Thermally conductive polymer resin composition based on styrenics with low density
Thermally conductive polymer (TCP) resin compositions are described, comprising components (X) and (Y): 90 to 99.9% component (X) comprising components (I) and (II): 60 to 85% matrix polymer (I) comprising styrenic polymers (F) selected from: ABS resins, ASA resins, and elastomeric block copolymers of the structure (S—(B/S)) n —S; 15 to 40% thermally conductive filler material (II) (D 50 1 to 200 μηη), consisting of a ceramic material and/or graphite; 0.1 to 10% chemical foaming agent (Y). Shaped articles made thereof can be used for automotive applications, as a heat sink for high performance electronics, LED sockets or electrical and electronic housings.
1. A thermally conductive polymer (TCP) resin composition comprising components (X) and (Y):
90 to 99.9% by weight of component (X) which is a composition comprising components (I) and (II):
60 to 85% by volume of at least one matrix polymer (I) as component (I) comprising styrenic polymers (I′) selected from the group consisting of: ABS (acrylonitrile-butadiene-styrene) resins, ASA (acrylonitrile-styrene-acrylate) resins, and elastomeric block copolymers; wherein the elastomeric block copolymers have a structure
(S—(B/S)) n —S,
where S is a vinylaromatic block forming a hard phase, (B/S) is a random copolymer block of vinylaromatic monomer and of a conjugated diene forming a soft phase, and n are natural numbers from 1 to 10, wherein the elastomeric block copolymer has a monomer composition comprising from 25 to 60% by weight (based on the elastomeric block copolymer) of diene and from 75 to 40% by weight (based on the elastomeric block copolymer) of vinylaromatic compound, the glass transition temperature Tg of block S is above 25° C. and that of block (B/S) is below 25° C., wherein the proportions of the soft phase and the hard phase total 100% by weight and the proportion of the hard phase in the elastomeric block copolymers is from 5 to 40% by weight and the relative amount of 1,2 linkages of the diene, based on the sum of 1,2- and 1,4-cis/trans-linkages, is less than 15%;
15 to 40% by volume of at least one thermally conductive filler material (II) as component (II) having a weight median particle diameter (D 50 ) of from 1 to 200 μm,
which consists of at least one ceramic material and/or graphite;
wherein components (I) and (II) total 100% by volume;
0.1 to 10% by weight of at least one chemical foaming agent as component (Y);
wherein components (X) and (Y) total 100% by weight; and
the thermal conductivity K is more than 0.4 W/m⋅K.
2. The thermally conductive polymer (TCP) resin composition according to claim 1 , wherein the matrix polymer (I) comprises at least one further thermoplastic polymer (I″) selected from the group consisting of: polycarbonates and polyamides.
3. The TCP resin composition according to claim 1 , wherein the matrix polymer (I) is selected from the group consisting of: ABS resins, ASA resins, elastomeric block copolymers of the structure (A-(B/A)) n -A, blend of ABS resins with polycarbonate, blend of ABS resins with polyamide, blend of ASA resins with polycarbonate, and blend of ASA resins with polyamide.
4. The TCP resin composition according to claim 1 , wherein component (X) comprises 65 to 80% by volume of component (I) and 20 to 35% by volume of component (II).
5. The TCP resin composition according to claim 1 , comprising 95 to 99.5% by weight of component (X) and 0.5 to 5% of component (Y).
6. The TCP resin composition according to claim 1 , wherein the thermally conductive filler material (II) consists of boron nitride, aluminosilicate, and/or graphite.
7. The TCP resin composition according to claim 1 , wherein the chemical foaming agent is at least one compound selected from the group consisting of: Sodium carbonate, Sodium hydrogen carbonate, Magnesium carbonate, Stearic acid, Sodium stearate, Potassium stearate, Magnesium stearate, Zinc carbonate, and Citric acid derivatives.
8. The TCP resin composition according to claim 1 , wherein the thermally conductive filler material (II) is boron nitride.
9. The TCP resin composition according to claim 1 , wherein the thermally conductive filler material (II) is a mixture of boron nitride (II-1) and aluminosilicate (II-2).
10. The TCP resin composition according to claim 1 , wherein the matrix polymer (I) is an ABS resin.
11. The TCP resin composition according to claim 1 , wherein the elastomeric block copolymer (I) is a linear styrene-butadiene block copolymer of the general structure S—(B/S)—S having, situated between the two styrene S blocks, one or more (B/S)-random blocks having random styrene/butadiene distribution.