Separator and electrochemical device including the same
Disclosed are a separator and an electrochemical device including the same. The separator includes: a porous substrate having a plurality of pores; and a pair of porous coating layers formed on both surfaces of the porous substrate, and including a plurality of inorganic particles and a binder polymer disposed partially or totally on the surface of the inorganic particles to connect and fix the inorganic particles with each other, wherein the amount of the binder polymer and the amount of the inorganic particles in one porous coating layer are the same as those in the other porous coating layer, the binder polymer is used in an amount of 5-40 wt % based on the total weight of the porous coating layer, the inorganic particles include boehmite particles and non-boehmite particles, and the boehmite particles and the binder polymer are used at a weight ratio of 1:1-1:5.
1. A separator comprising:
a porous substrate having a plurality of pores; and
a pair of porous coating layers formed on both surfaces of the porous substrate, and including a plurality of inorganic particles and a binder polymer disposed partially or totally on the surface of the inorganic particles to connect and fix the inorganic particles with each other,
wherein the amount of the binder polymer and the amount of the inorganic particles in one porous coating layer are the same as those in the other porous coating layer,
the binder polymer is used in an amount of 5-40 wt % based on the total weight of the porous coating layer,
the inorganic particles include boehmite particles and non-boehmite particles,
wherein a weight % of non-boehmite particles to boehmite particles is 40:20 to 93.3:1.7, and
the boehmite particles and the binder polymer are used at a weight ratio of 1:2 to 1:3,
wherein the binder polymer is polyvinylidene fluoride-co-hexafluoropropylene,
wherein the non-boehmite particles are Al 2 O 3 , and
wherein the separator comprising the pair of porous coating layers has a thickness of 13.1-13.7 μm.
2. The separator according to claim 1 , wherein the boehmite particles have an average particle diameter 0.01-0.9 times higher than the average particle diameter of the non-boehmite particles.
3. The separator according to claim 1 , wherein the non-boehmite particles have an average particle diameter of 0.5-3 μm.
4. The separator according to claim 1 , wherein the boehmite particles have an average particle diameter of 0.05-0.4 μm.
5. The separator according to claim 1 , wherein the porous substrate is a polyolefin-based porous substrate.
6. The separator according to claim 5 , wherein the polyolefin-based porous substrate comprises any one polymer selected from the group consisting of polyethylene, polypropylene, polybutylene and polypentene, or a combination thereof.
7. The separator according to claim 1 , wherein the porous substrate has a porosity of 40%.
8. An electrochemical device comprising a cathode, an anode and a separator interposed between the cathode and the anode, wherein the separator is the separator as defined in claim 1 .
9. The electrochemical device according to claim 8 , which is a lithium secondary battery.