Polypropylene-polyethylene composition with improved flowability
View Patent ↗The invention is related to a composition of polypropylene and polyethylene, which contains specific compatibilizer and flow enhancer. Furthermore the present invention is also related to articles comprising the said composition and the use of said articles in packaging application.
1. A polymer composition comprising
a) 10 to 50 wt % of a polymer blend (A) comprising 30 to 70 wt % of polypropylene (A1) and 70 to 30 wt % of polyethylene (A2),
b) 47 to 90 wt % of a polypropylene (B) having a melt flow rate MFR2 (230° C.) measured according to ISO 1133 of not lower than 50 g/10 min, and
c) 3 to 25 wt % of a Compatibilizer (C) being a heterophasic polyolefin composition comprising 55 to 90 wt % of a matrix (C1) being a polypropylene and 45 to 10 wt % of an elastomer (C2) being a copolymer of ethylene and propylene or C4 to C10 alpha olefin with a glass transition temperature Tg measured according to ISO 6721-7 of below −25° C. and an intrinsic viscosity measured according to DIN ISO 1628/1 at 135° C. of at least 3.0 dl/g,
wherein the polymer composition has a melt flow rate MFR2 (230° C.) measured according to ISO 1133 of higher than 25 g/10 min.
2. The polymer composition according to claim 1 , wherein the heat deflection temperature (HDT) measured according to ISO 75B of said polymer composition is at least 5° C. higher than the HDT of the polymer blend (A).
3. The polymer composition according to claim 1 , wherein said polymer composition has
(i) a Charpy Notched Impact Strength measured according to ISO 179-1eA at 23° C. of at least 15% higher than the polymer blend (A), and at the same time
(ii) a Tensile Modulus measured according to ISO527-2 of at least 20% higher than the polymer blend (A).
4. The polymer composition according to claim 1 , wherein the polymer blend (A) is a recycled material, which is recovered from waste plastic material derived from at least one of post-consumer or post-industrial waste.
5. The polymer composition according to claim 1 , wherein the polypropylene (A1) has a melt flow rate MFR2 (230° C.) measured according to ISO 1133 of 0.1 to 30.0 g/10 min.
6. The polymer composition according to claim 1 , wherein the polypropylene (B) is a heterophasic polyolefin composition having a xylene cold soluble (XCS) content measured according to ISO 6427 in the range of 7.0 to 25.0 wt %.
7. The polymer composition according to claim 1 , wherein the intrinsic viscosity (IV) measured according to ISO 1268-1 (decalin) of the xylene cold soluble (XCS) fraction of the polypropylene (B) being a heterophasic polyolefin composition is below 3.5 dl/g.
8. The polymer composition according to claim 1 , wherein the melt flow rate MFR2 (230° C.) measured according to ISO 1133 of the xylene cold insoluble (XCI) fraction of the polypropylene (B) being a heterophasic polyolefin composition is in the range of 100.0 to 1500.0 g/10 min.
9. The polymer composition according to claim 1 , wherein the polypropylene (B) has at least one of:
(i) a total propylene content of 85.0 to 96.0 wt %, or
(ii) a propylene content in the xylene cold soluble (XCS) fraction of 45.0 to 75.0 wt %.
10. The polymer composition according to claim 1 , wherein the Compatibilizer (C) is selected from the group consisting of (i) an in-reactor blend obtained by a sequential polymerization process in at least two reactors, whereby first the matrix (C1) is produced and secondly a elastomer (C2) being a copolymer of ethylene and propylene is produced in the presence of the matrix (C1) and (ii) a mechanical blend of a matrix (C1) and a elastomer (C2) being a copolymer of ethylene and C4 to C10 alpha olefin.
11. The polymer composition according to claim 1 , wherein the matrix (C1) is selected from the group consisting of isotactic polypropylene homopolymer, predominantly isotactic polypropylene homopolymer, random copolymers of propylene with ethylene, C4 to C8 alpha-olefins, and combinations thereof, wherein the total comonomer content ranges from 0.05 to 10.0 wt %, whereby the polypropylenes have a density of from 0.895 to 0.920 g/cm 3 measured according to ISO 1183.
12. The polymer composition according to claim 1 , wherein the polymer composition may further comprise inorganic or organic reinforcements.
13. An article comprising a polymer composition according to claim 1 .
14. A process comprising forming packaging articles from the polymer composition according to claim 1 .