Cathode active substance used for lithium ion secondary battery, cathode including same, and lithium ion secondary battery provided with cathode
Provided are a cathode active substance used for a lithium ion secondary battery capable of suppressing an increase in an internal resistance inside the battery caused following charge/discharge cycles, a cathode including the cathode active substance, and a lithium ion secondary battery provided with the cathode. The cathode active substance includes a lithium composite compound represented by Formula: Li 1+α Ni x Co y M 1 1-x-y-z M 2 z O 2+β . When Pi is defined as porosity with respect to an opening diameter of 0.6 μm or less and measured by subjecting the active substance to a mercury press-in method, and Pp is defined as porosity with respect to the same diameter and measured by filling the active substance in a mold with an inner diameter of 10 mm, pressing the filled substance by a load of 40 MPa, and subjecting the pressed substance to the same method, a value of Pp/Pi is 1.5 or less.
1. A cathode active substance used for a lithium ion secondary battery, the cathode active substance comprising:
a lithium composite compound represented by the following Formula (1):
Li 1+α Ni x Co y M 1 1-x-y-z Ti z O 2+β Formula (1)
where “α”, “β”, “x”, “y” and “z” are respectively numbers satisfying the following conditions: −0.03≤α≤0.08, −0.2≤β≤0.2, 0.7≤x≤0.9, 0.03≤y≤0.3, 0≤z≤0.1, M 1 is at least one element selected from Mn and Al, wherein
when Pi is defined as porosity in an initial state before charge/discharge operation and before being pressed with respect to an opening diameter of 0.6 μm or less, the porosity Pi being measured by subjecting the cathode active substance to a mercury press-in method, and
when Pp is defined as porosity with respect to an opening diameter of 0.6 μm or less, the porosity Pp being measured by filing the cathode active substance in a mold with an inner diameter of 10 mm, pressing the substance thus filled therein by a load of 40 MPa, thereby subjecting the pressed substance to a mercury press-in method,
a value of Pp/Pi is 1.5 or less, and an atomic ratio of Ti 3+ to Ti 4+ (Ti 3+ /Ti 4+ ) is 1.5 or more and 20 or less based on an X-ray photoelectron spectroscopic analysis.
2. The cathode active substance used for a lithium ion secondary battery according to claim 1 , wherein the porosity Pp is 20% or less.
3. A cathode used for a lithium ion secondary battery, the cathode comprising a cathode active substance used for a lithium ion secondary battery according to claim 1 .
4. A lithium ion secondary battery, the secondary battery comprising a cathode used for a lithium ion secondary battery according to claim 3 .