Curable epoxy resin composition, and fiber-reinforced composite material obtained using same
View Patent ↗Provided is a resin composition to be suitably used as the matrix resin of a fiber-reinforced composite material excellent in fatigue resistance. In the resin composition for a fiber-reinforced composite material, 50 mass % or more of an epoxy resin (A) includes a phenol novolac-type epoxy resin containing a compound represented by the following general formula (1) and a compound represented by the following general formula (2), and in gel permeation chromatography measurement, the phenol novolac-type epoxy resin contains a body corresponding to m=0 at a ratio of 75% by area or more and a body corresponding to m=1 at a ratio of 6% by area or less.
1. A resin composition for a fiber-reinforced composite material, comprising, as essential components:
an epoxy resin (A);
an acid anhydride-based curing agent (B);
an imidazole-based curing accelerator (C); and
a radical-polymerizable monomer (D) that is free of an acid group and that is liquid at 25° C. in addition to the epoxy resin (A), the acid anhydride-based curing agent (B), and the imidazole-based curing accelerator (C), wherein a blending amount of the radical-polymerizable monomer (D) is from 5 parts by mass to 25 parts by mass with respect to 100 parts by mass of a total amount of the component (A), the component (B), the component (C), and the component (D),
the resin composition capable of being applied to or impregnated into reinforcing fibers in a wet lay-up molding method, a pultrusion molding method, or a filament winding molding method without using a solvent,
wherein 50 mass % or more of the epoxy resin (A) comprises a phenol novolac-type epoxy resin containing a compound represented by the following general formula (1) and a compound represented by the following general formula (2),
wherein, in gel permeation chromatography measurement, the phenol novolac-type epoxy resin contains a body corresponding to m=0 of the compound represented by the following general formula (1) at a ratio of 75% by area or more and a body corresponding to m=1 thereof at a ratio of 6% by area or less, and
wherein the composition has a viscosity (25° C.) measured with an E-type viscometer in a range of from 50 mPa·s to 800 mPa·s, and the composition shows a viscosity increase ratio (25° C.) after a lapse of 6 hr of 200% or less:
where m represents an integer of 0 or more, and represents from 0 to 5;
where n represents an integer of 0 or more, and represents from 0 to 2.
2. A resin composition for a fiber-reinforced composite material according to claim 1 , wherein in the gel permeation chromatography measurement, the phenol novolac-type epoxy resin contains a body corresponding to n=1 of the compound represented by the general formula (2) at a ratio of 8% by area or more and 16% by area or less.
3. A fiber-reinforced composite material, which is obtained by blending the resin composition for a fiber-reinforced composite material of claim 1 with reinforcing fibers.
4. A fiber-reinforced composite material according to claim 3 , wherein a volume content of the reinforcing fibers is from 50% to 70%.
5. A molded body, which is obtained by molding the fiber-reinforced composite material of claim 3 or 4 by a wet lay-up molding method, a pultrusion molding method, or a filament winding molding method.