Coating compositions comprising monoallophanates based on alkoxysilane alkyl isocyanates

1. A coating composition, comprising:

A) at least one allophanate-containing compound having the formula (1):

wherein

R, R 1 -R 6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and

m and n are each independently 0-2,

B) at least one binder,

C) optionally at least one aliphatic or cycloaliphatic polyisocyanate having an NCO functionality of at least 2,

D) optionally at least one catalyst,

E) optionally at least one auxiliary and/or additive,

F) optionally at least one solvent.

2. The coating composition according to claim 1 , comprising:

A) 10-99 wt % of at least one allophanate-containing compound having the formula (1):

wherein

R, R 1 -R 6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and

m and n are each independently 0-2,

B) 1-90 wt % of at least one binder,

C) 0-50 wt % of at least one aliphatic or cycloaliphatic polyisocyanate having an NCO functionality of at least 2,

D) 0-5 wt % of at least one catalyst,

E) 0-50 wt % of at least one auxiliary and/or additive,

F) optionally at least one solvent,

where components A)-F) add up to 100 wt. %.

3. The coating composition according to claim 1 , wherein m and n are each 0,

R 1 and R 5 are each methyl or ethyl, and

R 2 and R 4 are each methylene or propylene.

4. The coating composition according to claim 1 , wherein

m and n are each 0,

R 1 =R 5 =methyl and R 2 =R 4 =propylene.

5. The coating composition according to claim 1 , wherein binder B) comprises at least one member selected from the group consisting of a hydroxyl-containing binder and an amine-containing binder.

6. The coating composition according to claim 1 , wherein binder B) comprises at least one member selected from the group consisting of a hydroxyl-containing polyester having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol, a hydroxyl-containing polyether having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol, a hydroxyl-containing polyacrylate having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol, a hydroxyl-containing polycarbonate having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol, and a hydroxyl-containing polyurethane having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol.

7. The coating composition according to claim 1 , wherein binder B) comprises at least one member selected from the group consisting of a hydroxyl-containing polyester having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol and a hydroxyl-containing polyacrylate having an OH number of 20 to 500 mg KOH/g and a mean molar mass of 250 to 6000 g/mol.

8. The coating composition according to claim 1 , wherein binder B) comprises at least one adduct of an isocyanatotrialkoxysilane and a mono- or polyhydric alcohol.

9. The coating composition according to claim 1 , wherein binder B) comprises at least one member selected from the group consisting of a derivative of a hydroxyl-containing polyether with isocyanatopropyltrialkoxysilane, a derivative of a polyester with isocyanatopropyltrialkoxysilane, a derivative of a polycarbonatediol with isocyanatopropyltrialkoxysilane, and a derivative of a polyacrylate with isocyanatopropyltrialkoxysilane.

10. The coating composition according to claim 1 , wherein binder B) comprises at least one member selected from the group consisting of aminopropyltriethoxysilane, aminomethyltrimethoxysilane, and aminomethyltriethoxysilane.

11. The coating composition according to claim 1 , wherein component C) is present and is at least one member selected from the group consisting of isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), diisocyanatodicyclohexylmethane (H12MDI), 2-methylpentane diisocyanate (MPDI), 2,2,4-trimethylhexamethylene diisocyanate/2,4,4-trimethylhexamethylene diisocyanate (TMDI), and norbornane diisocyanate (NBDI).

12. The coating composition according to claim 1 , wherein component C) is present and is at least one member selected from the group consisting of isophorone diisocyanate (IPDI), hexamethylene diisocyanate (HDI), 2,2,4-trimethylhexamethylene diisocyanate/2,4,4-trimethylhexamethylene diisocyanate (TMDI) and diisocyanatodicyclohexylmethane (H12MDI).

13. The coating composition according to claim 1 , wherein component C) is present and comprises at least one isocyanurate.

14. The coating composition according to claim 1 , wherein component D) is present and comprises at least one member selected from the group consisting of a metal carboxylate, a tert-amine, an amidine, a guanidine, a quaternary ammonium salt, a tetraalkylammonium salt, a quaternary phosphonium salt, a metal acetylacetonate, a quaternary ammonium acetylacetonate, and a quaternary phosphonium acetylacetonate.

15. The coating composition according to claim 1 , wherein component E) is present and comprises at least one member selected from the group consisting of a stabilizer, a light stabilizer, a catalyst, an additional crosslinker, a filler, a pigment, a levelling agent, and a rheology aid.

16. A process for producing the coating composition according to claim 1 , the process comprising:

mixing components A) and B), and, when present, any or all of components C), D), E), and F).

17. A paint composition, an adhesive composition, or a metal coating composition, which comprises:

the coating composition according to claim 1 .