POLYMER BLENDS FOR IMPROVED GAS BARRIER PROPERTIES
The present invention relates to novel polymer compositions and their use in polyolefin resins. Films and rigid or semi-ridged articles made from these novel polymer compositions provide improved oxygen and/or carbon dioxide barrier protections.
1 . A composition comprising:
a) polyolefin,
b) polymer containing an oxidizable component, said polymer selected from the group consisting of polyethers, copolyether esters, copolyether amides, polyether glycols, at least partially aromatic polyamides, and combinations thereof,
c) transition metal or metal compound, and
d) optionally separately added additive,
said composition characterized in that when an article is formed therefrom and oriented in the x and/or y direction, the article exhibits lower oxygen and/or carbon dioxide transmission than an article formed from a composition without components b) and c) when oriented in the x and/or y direction, or with components b) and c) when not oriented in the x and/or y direction, compared with a control.
2 . The composition of claim 1 comprising:
a) from 90 to 99 parts polyolefin,
b) from 0.1 to 10 parts of polymer containing an oxidizable component, said polymer selected from the group consisting of polyethers, copolyether esters, copolyether amides, polyether glycols, at least partially aromatic polyamides, and combinations thereof,
c) from 10 to 1000 parts per million (ppm) of transition metal or metal compound, and
d) optionally from 0 to 5 parts of separately added additive,
said composition characterized in that when an article is formed therefrom and oriented in the x and/or y direction from 50 to 400%, the article exhibits lower oxygen and/or carbon dioxide transmission than an article formed from a composition without components b) and c) when oriented in the x and/or y direction from 50 to 400%, or with components b) and c) when not oriented in the x and/or y direction from 50 to 400%, compared with a control.
3 . The composition of claim 1 wherein the polymer b) containing an oxidizable component comprises a polyether, and wherein the separately added additive d) comprises at least one compatibilizing agent.
4 . The composition of claim 3 wherein the compatibilizing agent is selected from the group consisting of polyolefins grafted with COPE, maleic anhydride grafted polypropylene, maleic anhydride grafted polyvinyl pyrrolidone, maleic anhydride (MAH), PTMEG, and combinations thereof.
5 . The composition of claim 1 wherein the transition metal is cobalt and is present at 600 ppm or less.
6 . The composition of claim 1 wherein the separately added additive d) comprises stabilizer.
7 . The composition of claim 6 wherein the stabilizer comprises a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS).
8 . The composition of claim 1 wherein an article formed therefrom has been oriented at least 50% in the x and/or y direction.
9 . The composition of claim 1 wherein an article formed therefrom has been oriented at least 100% in the x and/or y direction.
10 . The composition of claim 1 which is liquid at 25° C.
11 . The composition of of claim 1 wherein the polymer b) containing an oxidizable component comprises MXD6 polyamide.
12 . A film having improved oxygen and/or carbon dioxide barrier properties comprising:
a) polyolefin,
b) polymer containing an oxidizable component, said polymer selected from the group consisting of polyethers, copolyether esters, copolyether amides, polyether glycols, at least partially aromatic polyamides, and combinations thereof,
c) transition metal or metal compound, and
d) optionally separately added additive,
said film having been oriented in the x and/or y direction from 50 to 400%.
13 . The film of claim 12 comprising:
a) from 90 to 99.5 parts polyolefin,
b) from 0.1 to 10 parts of polymer containing an oxidizable component, said polymer selected from the group consisting of polyethers, copolyether esters, copolyether amides, polyether glycols, at least partially aromatic polyamides, and combinations thereof,
c) from 10 to 600 parts per million (ppm) of transition metal or metal compound, and
d) optionally from 0 to 5 parts of separately added additive.
14 . The film of claim 12 wherein the polymer b) containing an oxidizable component comprises a polyether, and wherein the separately added additive d) comprises at least one compatibilizing agent.
15 . The film of claim 14 wherein the compatibilizing agent is selected from the group consisting of polyolefins grafted with COPE, maleic anhydride grafted polypropylene, maleic anhydride grafted polyvinyl pyrrolidone, maleic anhydride (MAH), PTMEG, and combinations thereof.
16 . The film of claim 12 wherein the separately added additive d) comprises stabilizer.
17 . The film of claim 12 wherein the polymer b) containing an oxidizable component comprises MXD6 polyamide.
18 . A rigid or semi-rigid article having improved oxygen and/or carbon dioxide barrier properties comprising:
a) polyolefin,
b) polymer containing an oxidizable component, said polymer selected from the group consisting of polyethers, copolyether esters, copolyether amides, polyether glycols, at least partially aromatic polyamides, and combinations thereof,
c) transition metal or metal compound, and
d) optionally separately added additive,
said rigid or semi-rigid article having been oriented in the x and/or y direction from 50 to 400%.
19 . The article of claim 18 comprising:
a) from 90 to 99.5 parts polyolefin,
b) from 0.1 to 10 parts of polymer containing an oxidizable component, said polymer selected from the group consisting of polyethers, copolyether esters, copolyether amides, polyether glycols, at least partially aromatic polyamides, and combinations thereof,
c) from 10 to 600 parts per million (ppm) of transition metal or metal compound, and
d) optionally from 0 to 5 parts of separately added additive.
20 . The article of claim 18 wherein the polymer b) containing an oxidizable component comprises a polyether, and wherein the separately added additive d) comprises at least one compatibilizing agent.
21 . The article of claim 20 wherein the compatibilizing agent is selected from the group consisting of polyolefins grafted with COPE, maleic anhydride grafted polypropylene, maleic anhydride grafted polyvinyl pyrrolidone, maleic anhydride (MAH), PTMEG, and combinations thereof.
22 . The article of claim 18 wherein the separately added additive d) comprises stabilizer.
23 . The article of claim 18 having been blow-molded.
24 . The blow-molded article of claim 23 comprising a bottle.
25 . The article of claim 18 wherein the polymer b) containing an oxidizable component comprises MXD6 polyamide.