Conductive material dispersed liquid and secondary battery manufactured using the same
The present invention provides a conductive material dispersed liquid including a conductive material which includes bundle-type carbon nanotubes; a dispersant which includes a hydrogenated nitrile-based rubber; and a dispersion medium, where a complex modulus (|G*| @ 1 Hz) is in a range of 20 to 500 Pa when measured by a rheometer at a frequency of 1 Hz, and a secondary battery manufactured using the same. The conductive material dispersed liquid has a controlled complex modulus to exhibit excellent dispersibility and powder resistance characteristics, and as a result, can greatly improve the output characteristics of batteries.
1. A conductive material dispersed liquid, comprising:
a conductive material including bundle-type carbon nanotubes;
a dispersant including a hydrogenated nitrile-based rubber; and
a dispersion medium,
wherein a complex modulus (|G*| @ 1 Hz) of the conductive material dispersed liquid is in a range of 20 to 500 Pa when measured by a rheometer at a frequency of 1 Hz,
wherein the hydrogenated nitrile-based rubber includes a repeating unit of a structure derived from a hydrogenated conjugated diene at 1 to 15 wt % based on the total weight of the rubber.
2. The conductive material dispersed liquid according to claim 1 , wherein a shear viscosity of the conductive material dispersed liquid is in a range of 2 to 20 Pa·s at a shear rate of 1/6.3 s when measured by a rheometer.
3. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes have an average value in a range of 0.7 to 1.2 of a ratio (ID/IG) of a maximum peak intensity (ID) of a D band at 1,360±50 cm −1 to a maximum peak intensity (IG) of a G band at 1,580±50 cm −1 obtained by Raman spectroscopy using a laser having a wavelength of 514 nm.
4. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes have a volume resistance of 0.01Ω· cm or less at a pressure of 62 MPa.
5. The conductive material dispersed liquid according to claim 1 , wherein the carbon nanotubes are included at 1 to 5 wt % based on the total weight of the conductive material dispersed liquid.
6. The conductive material dispersed liquid according to claim 1 , wherein the hydrogenated nitrile-based rubber includes a repeating unit of a structure derived from an α,β-unsaturated nitrile at 10 to 60 wt % based on the total weight of the rubber.
7. The conductive material dispersed liquid according to claim 1 , wherein the hydrogenated nitrile-based rubber is a hydrogenated acrylonitrile butadiene-based rubber including a repeating unit of a structure derived from hydrogenated butadiene at 1 to 15 wt % and a repeating unit of a structure derived from acrylonitrile at 10 to 60 wt % based on the total weight of the rubber.
8. The conductive material dispersed liquid according to claim 1 , wherein the hydrogenated nitrile-based rubber has a weight average molecular weight of 10,000 to 700,000 g/mol, and a polydispersity index of 2.0 to 6.0.
9. The conductive material dispersed liquid according to claim 1 , wherein the dispersant is included at 10 to 50 parts by weight based on 100 parts by weight of the carbon nanotubes.
10. The conductive material dispersed liquid according to claim 1 , wherein the dispersant is introduced into a surface of the carbon nanotubes to form a carbon nanotubes-dispersant composite, and the carbon nanotubes-dispersant composite has a D 99 of particle size distribution of 50 μm or less and is included in an amount of 1 to 5 wt % based on the total weight of the dispersed liquid.
11. The conductive material dispersed liquid according to claim 1 , wherein the dispersion medium is an amide-based organic solvent.
12. A method of preparing a conductive material dispersed liquid, comprising mixing a conductive material which includes bundle-type carbon nanotubes, a dispersant and a dispersion medium comprising a hydrogenated nitrile-based rubber, and then milling such that a complex modulus (|G*| @ 1 Hz) of the conductive material dispersed liquid is in a range of 20 to 500 Pa when measured by a rheometer at a frequency of 1 Hz, and
wherein the hydrogenated nitrile-based rubber includes a repeating unit of a structure derived from a hydrogenated conjugated diene at 1 to 15 wt % based on the total weight of the rubber.
13. The method according to claim 12 , wherein the milling is performed by a bead mill.
14. The method according to claim 12 , wherein the milling is performed using a bead mill having an average diameter of 0.5 to 2 mm for 90 to 120 minutes.
15. A composition for forming an electrode of a secondary battery, comprising:
an electrode active material;
a binder; and
the conductive material dispersed liquid according to claim 1 .