Postponed onset of quicklime hydration
View Patent ↗The present invention provides compositions and methods relative to controlling hydration onset of an alkaline earth metal oxide such as calcium oxide, comprising heating an inorganic alkaline earth metal oxide to sub-calcination temperatures in the presence of organic material comprising a carbohydrate, an amino-carboxylic acid, a hydroxycarboxylic acid, or a mixture thereof. Preferred treated particles comprise at least 40% and more preferably at least 80% by dry weight calcium oxide which is heated in the presence of ascorbic acid and a starch. Treated particles of the present invention manifest an unexpected, surprising hydration induction postponement behavior as demonstrated through calorimetric testing.
1. A composition comprising: treated alkaline earth metal oxide particles treated by heating precursor alkaline earth metal oxide particles comprising 40-100 percent by total dry weight of calcium oxide, magnesium oxide, or mixture thereof, at an average temperature within 200° C.-700° C., for a period of 20-300 minutes, in the presence of an organic material comprising (i) a starch, (ii) an amino-carboxylic acid selected from the group consisting of aspartic acid, glutamic acid, glycine, alanine, phenylalanine, methionine, serine, and threonine, or (iii) a mixture of (i) and (ii).
2. The composition of claim 1 wherein the treated alkaline earth metal oxide particles comprise at least 50 percent by total dry weight of calcium oxide based on total dry weight of the treated particles; and the treated particles are treated by heating to 250° C.-500° C. for 20-200 minutes.
3. The composition of claim 1 wherein the treated alkaline earth metal oxide particles comprise at least 80-100 percent by total dry weight of calcium oxide based on total dry weight of the treated particles; and the treated particles are treated by heating to 250° C.-500° C. for 20-200 minutes.
4. The composition of claim 1 wherein the treated precursor particles are heated in the presence of starch.
5. The composition of claim 1 wherein the treated precursor particles are heated in the presence of amino-carboxylic acid.
6. The composition of claim 5 wherein the precursor particles are heated in the presence of aspartic acid.
7. The composition of claim 6 wherein at least 80 percent by weight of the aspartic acid is L-aspartic acid.
8. The composition of claim 1 wherein the precursor particles are heated in the additional presence of a hydroxycarboxylic acid.
9. The composition of claim 8 wherein the hydroxycarboxylic acid is citric acid.
10. The composition of claim 1 wherein the precursor particles are heated in the presence of aspartic acid and starch.
11. The composition of claim 1 wherein the starch is a pregelatinized starch selected from a refined starch obtained from corn, tapioca, wheat, rice, potato, sweet potato, sago, beans, and mixtures thereof.
12. The composition of claim 1 further comprising a hydratable cementitious binder.
13. The composition of claim 12 further comprising an aggregate.
14. The composition of claim 13 wherein the composition, when mixed with water, forms a paste or slurry of cementitious mortar, concrete, or shotcrete.
15. A method for modifying a cementitious composition comprising: mixing together a cementitious binder and composition according to claim 1 .
16. The method of claim 15 wherein the cementitious binder and the composition are mixed together as dry powder.
17. The method of claim 16 wherein the dry powder is mixed into a cementitious slurry and then pumped through a hose to a location where the cementitious slurry is placed and hardened.
18. A composition comprising: treated alkaline earth metal oxide particles treated by heating precursor alkaline earth metal oxide particles comprising calcium oxide, magnesium oxide, or mixture thereof in the amount of 70-100 percent by dry weight based on the total inorganic portion of the particles, at an average temperature within 250° C.-500° C., for a period of 20-200 minutes, in the presence of an organic material comprising aspartic acid and a starch.