Method of preparing electrode for lithium secondary battery and electrode for lithium secondary battery prepared thereby
The present invention relates to a method of preparing an electrode for a lithium secondary battery and an electrode for a lithium secondary battery prepared thereby, wherein, since the method may suppress the migration of a binder and may uniformly control the distribution of the binder in the electrode by forming a plurality of negative electrode active material layers and allowing a drying condition of each of the negative electrode active material layers to be different, the method may improve life characteristics by improving adhesion between a negative electrode active material and a current collector and may improve charging characteristics by reducing interfacial resistance of the negative electrode.
1. A method of preparing a negative electrode for a lithium secondary battery, the method comprising:
(a) preparing a negative electrode collector;
(b) coating the negative electrode collector with a first negative electrode active material composition including a first negative electrode active material and a first binder;
(c) performing primary drying of the coated first negative electrode active material composition at a primary drying temperature to form a first negative electrode active material layer;
(d) coating the first negative electrode active material layer with a second negative electrode active material composition including a second negative electrode active material and a second binder; and
(e) performing secondary drying of the coated second negative electrode active material composition at a secondary drying temperature to form a second negative electrode active material layer,
wherein the secondary drying temperature is lower than the primary drying temperature,
wherein the secondary drying temperature is 40° C. to 60° C.,
wherein the secondary drying is the only drying performed on the second negative electrode active material composition, and
wherein a weight percent of the first binder to the first negative electrode active material composition is in a range of 2.0 wt % to 3.0 wt %, and
a weight percent of the second binder to the second negative electrode active material composition is in a range of 1.0 wt % to 2.5 wt %.
2. The method of claim 1 , wherein the secondary drying temperature is 30° C. to 60° C. lower than the primary drying temperature.
3. The method of claim 1 , wherein a weight ratio of the first binder of the first negative electrode active material layer to the second binder of the second negative electrode active material layer is in a range of 5:5 to 6:4.
4. The method of claim 1 , wherein the first binder and the second binder are the same or different from each other.
5. The method of claim 1 , wherein a loading ratio of the negative electrode active material of the first negative electrode active material layer to the second negative electrode active material layer is in a range of 5:5 to 6:4.
6. The method of claim 1 , wherein a loading amount of the entire multilayer-structured negative electrode active material including the first and second negative electrode active material layers is in a range of 3 mAh/cm 2 to 6 mAh/cm 2 .
7. A negative electrode for a lithium secondary battery prepared by the method of claim 1 , the negative electrode comprising: a negative electrode collector; a first negative electrode active material layer including a first negative electrode active material and a first binder and formed on the negative electrode collector; and a second negative electrode active material layer including a second negative electrode active material and a second binder and formed on the first negative electrode active material layer, wherein a weight ratio of the second binder included in the second negative electrode active material layer is smaller than a weight ratio of the first binder included in the first negative electrode active material layer.
8. The negative electrode for a lithium secondary battery of claim 7 , wherein the first binder and the second binder are the same or different from each other.
9. The negative electrode for a lithium secondary battery of claim 7 , wherein a loading ratio of the negative electrode active material of the first negative electrode active material layer to the second negative electrode active material layer is in a range of 5:5 to 6:4.
10. A lithium secondary battery comprising the negative electrode of claim 7 .