Process for the synthesis of acrylic acid oligomers
A process for the synthesis of acrylic acid oligomer represented by formula (I): in which n is an integer ranging from 1 to 10, wherein the process comprises the step of heating acrylic acid at a temperature from 50° C. to 200° C. in the presence of a catalyst, water and at least one polymerization inhibitor. Formula (I) where n=0 is acrylic acid, the precursor for preparing the acrylic acid oligomer.
1. A process for the synthesis of an acrylic acid oligomer represented by the formula (I):
in which n is an integer ranging from 1 to 10,
wherein said process comprises the step of heating acrylic acid at a temperature ranging from 50° C. to 200° C. in the presence of a catalyst, water and at least one polymerization inhibitor.
2. The process according to claim 1 , wherein the acrylic acid is of petrochemical origin.
3. The process according to claim 1 , wherein the acrylic acid is at least partly of renewable origin.
4. The process according to claim 1 wherein the catalyst is a homogeneous acid catalyst or a heterogeneous acid catalyst.
5. The process according to claim 1 wherein the catalyst is a homogeneous basic catalyst or a heterogeneous basic catalyst.
6. The process according to claim 5 , wherein the basic catalyst is sodium hydroxide or potassium hydroxide, and the water present in the reaction medium comes from the reaction of the acrylic acid with the catalyst, without the addition of water to the reaction medium.
7. The process according to claim 1 wherein the weight amount of water used represents from 0.01% to 20% relative to the weight of acrylic acid.
8. The process according to claim 1 wherein the weight amount of polymerization inhibitor used is between 10 and 2000 ppm relative to the weight of acrylic acid.
9. The process according to claim 1 wherein the polymerization inhibitor is chosen from the group consisting of phenothiazine, hydroquinone, hydroquinone monomethyl ether, hindered phenols, TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy), and TEMPO derivatives, alone or mixtures thereof in any proportions.
10. The process according to claim 1 comprising a purification step comprising at least one distillation to eliminate water and/or residual acrylic acid.
11. A process for the synthesis of an acrylic acid oligomer represented by formula (I):
in which n is an integer ranging from 1 to 10,
the process comprising the following steps:
a) heating acrylic acid at a temperature ranging from 50° C. to 200° C. in a reactor comprising a catalyst, in the presence of water and at least one polymerization inhibitor, resulting in a reaction mixture comprising acrylic acid oligomers, acrylic acid, water and polymerization inhibitors;
b) subjecting the reaction mixture to a first distillation to enable separation of a top stream comprising water and acrylic acid, which is at least partially sent back to the reactor, and at the bottom a stream comprising acrylic acid oligomers, residual acrylic acid and polymerization inhibitors;
c) subjecting the bottom stream to a second distillation to enable separation of a stream consisting essentially of acrylic acid and a stream consisting essentially of the acrylic acid oligomer of formula (I) and the polymerization inhibitors;
d) recycling the acrylic acid stream to step a);
e) optionally, subjecting the stream comprising the acrylic acid oligomer obtained in step c) to a film evaporator to enable the separation of, on the one hand, a stream consisting essentially of acrylic acid dimers and trimers and, on the other hand, a stream consisting essentially of acrylic acid oligomers, corresponding to formula (I) in which n is an integer ranging from 2 to 10.