METHOD AND COMPOSITION FOR STABLE LIQUID TETRAACETYLETHYLENEDIAMINE COMPOSITION
The presently disclosed subject matter is directed to a stable liquid tetraacetylethylenediamine composition that can be used in hot and cold temperature washes. The disclosed liquid tetraacetylethylenediamine composition comprises tetraacetylethylenediamine, water, polymeric sulfonic acid, a buffer system and at least one additive. Also disclosed is a method for preparing a peroxide solution using a stable liquid tetraacetylethylenediamine composition and a peroxide and a method of using the peroxide solution.
1 . A liquid tetraacetylethylenediamine composition comprising:
15 wt % to 20 wt % tetraacetylethylenediamine,
75 wt % or less water,
0.5 wt % to 2 wt % polymeric sulfonic acid,
1 wt % to 4 wt % of a buffer system, and
0.5 wt % to 3 wt % of at least one additive.
2 . The liquid tetraacetylethylenediamine composition of claim 1 , wherein the buffer system is an acetic acid buffer system comprising acetic acid and sodium acetate.
3 . The liquid tetraacetylethylenediamine composition as in either claim 1 or 2 , wherein the additive comprises at least one member selected from the group consisting of a colorant, perfume, preservative, chelating agent, and solvent.
4 . The liquid tetraacetylethylenediamine composition of claim 3 , wherein the preservative comprises at least one member selected from the group consisting of glutaraldehyde, isothiazolinone, benzyalkonium chloride, polyaminopropyl biguanide, ethylenediaminetetraacetic acid, triclosan and thimerosal.
5 . The liquid tetraacetylethylenediamine composition of claim 3 , wherein the chelating agent comprises at least one member selected from the group consisting of diethylene triamine pentaacetic acid, ethylenediaminetetraacetate, diethylene triamine penta(methylene phosphonic)acid, ethylene diamine tetra(methylene phosphonic) acid, ethylene diamine disuccinic acid, 1-hydroxyethane-1,1-diphosphonic acid, methylglycine diacetic acid, nitriloacetic acid, L-glutamic acid N,N-diacetic acid, tetrasodium salt, glutamic acid, N,N-diacetic acid sodium salt and their salts.
6 . A method of preparing a peroxide solution, the method comprising:
preparing the liquid tetraacetylethylenediamine composition of claim 1 ; and
contacting the liquid tetraacetylethylenediamine composition and a bleaching compound;
wherein the liquid tetraacetylethylenediamine composition is contacted with the bleaching compound in the presence of a reaction medium.
7 . The method of claim 6 , wherein the bleaching compound is hydrogen peroxide.
8 . The method of claim 6 or 7 , wherein the buffer system is an acetic acid buffer system comprising acetic acid and sodium acetate.
9 . The method as in any one of claims 6 - 8 , wherein the additive comprises at least one member selected from the group consisting of a colorant, perfume, preservative, chelating agent and solvent.
10 . The method of claim 9 , wherein the preservative comprises at least one member selected from the group consisting of glutaraldehyde, isothiazolinone, benzyalkonium chloride, polyaminopropyl biguanide, ethylenediaminetetraacetic acid, triclosan and thimerosal.
11 . The method of claim 9 , wherein the chelating agent comprises at least one member selected from the group consisting of diethylene triamine pentaacetic acid, ethylenediaminetetraacetate, diethylene triamine penta(methylene phosphonic)acid, ethylene diamine tetra(methylene phosphonic) acid, ethylene diamine disuccinic acid, 1-hydroxyethane-1,1-diphosphonic acid, methylglycine diacetic acid, nitriloacetic acid, L-glutamic acid N,N-diacetic acid, tetrasodium salt, glutamic acid, N,N-diacetic acid sodium salt and their salts.
12 . The method as in any one of claims 6 - 11 , wherein the reaction medium is water.
13 . A method of treating a product, the method comprising:
preparing the liquid tetraacetylethylenediamine composition of claim 1 ;
contacting the liquid tetraacetylethylenediamine composition of claim 1 and a bleaching compound to form a peroxide solution, wherein the liquid tetraacetylethylenediamine composition of claim 1 is contacted with the bleaching compound in the presence of a reaction medium; and
treating a fabric with the peroxide solution by adding the peroxide solution to a container containing the fabric.
14 . The method of claim 13 , wherein the bleaching compound is hydrogen peroxide.
15 . The method of claim 13 or 14 , wherein the buffer system is an acetic acid buffer system comprising acetic acid and sodium acetate.
16 . The method as in any one of claims 13 - 15 , wherein the additive comprises at least one member selected from the group consisting of a colorant, perfume, preservative, chelating agent and solvent.
17 . The method of claim 16 , wherein the preservative comprises at least one member selected from the group consisting of glutaraldehyde, isothiazolinone, benzyalkonium chloride, polyaminopropyl biguanide, ethylenediaminetetraacetic acid, triclosan and thimerosal.
18 . The method of claim 16 , wherein the chelating agent comprises at least one member selected from the group consisting of diethylene triamine pentaacetic acid, ethylenediaminetetraacetate, diethylene triamine penta(methylene phosphonic)acid, ethylene diamine tetra(methylene phosphonic) acid, ethylene diamine disuccinic acid, 1-hydroxyethane-1,1-diphosphonic acid, methylglycine diacetic acid, nitriloacetic acid, L-glutamic acid N,N-diacetic acid, tetrasodium salt, glutamic acid, N,N-diacetic acid sodium salt and their salts.
19 . The method as in any one of claims 13 - 18 , wherein the reaction medium is water.