Method for purifying and drying a hydrofluoroolefin stream
The invention concerns a method for purifying and drying a hydrofluoroolefin stream comprising a hydrofluoroolefin, water and impurities composed of halogenated carbon compounds, characterised in that said stream is brought into contact with an adsorbent and in that the purification and the drying processes are carried out simultaneously in one and the same step, said hydrofluoroolefin being a compound of formula (I): CX 1 X 2 ═CX 3 CX 4 X 5 X 6 in which each X i (i ranging from 1 to 6) represents, independently of one another, a hydrogen atom or a chlorine or fluorine atom, it being understood that at least one of the Xi's represents a fluorine atom.
1. A method for purifying and drying a hydrofluoroolefin stream comprising a stream of 2,3,3,3-tetrafluoro-1-propene (1234yf), water and impurities based on halogenated carbon compounds, the method comprising placing the hydrofluoroolefin stream in contact with an adsorbent, wherein the adsorbent is molecular sieves which comprise zeolites of type A having a pore diameter ranging from 3 Å to 6 Å, such that purification and drying are performed in one same step, wherein the impurities comprise one or more of chloromethane (F40), tetrafluoromethane (F14), trifluoromethane (F23), or 1,1-difluoroethane (F152a).
2. The method of claim 1 , wherein the hydrofluoroolefin stream comprises at least 50% by weight of at least one same hydrofluoroolefin, relative to the total weight of the hydrofluoroolefin stream.
3. The method according to claim 1 , wherein the hydrofluoroolefin stream comprises at least 70% by weight of at least one same hydrofluoroolefin, relative to the total weight of the hydrofluoroolefin stream.
4. The method of claim 1 , wherein the impurities based on halogenated carbon compounds further comprise one or more of fluoromethane (F41), difluoromethane (F32), 1,1,1-trifluoroethane (F143 a), pentafluoroethane (F125), chloropentafluoroethane (F115), 1,1,1,2-tetrafluoroethane (F134a), pentafluoropropane (F245), monochlorotetrafluoropropene (F244), 1,3,3,3-tetrafluoropropene (F1234ze) isomer E or Z, 3,3,3-trifluoropropene (1243zf), 1,2,3,3,3-pentafluoropropene (F1225 ye), 3,3,3-trifluoropropyne, 1,3-dichloro-3,3-difluoropropene (F1232zd), 1,1-dichloro-3,3-difluoropropene (F1232za), 1,1-dichloro-1,3,3-trifluoropropane (F243fc), or cis isomer of 1-chloro-3,3,3-trifluoropropene (Z-1233zd).
5. A method for purifying and drying a hydrofluoroolefin stream comprising a stream of 1-chloro-3,3,3-trifluoropropene (1233zd), water and impurities based on halogenated carbon compounds, the method comprising placing the hydrofluoroolefin stream in contact with an adsorbent, wherein the adsorbent is a zeolite of type X having a pore diameter ranging from 8 Å to 12 Å, such that purification and drying are performed in one same step.
6. The method of claim 5 , wherein the impurities comprise one or more of pentafluoropropane (F245), 1,3,3,3-tetrafluoropropene (F1234ze), 1,3-dichloro-3,3-difluoropropene (F1232zd), 1,1-dichloro-3,3-difluoropropene (F1232za), 1,1-dichloro-1,3,3-trifluoropropane (F243fc).
7. The method of claim 1 , wherein the hydrofluoroolefin stream, before being placed in contact with the adsorbent, comprises from 10 to 10,000 ppm by mass of water.
8. The method of claim 1 , wherein the hydrofluoroolefin stream, before being placed in contact with the adsorbent, comprises from 500 to 8,000 ppm by mass of impurities.
9. The method of claim 5 , wherein the hydrofluoroolefin stream comprises at least 50% by weight of at least one same hydrofluoroolefin, relative to the total weight of the hydrofluoroolefin stream.
10. The method according to claim 5 , wherein the hydrofluoroolefin stream comprises at least 70% by weight of at least one same hydrofluoroolefin, relative to the total weight of the hydrofluoroolefin stream.
11. The method of claim 5 , wherein the impurities based on halogenated carbon compounds comprise one or more of chloromethane (F40), fluoromethane (F41), difluoromethane (F32), tetrafluoromethane (F14), trifluoromethane (F23), 1,1,1-trifluoroethane (F143a), 1,1-difluoroethane (F152a), pentafluoroethane (F125), chloropentafluoroethane (F115), 1,1,1,2-tetrafluoroethane (F134a), pentafluoropropane (F245), monochlorotetrafluoropropene (F244), 1,3,3,3-tetrafluoropropene (F1234ze) isomer E or Z, 3,3,3-trifluoropropene (1243zf), 1,2,3,3,3-pentafluoropropene (F1225ye), 3,3,3-trifluoropropyne, 1,3-dichloro-3,3-difluoropropene (F1232zd), 1,1-dichloro-3,3-difluoropropene (F1232za), 1,1-dichloro-1,3,3-trifluoropropane (F243fc), or cis isomer of 1-chloro-3,3,3-trifluoropropene (Z-1233zd).
12. The method of claim 5 , wherein the hydrofluoroolefin stream, before being placed in contact with the adsorbent, comprises from 10 to 10,000 ppm by mass of water.
13. The method of claim 5 , wherein the hydrofluoroolefin stream, before being placed in contact with the adsorbent, comprises from 500 to 8,000 ppm by mass of impurities.