Negative electrode active material, and negative electrode and lithium secondary battery which include the same

1. An active material for a lithium secondary battery, which comprises a secondary particle formed by agglomeration of primary particles comprising a lithium titanium composite oxide represented by Formula 1 or Formula 2,

wherein the secondary particle has a pore volume of 0.001 cm 3 /g to 0.05 cm 3 /g:

Li (4-x) M x Ti 5 O 12    [Formula 1]

Li 4 Ti (5-x) M x O 12    [Formula 2]

wherein, in Formula 1 or Formula 2,

0<x≤0.5,

M is sodium (Na), potassium (K), rubidium (Rb), zirconium (Zr), tungsten (W), magnesium (Mg), molybdenum (Mo), or tantalum (Ta), and

wherein an average particle diameter (D 50 ) of the primary particles is decreased by 0.5% to 2% when x is increased by 0.01.

2. The active material for a lithium secondary battery of claim 1 , wherein the primary particles have the average particle diameter (D 50 ) of 0.05 μm to 2 μm.

3. The active material for a lithium secondary battery of claim 1 , wherein an average particle diameter (D 10 ) of the primary particles is 60% to 95% of the average particle diameter (D 50 ), and an average particle diameter (D 90 ) is 105% to 140% of the average particle diameter (D 50 ).

4. The active material for a lithium secondary battery of claim 1 , wherein the secondary particle has an average particle diameter (D 50 ) of 1 μm to 30 μm.

5. The active material for a lithium secondary battery of claim 1 , wherein, when a pressure of 2,000 kgf/cm 2 is applied to the secondary particle, the secondary particle has a pore volume of 70 vol % to 99 vol % based on 100 vol % of the pore volume before applying the pressure.

6. The active material for a lithium secondary battery of claim 1 , wherein M is K, Rb, Mg, or Ta.

7. An electrode for a lithium secondary battery, the electrode comprising the active material for a lithium secondary battery of claim 1 .

8. A lithium secondary battery comprising the electrode for a lithium secondary battery of claim 7 .

9. A method of preparing an active material for a lithium secondary battery, the method comprising steps of:

(1) solid mixing a lithium-containing compound, a titanium oxide, and a doping metal-containing compound;

(2) dispersing the solid mixture of step (1) in a solvent to prepare a slurry;

(3) spray drying the slurry prepared in step (2) to prepare a secondary particle formed by agglomeration of primary particles; and

(4) sintering the secondary particle formed by the agglomeration of the primary particles,

wherein the method does not comprise a separate grinding process of the solid mixture the slurry,

the doping metal comprises at least one selected from the group consisting of sodium (Na), potassium (K), rubidium (Rb), zirconium (Zr), tungsten (W), magnesium (Mg), molybdenum (Mo), and tantalum (Ta), and the secondary particle has a pore volume of 0.001 cm 3 /g to 0.05 cm 3 /g, and

wherein the solid mixing of step (1) further comprises a process of adjusting an amount of the doping metal-containing compound according to a desired particle diameter of the primary particles before the solid mixing.

10. The method of claim 9 , wherein the lithium-containing compound comprises at least one selected from the group consisting of lithium carbonate, lithium hydroxide, and lithium oxide.

11. The method of claim 9 , wherein the doping metal-containing compound comprises at least one selected from the group consisting of carbonate, hydroxide, and oxide of the doping metal.

12. The method of claim 11 , wherein an average particle diameter (D 50 ) of the primary particles formed is reduced by 0.5% to 2% when a molar ratio of the doping metal-containing compound among the lithium-containing compound, titanium oxide, and doping metal-containing compound is increased by 0.01.

13. The method of claim 9 , wherein the primary particles comprise a lithium titanium composite oxide represented by Formula 1 or Formula 2:

Li (4-x) M x Ti 5 O 12    [Formula 1]

Li 4 Ti (5-x) M x O 12    [Formula 2]

wherein, in Formula 1 or Formula 2,

0<x≤0.5, and

M is Na, K, Rb, Zr, W, Mg, Mo, or Ta.

14. The method of claim 13 , wherein an average particle diameter (D 50 ) of the primary particles is reduced by 0.5% to 2% when an x value in Formula 1 or Formula 2 is increased by 0.01.

15. The method of claim 9 , wherein an average particle diameter (D 10 ) of the primary particles is 60% to 95% of an average particle diameter (D 50 ), and an average particle diameter (D 9 O) is 105% to 140% of the average particle diameter (D 50 ).