

NH  (B)

wherein the carbon atom of moiety (A) and the nitrogen atom of moiety (B) are separated by at least one and not more than two atoms;

(II) a second fragment which comprises a moiety

and a moiety

NH  (B)

wherein the carbon atom of moiety (A) and the nitrogen atom of moiety (B) are separated by at least one and not more than two atoms; and

(III) a third fragment which comprises a moiety

and a moiety

NH  (B).

18. A method according to claim 3 , wherein:

the carbon atom of moiety (A) and the nitrogen atom of moiety (B) of the first fragment (I) are separated by two atoms which are both unsaturated carbon atoms;

said second fragment comprises a moiety:

wherein R′ represents a substituent and n1 is 0 to 4;

moiety (B) of said second fragment is NH 2 and/or the NH moiety bonded to the benzene moiety is NH 2 ;

said third fragment comprises a moiety:

wherein R′ represents a substituent and n1 is 0 to 4; and

wherein moiety (B) of said third fragment is NH 2 and/or the NH moiety bonded to the benzene moiety (C) is NH 2 .

19. A method according to claim 1 , wherein:

said compound (A) is a liquid at 250° C.;

wherein said first fragment, said second fragment and said third fragment are bonded to a main fragment of compound (A) via the nitrogen atoms of moiety CO.NH of respective moieties (A) of said first fragment, said second fragment and said third fragment, wherein said main fragment is saturated;

said main fragment includes substantially no primary amine moieties except primary amine moieties which are separated from a carbonyl moiety by at least one and not more than two atoms;

said polymeric material contacted in the method is a polyester.