Rare earth cobalt-based permanent magnet
A rare-earth cobalt permanent magnet with good magnetic properties is provided. A rare-earth cobalt permanent magnet contains 23 to 27 mass % R, 3.5 to 5.0 mass % Cu, 18 to 25 mass % Fe, 1.5 to 3.0 mass % Zr in mass and a remainder Co with inevitable impurities, where an element R is a rare earth element at least containing Sm. The rare-earth cobalt permanent magnet has a metal structure including a plurality of crystal grains and a continuously extending grain boundary. A content of Cu in the grain boundary is higher than a content of Cu in the crystal grains, and a content of Zr in the grain boundary is higher than a content of Zr in the crystal grains.
1. A rare earth-cobalt permanent magnet containing 23 to 27 mass % R, 3.5 to 5.0 mass % Cu, 18 to 25 mass % Fe, 1.5 to 3.0 mass % Zr, and a remainder Co with inevitable impurities, where R is Sm and optionally additional rare earth elements, wherein the rare earth-cobalt permanent magnet has a metal structure including a plurality of crystal grains and a grain boundary, the grain boundary has a continuously extending shape, a content of Cu in the grain boundary is higher than a content of Cu in the crystal grains, a content of Zr in the grain boundary is higher than a content of Zr in the crystal grains, the grain boundary contains 6 to 20 mass % Zr; and wherein in a magnetic field, a reverse magnetic domain occurs only from one side of a cross section of the grain boundary and propagates into the crystal grains.
2. The rare earth-cobalt permanent magnet according to claim 1 , wherein the grain boundary contains 5 to 45 mass % Cu.
3. The rare earth-cobalt permanent magnet according to claim 1 , wherein when a specified applied magnetic field is applied in a demagnetizing field and the applied magnetic field is gradually increased, a magnetic wall comes into existence in a boundary between the plurality of crystal grains, and wherein when the applied magnetic field continues to be gradually increased and the applied magnetic field exceeds a critical magnetic field, the magnetic wall propagates into the crystal grain, and the critical magnetic field is equal to or more than 480 kA/m.
4. The rare earth-cobalt permanent magnet according to claim 1 , wherein an inherent coercive force is equal to or more than 1600 kA/m.
5. The rare earth-cobalt permanent magnet according to claim 1 , wherein, among inevitable impurities, C is restricted to 200 to 1000 ppm by mass.
6. The rare earth-cobalt permanent magnet according to claim 1 , wherein, among inevitable impurities, O is restricted to 1000 to 5000 ppm by mass.
7. The rare earth-cobalt permanent magnet according to claim 4 , wherein a density is equal to or more than 8.25 g/cm 3 , and a maximum energy product is equal to or more than 255 kJ/m 3 .
8. A motor using the rare earth-cobalt permanent magnet according to claim 1 .
9. A device using the rare earth-cobalt permanent magnet according claim 1 .
10. The rare earth-cobalt permanent magnet according to claim 2 , wherein when a specified applied magnetic field is applied in a demagnetizing field and the applied magnetic field is gradually increased, a magnetic wall comes into existence in a boundary between the plurality of crystal grains, and wherein when the applied magnetic field continues to be gradually increased and the applied magnetic field exceeds a critical magnetic field, the magnetic wall propagates into the crystal grain, and the critical magnetic field is equal to or more than 480 kA/m.
11. The rare earth-cobalt permanent magnet according to claim 2 , wherein an inherent coercive force is equal to or more than 1600 kA/m.
12. The rare earth-cobalt permanent magnet according to claim 2 , wherein, among inevitable impurities, C is restricted to 200 to 1000 ppm by mass.
13. The rare earth-cobalt permanent magnet according to claim 2 , wherein, among inevitable impurities, O is restricted to 1000 to 5000 ppm by mass.
14. The rare earth-cobalt permanent magnet according to claim 11 , wherein a density is equal to or more than 8.25 g/cm 3 , and a maximum energy product is equal to or more than 255 kJ/m 3 .
15. A motor using the rare earth-cobalt permanent magnet according to claim 2 .
16. A device using the rare earth-cobalt permanent magnet according to claim 2 .