IP Library Granted Patent US 10,919,198
Granted Patent B2
US 10,919,198 · App. 15/769,778 · Granted Feb 16, 2021

Production of complex hollow foam or sandwich structures by means of a mold core

Inventors: Arnim Kraatz (Darmstadt, DE); Denis Holleyn (Hofheim am Taunus, DE)
Assignee: Evonik Operations GmbH
B29C44/14B29C33/485B29C44/1252B29C44/1266B29C44/445B29C33/3821B29C33/54B29C44/129B29C44/1233B29C44/1271B29K2023/06B29K2023/12B29K2027/06B29K2067/003B29K2075/00B29K2079/08B29K2105/048B29K2671/00B29K2705/00B29K2709/08B29K2995/0063B29L2031/085B29L2031/30B29L2031/44B29L2031/52Y02P70/50
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Quick Facts
Patent No.
US 10,919,198
App. No.
15/769,778
Granted
Feb 16, 2021
Kind
B2
Abstract

The invention relates to a process for producing complex, mould-foamed rigid foam materials, more particularly of poly(meth)acrylimide (P(M)I) cores, preferably of polymethacrylimide (PMI) cores, which may be employed, for example, in carmaking or aircraft construction. A feature of the process is that through use of a particulate core during foam, it is possible to achieve an additional weight saving relative to foam materials or sandwich materials of the prior art.

Claims (49)

1. A process for producing at least one complex rigid foam core, the process comprising:

producing a filling core, filled with particles and consisting of a foil,

inserting the filling core into a mold and then closing the mold,

introducing matrix particles into a cavity between the filling core and an inside wall of the mold,

foaming the matrix particles, opening the mold, and withdrawing a rigid foam core,

optionally opening the foil at an accessible former contact region from the inserting, and

withdrawing the particles from the rigid foam core,

wherein the matrix particles are pre-foamed P(M)I particles having a particle size between 1.0 and 25.0 mm or are P(M)I suspension polymers having a particle size between 0.1 and 1.0 mm.

2. The process according to claim 1 ,

wherein the inserting comprises inserting the filling core such that the filling core contacts between 0.5 and 10 area percent of the inside wall of the mold.

3. The process according to claim 1 ,

wherein the inserting comprises inserting the filling core such that the filling core after the foaming is entirely surrounded by foam, and

in the optionally opening, the foam is partly drilled open or cut open for withdrawal of the particles in the withdrawing.

4. The process according to claim 1 ,

wherein in the inserting, the filling core is inserted such that the filling core contacts between 0.5 and 10 area percent of the inside wall of the mold, which is sealed with a readily removable means, and

the readily removable means is removed in the optionally opening.

5. The process according to claim 1 ,

wherein the particles comprise sand, polymer particles which are solid and stable at a foaming temperature, metal particles or glass beads.

6. The process according to claim 1 ,

wherein the foil is a PTFE, PEEK or PPSU foil or is a silicone-containing paper or a silicone-containing foil, and

the foil is optionally extracted from the rigid foam core after the withdrawing.

7. The process according to claim 1 ,

wherein in the producing, the filling core is tightly packed and shaped by pressing and/or by applying a subatmospheric pressure.

8. The process according to claim 1 ,

wherein the filling core is open at one location where the filling core is placed hanging into the mold.

9. The process according to claim 1 ,

wherein the inside of the mold is lined before the inserting or the introducing, with a material forming a later outer layer.

10. The process according to claim 1 ,

wherein the outside of the filling core is lined before the inserting or the introducing, with a material forming a later outer layer.

11. The process according to claim 1 ,

wherein in the inserting, the filling core is inserted such that the filling core contacts the inside wall of the mold at not less than two locations, and

in the withdrawing, the particles are blown out of the cavity with compressed air.

12. The process according to claim 1 ,

wherein in the introducing, the matrix particles are introduced in preheated form under pressure, and

the foaming takes place at a foaming temperature by lowering of a pressure.

13. The process according to claim 1 ,

wherein in the introducing, the matrix particles are introduced into the mold by suction, blowing, or both suction and blowing.

14. The process according to claim 1 ,

wherein the cavity is filled in the introducing, to a filling level of between 50% and 100% with matrix particles.

15. The process according to claim 1 ,

wherein before the introducing, the matrix particles are stored in a reservoir container at a temperature which is less than 50° C. below a foaming temperature and at a pressure which is at least 1 bar above atmospheric pressure, and

in the introducing, the matrix particles are introduced batchwise into the mold, a connection between the reservoir container and the mold being closed after each batchwise introduction.

16. A foam body or sandwich material, comprising:

a foam core,

wherein the foam body or sandwich material has a cavity connected at not less than one location to a surface of the foam core,

between the foam core and the cavity, there is a foil, a cured prepreg or organopanel, or nothing at all, and

the foam core is obtained by the process according to claim 1 .

17. The process according to claim 9 , wherein the material is a prepreg or an organopanel.

18. The process according to claim 10 , wherein the material is a prepreg or an organopanel.

Assignments (4)
CHANGE OF NAME Recorded Feb 11, 2020
From: EVONIK ROEHM GMBH
To: ROEHM GMBH
Reel/Frame 051893/0671 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 11, 2020
From: ROEHM GMBH
To: EVONIK DEGUSSA GMBH
Reel/Frame 051893/0727 →
CHANGE OF NAME Recorded Feb 11, 2020
From: EVONIK DEGUSSA GMBH
To: EVONIK OPERATIONS GMBH
Reel/Frame 051894/0001 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 20, 2018
From: KRAATZ, ARNIM; HOLLEYN, DENIS
To: EVONIK ROEHM GMBH
Reel/Frame 045595/0354 →