IP Library Granted Patent US 10,837,096
Granted Patent B2
US 10,837,096 · App. 15/754,641 · Granted Nov 17, 2020

Nitrided steel part and method of production of same

Inventors: Takahide Umehara (Tokyo, JP); Masato Yuya (Tokyo, JP); Yoshihiro Daito (Tokyo, JP)
Assignee: NIPPON STEEL CORPORATION
C23C8/26C21D9/00C22C38/00C22C38/001C22C38/02C22C38/04C22C38/06C22C38/08C22C38/12C22C38/28C22C38/60C21D9/30
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Quick Facts
Patent No.
US 10,837,096
App. No.
15/754,641
Granted
Nov 17, 2020
Kind
B2
Abstract

A nitrided steel part excellent in bending straightening ability and bending fatigue characteristic enabling reduction of size and decrease of weight of parts or enabling demand for high load capacities to be met, using as a material a steel material containing, by mass %, C: 0.2 to 0.6%, Si: 0.05 to 1.5%, Mn: 0.2 to 2.5%, P: 0.025% or less, S: 0.003 to 0.05%, Cr: 0.05 to 0.5%, Al: 0.01 to 0.05%, and N: 0.003 to 0.025%, and having a balance of Fe and impurities, having formed on the steel surface a compound layer of a thickness 3 μm or less comprising iron, nitrogen, and carbon and a hardened layer formed below the compound layer, and having an effective hardened layer depth of 160 to 410 μm.

Claims (51)

1. A nitrided steel part comprising a steel material as a material, the steel material consisting of, by mass %,

C: 0.2 to 0.6%,

Si: 0.05 to 1.5%,

Mn: 0.2 to 2.5%,

P: 0.025% or less,

S: 0.003 to 0.05%,

Cr: 0.05 to 0.5%,

Al: 0.01 to 0.05%,

N: 0.003 to 0.025%,

optionally one or more of

Mo: 0.01 to less than 0.50%,

V: 0.01 to less than 0.50%,

Cu: 0.01 to less than 0.50%,

Ni: 0.01 to less than 0.50%, and

Ti: 0.005 to less than 0.05%, and

a balance of Fe and impurities,

the surface structure of the nitrided steel part is mainly composed of ferrite phase,

the nitrided steel part comprising a compound layer of a thickness of 3 μm or less comprising iron, nitrogen, and carbon formed on the steel surface and a hardened layer formed under the compound layer,

an effective hardened layer depth of the nitrided steel part being 160 to 410 μm,

wherein

the effective hardened layer depth is a depth where a Vickers hardness measured in the depth direction from the surface of the nitrided steel part, using a hardness distribution in the depth direction of the Vickers hardness measured in accordance with JIS Z 2244, is 250HV or more; and

a ratio of voids in an area of 25 μm 2 in a range of 5 μm depth from an outermost surface of the steel part is less than 10%.

2. A method of nitriding production of a nitrided steel part, comprising

using as a material a steel material consisting of, by mass %,

C: 0.2 to 0.6%,

Si: 0.05 to 1.5%,

Mn: 0.2 to 2.5%,

P: 0.025% or less,

S: 0.003 to 0.05%,

Cr: 0.05 to 0.5%,

Al: 0.01 to 0.05%,

N: 0.003 to 0.025%,

optionally one or more of

Mo: 0.01 to less than 0.50%,

V: 0.01 to less than 0.50%,

Cu: 0.01 to less than 0.50%,

Ni: 0.01 to less than 0.50%, and

Ti: 0.005 to less than 0.05%, and

a balance of Fe and impurities,

gas nitriding by heating the steel material in a gas atmosphere containing NH 3 , H 2 , and N 2 to 550 to 620° C., and making the overall treatment time A 1.5 to 10 hours,

the gas nitriding comprised of high K N value treatment having a treatment time of X hours and a low K N value treatment after the high K N value treatment having a treatment time of Y hours,

the high K N value treatment having a nitriding potential K NX determined by formula (1) of 0.15 to 1.50 and having an average value K NXave of the nitriding potential K NX determined by formula (2) of 0.30 to 0.80, and

the low K N value treatment having a nitriding potential K NY determined by formula (3) of 0.02 to 0.25, having an average value K NYave of the nitriding potential K NY determined by formula (4) of 0.03 to 0.20 and having an average value K Nave of the nitriding potential determined by formula (5) of 0.07 to 0.30:

K NX =( NH 3 partial pressure) X /[( H 2 partial pressure) 3/2 ] X   (1)

K NXave =Σ i=1 n ( X 0 ×K NXi )/ X   (2)

K NY =( NH 3 partial pressure) Y /[( H 2 partial pressure) 3/2 ] Y   (3)

K NYave =Σ i=1 n ( Y 0 ×K NYi )/ Y   (4)

K Nave =( X×K NXave +Y×K NYave )/ A   (5)

wherein, in formula (2) and formula (4), the subscript “i” is a number indicating the number of measurements for each constant time interval, X 0 indicates the measurement interval (hours) of the nitriding potential K NX , Y 0 indicates the measurement interval (hours) of the nitriding potential K NY , K NXi indicates the nitriding potential at the i-th measurement during the high K N value treatment, and K Nyi indicates the nitriding potential at the i-th measurement during the low K N value treatment,

wherein, the surface structure of the nitrided steel part is mainly composed of ferrite phase.

3. The method of production of the nitrided steel part of claim 2 wherein the gas atmosphere includes a total of 99.5 vol % of NH 3 , H 2 , and N 2 .

Assignments (2)
CHANGE OF NAME Recorded May 14, 2019
From: NIPPON STEEL & SUMITOMO METAL CORPORATION
To: NIPPON STEEL CORPORATION
Reel/Frame 049257/0828 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 23, 2018
From: UMEHARA, TAKAHIDE; YUYA, MASATO; DAITO, YOSHIHIRO
To: NIPPON STEEL & SUMITOMO METAL CORPORATION
Reel/Frame 045017/0689 →