Device architecture
The present invention relates to an optoelectronic device comprising: (a) a substrate comprising at least one first electrode, which at least one first electrode comprises a first electrode material, and at least one second electrode, which at least one second electrode comprises a second electrode material; and (b) a photoactive material disposed on the substrate, which photoactive material is in contact with the at least one first electrode and the at least one second electrode, wherein the substrate comprises: a layer of the first electrode material; and, disposed on the layer of the first electrode material, a layer of an insulating material, which layer of an insulating material partially covers the layer of the first electrode material; and, disposed on the layer of the insulating material, the second electrode material, and wherein the photoactive material comprises a crystalline compound, which crystalline compound comprises: one or more first cations selected from metal or metalloid cations; one or more second cations selected from Cs + ′RB + , K + , NH 4 + and organic cations; and one or more halide or chalcogenide anions. A substrate comprising a first and second electrode and processes are also described.
1. A process for producing a substrate comprising at least one first electrode comprising a first electrode material, and at least one second electrode comprising a second electrode material;
wherein the substrate comprises:
a layer of the first electrode material; and,
disposed on the layer of the first electrode material, a layer of an insulating material, wherein the layer of the insulating material partially covers the layer of the first electrode material; and,
disposed on the layer of the insulating material, the second electrode material, and wherein the process comprises:
(i) providing the layer of the first electrode material disposed on a layer of a base material;
(ii) disposing on the layer of the first electrode material a layer of a resist;
(iii) performing a lithography step to define a second electrode pattern on the layer of the first electrode material;
(iv) then depositing the layer of the insulating material on the layer of the resist with the second electrode pattern defined thereon;
(v) disposing on the layer of the insulating material a layer of the second electrode material; and
(vi) removing the resist and said insulating material and said second electrode material disposed on the resist.
2. A process according to claim 1 , wherein the lithography step comprises an e-beam lithography step, an optical lithography step or a nanocontact printing step.
3. A process according to claim 1 , wherein the resist is removed by exposing the resist to a solvent.
4. A process according to claim 1 , wherein the process further comprises, between steps (iv) and (v), a step of disposing a layer of an adhesion material on the layer of the insulating material.
5. A process according to claim 1 , wherein:
step (v) comprises: (v-a) disposing, on the layer of the insulating material, a layer of a metal, and the process further comprises step (vii-a) of annealing the substrate to form a layer of metal oxide on the layer of the metal; or
step (v) comprises (v-b) disposing, on the layer of the insulating material, a layer of a metal, and disposing, on the layer of the metal, a layer of a p-type semiconductor, and the process further comprises step (vii-b) of treating the substrate with a compound suitable for forming a self-assembled monolayer on exposed surfaces of the layer of the metal.
6. A process for producing an optoelectronic device, which process comprises:
(a) producing a substrate comprising at least one first electrode comprising a first electrode material, and at least one second electrode comprising a second electrode material;
wherein the substrate comprises:
a layer of the first electrode material; and,
disposed on the layer of the first electrode material, a layer of an insulating material, wherein the layer of an insulating material partially covers the layer of the first electrode material; and,
disposed on the layer of the insulating material, the second electrode material, wherein the substrate is produced by a process comprising:
(i) providing the layer of the first electrode material disposed on a layer of a base material;
(ii) disposing on the layer of the first electrode material a layer of a resist;
(iii) performing a lithography step to define a second electrode pattern on the layer of the first electrode material;
(iv) then depositing the layer of the insulating material on the layer of the resist with the second electrode pattern defined thereon;
(v) disposing on the layer of the insulating material a layer of the second electrode material; and
(vi) removing the resist and said insulating material and said second electrode material disposed on the resist; and
(b) disposing a layer of a photoactive material on the substrate.
7. A process for producing an optoelectronic device accordingly to claim 6 , wherein the optoelectronic device is a photovoltaic device.