Fuel cell system
There is disclose a fuel cell system including at least one fuel cell and a duct to supply oxidant to the cathode of the at least one fuel cell. The duct includes at least one sorbent getter adapted to extract volatile species from the oxidant. The sorbent getter includes at least one member of the group consisting of magnesium oxide, calcium oxide and manganese oxide. The sorbent getter provides the advantage of extracting volatile species from the oxidant stream.
1. A solid oxide fuel cell system, the solid oxide fuel cell system comprising:
at least one fuel cell and a duct to supply oxidant to the cathode of the at least one fuel cell, the duct comprising a first sorbent getter and second sorbent getter located adjacent each other, and each having a plurality of oxidant apertures, each sorbent getter adapted to extract volatile species from the oxidant, each sorbent getter comprising at least one member of the group consisting of magnesium oxide, calcium oxide, manganese oxide and magnesia magnesium aluminate (MMA) MgO+MgAl 2 O 4 based material,
wherein each sorbent getter is porous with a pore size ranging from approximately 0.1 μm to approximately 100 μm,
wherein an oxidant aperture spacing for the plurality of oxidant apertures of each of the first and second sorbet getters and an oxidant aperture size for the plurality of oxidant apertures of each of the first and second sorbet getters are selected to dissipate jetting in the air stream flow over a separation distance between the first and second sorbet getters,
wherein an oxidant aperture spacing for the plurality of oxidant apertures of the second sorbent getter is selected so that the flow over a surface of the second sorbent getter from a point of impingement on a second surface of the second sorbent getter to one of the plurality of oxidant apertures in the second sorbent getter does not form a full boundary layer, and
wherein the plurality of oxidant apertures of the first sorbent getter are arranged in a uniform pattern with a majority of the apertures being substantially equidistant to at least three other apertures and the plurality of oxidant apertures of the second sorbent getter are arranged in a similar uniform pattern offset from the uniform pattern of first sorbent getter, such that the plurality of oxidant apertures of the second sorbent getter are offset from the plurality of oxidant apertures of the first sorbent getter.
2. A solid oxide fuel cell system as claimed in claim 1 , wherein the pore size of the porous sorbent getters is in the range from approximately 1 μm to approximately 10 μm.
3. A solid oxide fuel cell system as claimed in claim 1 , wherein the MMA based material is configured to have a coefficient of thermal expansion, CTE, complementary to a CTE of the other components in the fuel cell.
4. A solid oxide fuel cell system as claimed in claim 1 , wherein the MMA-based material contains magnesium aluminate spinel with excess magnesia.
5. A solid oxide fuel cell system as claimed in claim 4 , wherein the excess magnesia is located on an exposed surface of each sorbent getter.
6. A solid oxide fuel cell system as claimed in claim 1 , wherein at least one sorbent getter is formed as a substantially planar structure.
7. A solid oxide fuel cell system as claimed in claim 6 , wherein the substantially planar structure has substantially uniform opposed surfaces substantially devoid of apertures.
8. A solid oxide fuel cell system as claimed in claim 6 , wherein the substantially planar structure is provided with a plurality of oxidant apertures.
9. A solid oxide fuel cell system as claimed in claim 8 , wherein the oxidant apertures have a diameter ranging from approximately 0.1 mm to approximately 6 mm.
10. A solid oxide fuel cell system as claimed in claim 8 , wherein the oxidant apertures have a diameter ranging from approximately 0.3 mm to approximately 3 mm.
11. A solid oxide fuel cell system as claimed in claim 6 , wherein the substantially planar structure is arranged within the duct, in the direct flow path of the oxidant travelling through the duct, so that oxidant is forced to pass through the substantially planar structure.
12. A solid oxide fuel cell system as claimed in claim 8 , further comprising additional sorbent getters provided in pairs, wherein all of the sorbent getters are arranged substantially parallel to one another in flow series.
13. A solid oxide fuel cell system as claimed in claim 12 , wherein each pair of sorbent getters is arranged so that the plurality of oxidant apertures of one sorbent getter are off-set relative to those of an adjacent sorbent getter.
14. A solid oxide fuel cell system as claimed in claim 12 , wherein for each pair the sorbent getters are positioned such that the separation distance between them is 1 mm to 100 mm.
15. A solid oxide fuel cell system as claimed in claim 1 , wherein at least one sorbent getter comprises internal channels.
16. A solid oxide fuel cell system as claimed in claim 1 , wherein at least one sorbent getter is positioned at an inlet duct.
17. A solid oxide fuel cell system as claimed in claim 1 , wherein at least one sorbent getter is positioned at an oxidant recycle loop.
18. A solid oxide fuel cell system as claimed in claim 1 , wherein at least one sorbent getter is positioned at an oxidant passage within a heat exchanger.