WATER-REDISPERSIBLE POLYMER POWDER
In a water-redispersible polymer powder—the polymer is at least one esterified cellulose ether comprising (i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation, and—the polymer powder comprises from 0.05 to 20 percent of at least one salt of a fatty acid, based on the weight of the esterified cellulose ether(s).
1 . A water-redispersible polymer powder, wherein
the polymer is at least one esterified cellulose ether comprising (i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation, and
the polymer powder comprises from 0.05 to 20 percent of at least one salt of a fatty acid, based on the weight of the esterified cellulose ether(s).
2 . The water-redispersible polymer powder of claim 1 comprising from 0.5 to 10 percent of an ammonium, alkali metal or alkaline earth metal salt of a saturated or unsaturated fatty acid, based on the weight of the esterified cellulose ether.
3 . The water-redispersible polymer powder of claim 1 wherein the salt of a fatty acid is an ammonium, alkali metal or alkaline earth metal salt of stearic acid or oleic acid.
4 . The water-redispersible polymer powder of claim 1 wherein the degree of neutralization of the groups —C(O)—R—COOA is not more than 0.4.
5 . The water-redispersible polymer powder of claim 1 wherein the aliphatic monovalent acyl groups in the esterified cellulose ether are acetyl, propionyl or butyryl groups, and the groups of the formula —C(O)—R—COOA are —C(O)—CH 2 —CH 2 —COOA, —C(O)—CH═CH—COOA, or —C(O)—C 6 H 4 —COOA groups.
6 . The water-redispersible polymer powder of claim 1 wherein the esterified cellulose ether is hydroxypropyl methyl cellulose acetate succinate.
7 . The water-redispersible polymer powder of claim 1 wherein the median particle size, Dn50, of the powder particles is up to 5 micrometers, such median particle size, Dn50, being the size at which 50 number percent of the powder particles have a smaller equivalent diameter and 50 number percent have a larger equivalent diameter.
8 . The water-redispersible polymer powder of claim 7 wherein the median particle size, Dn50, of the powder particles is up to 4 micrometers.
9 . The water-redispersible polymer powder of claim 1 wherein Dn90 of the powder particles is up to 12 micrometers, Dn90 being the diameter where 90 number percent of the powder particles have a smaller equivalent diameter and the other 10 number percent have a larger equivalent diameter.
10 . A process for producing the water-redispersible polymer powder of claim 1 comprising the steps of
grinding, in the presence of an aqueous diluent, at least one esterified cellulose ether comprising (i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation,
blending from 0.05 to 20 percent of at least one salt of a fatty acid and optionally one or more adjuvants with the esterified cellulose ether before, during or after the grinding of the esterified cellulose ether, the percentage of the fatty acid salt being based on the weight of the esterified cellulose ether, and
subjecting the produced aqueous composition to spray-drying.
11 . A process for producing the water-redispersible polymer powder of claim 1 comprising the steps of
melting a) at least one esterified cellulose ether comprising
(i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation, and
emulsifying the molten esterified cellulose ether in b) an aqueous diluent,
adding c) from 0.05 to 20 percent of a salt of a fatty acid, based on the weight of the esterified cellulose ether, and optionally d) one or more adjuvants before, during or after the step of emulsifying the molten esterified cellulose ether in the aqueous diluent,
cooling the emulsion to form an aqueous dispersion and
subjecting the produced aqueous composition to spray-drying.
12 . A process for producing the water-redispersible polymer powder of claim 1 comprising the steps of
providing an aqueous composition which comprises
a) dispersed particles of at least one esterified cellulose ether comprising
(i) groups of the formula —C(O)—R—COOA or (ii) a combination of aliphatic monovalent acyl groups and groups of the formula —C(O)—R—COOA, wherein R is a divalent aliphatic or aromatic hydrocarbon group and A is hydrogen or a cation,
and
b) from 0.05 to 20 percent of at least one salt of a fatty acid, based on the weight of the dispersed esterified cellulose ether, and
subjecting the aqueous composition to spray-drying.
13 . The process of claim 10 wherein the median particle size, Dn50, of the dispersed particles is up to 5 micrometers, such median particle size, Dn50, being the size at which 50 number percent of the dispersed particles have a smaller equivalent diameter and 50 number percent have a larger equivalent diameter.
14 . A process for coating a dosage form comprising the steps of
dispersing the water-redispersible polymer powder of claim 1 in water,
adding a film forming aid and optional adjuvants to form an aqueous coating composition and
coating a dosage form with the aqueous coating composition.
15 . A process for producing capsule shells comprising the steps of
dispersing the water-redispersible polymer powder of claim 1 in water,
adding a film forming aid and optional adjuvants to form an aqueous composition,
pre-heating molding pins to a temperature higher than that of the aqueous composition,
dipping the pre-heated molding pins into the aqueous composition,
forming a film on said molding pins by withdrawing said pins from said aqueous composition, and
drying the film on the molding pins.
16 . The process of claim 11 wherein the median particle size, Dn50, of the dispersed particles is up to 5 micrometers, such median particle size, Dn50, being the size at which 50 number percent of the dispersed particles have a smaller equivalent diameter and 50 number percent have a larger equivalent diameter.
17 . The process of claim 12 wherein the median particle size, Dn50, of the dispersed particles is up to 5 micrometers, such median particle size, Dn50, being the size at which 50 number percent of the dispersed particles have a smaller equivalent diameter and 50 number percent have a larger equivalent diameter.