IP Library Granted Patent US 10,808,195
Granted Patent B2
US 10,808,195 · App. 15/761,539 · Granted Oct 20, 2020

Fuel compositions

Inventors: Amir Faizal Naidu Abdul-Manan (Kuala Lumpur, MY); Paul Anthony Stevenson (Manchester, GB); Richard John Heins (Manchester, GB); Richard Hugh Clark (Manchester, GB); Robert Wilfred Matthews Wardle (Manchester, GB)
Assignee: SHELL OIL COMPANY
C10L10/10C10G2/00C10L1/06C10L1/1832C10L1/223C10G2300/1022C10G2300/305C10G2300/80C10G2400/02C10L2200/0259C10L2200/0423C10L2200/0492C10L2270/023C10L2270/026
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Quick Facts
Patent No.
US 10,808,195
App. No.
15/761,539
Granted
Oct 20, 2020
Kind
B2
Abstract

Gasoline fuel composition suitable for use in an internal combustion engine comprising: (a) Fischer-Tropsch derived naphtha at a level from 2 to 20% v/v; (b) at least one aromatic octane booster present at a level of 0.75 to 8% v/v or less; and (c) a gasoline base fuel; wherein the gasoline fuel composition comprises 40% v/v or less of aromatics. In a preferred embodiment, the Research Octane Number (RON) of the gasoline fuel composition is increased while maintaining the aromatic content of the gasoline fuel composition at a level of 40% v/v or less, based on the gasoline fuel composition.

Claims (18)

1. Gasoline fuel composition suitable for use in an internal combustion engine comprising:

(a) Fischer-Tropsch derived naphtha at a level from 2 to 20% v/v, wherein the Fischer-Tropsch derived naphtha is a liquid hydrocarbon distillate with a final boiling point of up to 220° C. and an initial boiling point of at least 25° C. and which comprises at least 95% w/w of hydrocarbons having 5 or more carbon atoms and wherein the Fischer-Tropsch derived naphtha consists of at least 90% w/w of paraffinic components and has a Research Octane Number (RON), as measured by ASTM D2699, of at most 40;

(b) at least one aromatic octane booster present at a level of 0.75 to 8% v/v, wherein the aromatic octane booster is selected from aromatic amines, phenols, and mixtures thereof; and

(c) a gasoline base fuel;

wherein the gasoline fuel composition comprises in the range from 32% v/v to 34% v/v of aromatics.

2. Gasoline fuel composition according to claim 1 wherein the aromatic octane booster is an aromatic amine.

3. Gasoline fuel composition according to claim 1 wherein the aromatic octane booster is N-methyl aniline.

4. Gasoline fuel composition according to claim 1 wherein the aromatic octane booster is present at a level of from 1% v/v to 6% v/v, based on the gasoline fuel composition.

5. Gasoline fuel composition according to claim 1 wherein the Fischer-Tropsch naphtha is present at a level from 3.5% v/v to 10.5% v/v, based on the gasoline fuel composition.

6. A method of increasing the Research Octane Number (RON) of a gasoline fuel composition in an internal combustion engine, said method comprising fueling the internal combustion engine with a gasoline fuel composition comprising:

(a) Fischer-Tropsch derived naphtha at a level from 2 to 20% v/v, wherein the Fischer-Tropsch derived naphtha is a liquid hydrocarbon distillate with a final boiling point of up to 220° C. and an initial boiling point of at least 25° C. and which comprises at least 95% w/w of hydrocarbons having 5 or more carbon atoms and wherein the Fischer-Tropsch derived naphtha consists of at least 90% w/w of paraffinic components and has a Research Octane Number (RON), as measured by ASTM D2699, of at most 40;

(b) at least one aromatic octane booster present at a level of 0.75 to 8% v/v, wherein the aromatic octane booster is selected from aromatic amines, phenols, and mixtures thereof; and

(c) a gasoline base fuel;

wherein the gasoline fuel composition comprises in the range from 32% v/v to 34% v/v of aromatics.

7. Method according to claim 6 wherein the Research Octane Number (RON) of the gasoline fuel composition is increased by 1 unit or greater, while maintaining the aromatic content of the gasoline fuel composition at a level in the range from 32% v/v to 34% v/v, based on the gasoline fuel composition.

8. Method according to claim 6 wherein the aromatic octane booster is N-methyl aniline.

9. Method according to claim 6 wherein the aromatic octane booster is present at a level of from 1% v/v to 6% v/v, based on the gasoline fuel composition.

10. Method according to claim 6 wherein the Fischer-Tropsch naphtha is present at a level from 3.5% v/v to 10.5% v/v, based on the gasoline fuel composition.

Assignments (2)
CHANGE OF NAME Recorded Mar 7, 2022
From: SHELL OIL COMPANY
To: SHELL USA, INC.
Reel/Frame 059694/0819 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 20, 2018
From: ABDUL-MANAN, AMIR FAIZAL NAIDU; CLARK, RICHARD HUGH; HEINS, RICHARD JOHN; STEVENSON, PAUL ANTHONY; WARDLE, ROBERT WILFRED MATTHEWS
To: SHELL OIL COMPANY
Reel/Frame 045287/0656 →