Epoxy terminated butadiene and butadiene acrylonitrile copolymers
Novel method for production of epoxy terminated butadiene and butadiene acrylonitrile copolymer tougheners synthesized through the use of hydroxyl terminated polybutadiene and hydroxyl terminated butadiene acrylonitrile copolymers as starting materials. The epoxy terminated butadiene and butadiene acrylonitrile copolymers synthesized by the novel method have unexpectedly lower viscosity, contain no free epoxy and provide good improvements in T-peel resistance over traditional tougheners produced using traditional methods. Adhesives, composites and coatings utilizing the tougheners of the inventive method are within the scope of the invention.
1. A method of preparing a low viscosity epoxy terminated polybutadiene polymer, comprising the steps of:
a. providing a hydroxyl terminated butadiene polymer;
b. adding epichlorohydrin to the hydroxyl terminated butadiene polymer with mixing;
c. heating the mixture to a maximum temperature of 90° C.;
d. holding the mixture for a set time;
e. distilling the mixture with aqueous sodium hydroxide;
f. filtering the mixture;
g. adjusting the pH with monosodium phosphate;
h. adding the mixture to water; and
i. separating the organic layer for further distillation and removal of volatiles, wherein the epichlorohydrin:hydroxyl ratio ranges between 25:1 and 35:1, and wherein the NaOH:hydroxyl ratio is greater than about 1.5:1.
2. An epoxy adhesive composition consisting essentially of:
a. 100 parts of epoxy;
b. an epoxy terminated polybutadiene polymer prepared from the method of claim 1 , present as a reactive toughener in an amount of about 10 to about 15 phr of epoxy;
c. a curing agent; and
d. a thixotrope,
wherein the epoxy terminated polybutadiene polymer is the only reactive toughener present in the epoxy adhesive composition; and
wherein the epoxy terminated polybutadiene polymer provides a lower viscosity epoxy adhesive formulation having improved T-peel strength.
3. The epoxy adhesive composition according to claim 2 , wherein the curing agent is a dicyandiamide and the thixotrope is fumed silica.
4. A method of preparing a low viscosity epoxy terminated butadiene acrylonitrile copolymer, comprising the steps of:
a. providing a hydroxyl terminated butadiene acrylonitrile copolymer;
b. adding epichlorohydrin to the hydroxyl terminated butadiene acrylonitrile polymer with mixing;
c. heating the mixture to a maximum temperature of 90° C.;
d. holding the mixture for a set time;
e. distilling the mixture with aqueous sodium hydroxide;
f. filtering the mixture;
g. adjusting the pH with monosodium phosphate;
h. adding the mixture to water; and
i. separating the organic layer for further distillation and removal of volatiles, wherein the epichlorohydrin:hydroxyl ratio ranges between 22:1 to 35:1, and wherein the NaOH:hydroxyl ratio ranges is greater than about 1.5:1.
5. An epoxy adhesive composition consisting essentially of:
a. 100 parts of epoxy;
b. an epoxy terminated butadiene acrylonitrile copolymer prepared from the method of claim 4 , present as a reactive toughener in an amount of about 10 to about 15 phr of epoxy;
c. a curing agent; and
d. a thixotrope,
wherein the epoxy terminated butadiene acrylonitrile copolymer is the only reactive toughener present in the epoxy adhesive composition; and
wherein the epoxy terminated butadiene acrylonitrile copolymer provides a lower viscosity adhesive formulation having improved T-peel strength.
6. The epoxy adhesive composition according to claim 5 , wherein the curing agent is a dicyandiamide and the thixotrope is fumed silica.