IP Library Granted Patent US 10,822,574
Granted Patent B2
US 10,822,574 · App. 15/765,558 · Granted Nov 3, 2020

Glucan fiber compositions for use in laundry care and fabric care

Inventors: Robert DiCosimo (Chadds Ford, PA); Qiong Cheng (Wilmington, DE); Rakesh Nambiar (West Chester, PA); Jayme L. Paullin (Claymont, DE); Mark S. Payne (Wilmington, DE); Zheng You (Hoffman Estates, IL)
Assignee: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
C11D3/225C08B37/0009C08L5/00C11D3/222C11D3/386C11D3/38645C11D7/268C11D11/0017
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Quick Facts
Patent No.
US 10,822,574
App. No.
15/765,558
Granted
Nov 3, 2020
Kind
B2
Abstract

An enzymatically produced α-glucan oligomer/polymer compositions is provided. The enzymatically produced α-glucan oligomer/polymers can be derivatized into α-glucan ether compounds. The α-glucan oligomers/polymers and the corresponding α-glucan ethers are cellulose and/or protease resistant, making them suitable for use in fabric care and laundry care applications. Methods for the production and use of the present compositions are also provided.

Claims (22)

1. A fabric care or laundry care composition comprising:

(a) a soluble α-glucan composition, wherein the glycosidic linkages of the α-glucan composition consist of:

(i) 25-35% α-(1,3) glycosidic linkages,

(ii) 55-75% α-(1,6) glycosidic linkages, and

(iii) 5-15% α-(1,3,6) glycosidic linkages,

wherein the % glycosidic linkages are determined by methylation analysis;

wherein the α-glucan composition has

(iv) a weight average molecular weight of less than 5000 Daltons,

(v) a viscosity of less than 0.25 Pascal second (Pa·s) at 12 wt % in water at 20° C.,

(vi) a solubility of at least 20% (w/w) in water at 25° C., and

(vii) a polydispersity index of less than 5; and

(b) at least one additional fabric care or laundry care ingredient.

2. The fabric care or laundry care composition of claim 1 , wherein the additional ingredient is at least one cellulase.

3. The fabric care or laundry care composition of claim 1 , wherein the additional ingredient is at least one protease.

4. The fabric care or laundry care composition of claim 1 , wherein the fabric care or laundry care composition comprises 0.01 to 90 wt % of the soluble α-glucan composition.

5. The fabric care or laundry care composition of claim 1 , wherein the at least one additional ingredient comprises at least one of surfactants selected from anionic surfactants, nonionic surfactants, cationic surfactants, or zwitterionic surfactants; enzymes selected from proteases, cellulases, polyesterases, amylases, cutinases, lipases, pectate lyases, perhydrolases, xylanases, peroxidases, or laccases; detergent builders, complexing agents, polymers, soil release polymers, surfactancy-boosting polymers, bleaching systems, bleach activators, bleaching catalysts, fabric conditioners, clays, foam boosters, suds suppressors, anti-corrosion agents, soil-suspending agents, anti-soil redeposition agents, dyes, bactericides, tarnish inhibiters, optical brighteners, perfumes, saturated or unsaturated fatty acids, dye transfer inhibiting agents, chelating agents, hueing dyes, calcium and magnesium cations, visual signaling ingredients, anti-foam, structurants, thickeners, anti-caking agents, starch, sand, or gelling agents.

6. The fabric care or laundry care composition of claim 1 , wherein the composition is in the form of a liquid, a gel, a powder, a hydrocolloid, an aqueous solution, granules, tablets, capsules, single compartment sachets, or multi-compartment sachets.

7. The fabric care or laundry care composition of claim 1 , wherein the α-glucan composition is cellulase resistant, protease resistant, or amylase resistant.

8. A method of treating an article of clothing, textile, or fabric, said method comprising:

(a) providing a fabric care or laundry care composition according to claim 1 ;

(b) contacting, under suitable conditions, the composition of (a) with a fabric, textile, or article of clothing, whereby the fabric, textile, or article of clothing is treated by the composition; and

(c) optionally, rinsing the treated fabric, textile, or article of clothing of (b).

Assignments (6)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 28, 2020
From: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
To: NUTRITION & BIOSCIENCES USA 4, INC.
Reel/Frame 055028/0496 →
CORRECTIVE ASSIGNMENT TO CORRECT THE RAKESH HAMBIAR PREVIOUSLY RECORDED ON REEL 053784 FRAME 0208. ASSIGNOR(S) HEREBY CONFIRMS THE RAKESH NAMBIAR. Recorded Sep 17, 2020
From: NAMBIAR, RAKESH
To: E I DUPONT DE NEMOURS AND COMPANY
Reel/Frame 053800/0059 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 16, 2020
From: DICOSIMO, ROBERT; CHENG, QIONG; HAMBIAR, RAKESH; PAYNE, MARK S.; YU, ZHENG
To: E I DUPONT DE NEMOURS AND COMPANY
Reel/Frame 053784/0208 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 25, 2020
From: PAULLIN, JAYME L.
To: E I DU PONT DE NEMOURS AND COMPANY
Reel/Frame 051621/0482 →
CORRECTIVE ASSIGNMENT TO CORRECT THE ENTITY TYPE PREVIOUSLY RECORDED AT REEL: 049879 FRAME: 0043. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Sep 6, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 050300/0408 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2019
From: E. I. DU PONT DE NEMOURS AND COMPANY
To: DUPONT INDUSTRIAL BIOSCIENCES USA, LLC
Reel/Frame 049879/0043 →
Continuity (2)
Provisional Application 62255217 · Nov 13, 2015
Related Publication 20190136153A1 · May 9, 2019