Process for the extraction of metal pollutants from treated cellulosic biomass
The present invention relates to a process for extracting oxidised metal pollutants from treated cellulosic or lignocellulosic biomass to recover the metal. The treatment also generates a cellulosic or lignocellulosic biomass which can to be used as a feedstock for biofuel, for making cellulose containing materials, and provides a source of other renewable chemicals.
1. A process for the extraction of metal pollutants from treated lignocellulosic biomass, the process comprising
(a) contacting the treated lignocellulosic biomass with an ionic liquid, said ionic liquid comprising an anion and an organic protic cation selected from 1-butylimidazolium ([HBIM] + ) and 1-methylimidazolium ([HMIM] + ), wherein the contacting produces a cellulose-rich solid material and a liquid phase, wherein the liquid phase comprises a hemicellulose fraction, a lignin fraction, and metal pollutants.
2. The process of claim 1 wherein the anion is selected from C 1-20 alkyl sulfate [Alkyl SO 4 ] − , Chloride [Cl] − , Bromide [Br] − , hydrogen sulfate [HSO 4 ] − , hydrogen sulfite [HSO 3 ] − , trifluoromethanesulfonate [OTf] − and acetate [OAc] − .
3. The process of claim 1 wherein the ionic liquid is selected from [HBIM][HSO 4 ], [HMIM][Cl], [HMIM][HSO 4 ], or a mixture thereof.
4. The process of claim 1 wherein the organic protic cation is derived from its' conjugate base, and wherein the ionic liquid comprises at least 5% molar excess of the conjugate base.
5. The process of claim 1 wherein the ionic liquid is contacted with the biomass in the form of a composition comprising the ionic liquid and 10-40% v/v water.
6. The process of claim 1 , further comprising
(b) separating the cellulose containing solid residue obtained from the ionic liquid.
7. The process of claim 6 further comprising
(c(i)) washing the solid residue at least once with the ionic liquid or an organic solvent miscible with the ionic liquid.
8. The process of claim 7 further comprising
(c(ii)) separating the solid residue from the ionic liquid or organic solvent and optionally adding the ionic liquid or organic solvent to the ionic liquid obtained in (b).
9. The process of claim 6 further comprising
(d) adding an anti-solvent to the ionic liquid obtained in (b) to precipitate the lignin.
10. The process of claim 6 further comprising removing water from the ionic liquid, after step (b).
11. The process of claim 1 further comprising electrodeposition of the metal pollutant from the ionic liquid.
12. The process of claim 11 wherein after the electrodeposition, the ionic liquid is re-used in step (a).
13. The process of claim 1 further comprising saccharification of the cellulose containing solid residue obtained in step (a) to obtain glucose.
14. The process of claim 1 wherein the ionic liquid is contacted with the biomass in the form of a composition comprising the ionic liquid and 0.01-20% molar excess acid.
15. The process of claim 14 wherein the composition comprises 1-5% molar excess acid.
16. The process of claim 1 , wherein the contacting dissolves hemicellulose of the treated lignocellulosic biomass in the ionic liquid.
17. The process of claim 16 , wherein a majority of the cellulose of the treated lignocellulosic biomass remains solid.
18. The process of claim 1 , wherein the contacting is carried out for a time in the range of 5 min-22 hours.
19. The process of claim 1 , wherein the contacting is carried out for a time in the range of 5 min-8 hours.
20. The process of claim 1 , wherein the ionic liquid is contacted with the biomass in the form of a composition comprising the ionic liquid and water.
21. The process of claim 9 further comprising removing water from the ionic liquid after step (d).
22. The process of claim 7 further comprising electrodeposition of the metal pollutant from the ionic liquid, wherein after the electrodeposition, the ionic liquid is re-used in step (c(i)).
23. The process of claim 6 further comprising saccharification of the cellulose containing solid residue obtained in step (b) to obtain glucose.
24. The process of claim 8 further comprising saccharification of the cellulose containing solid residue obtained in step (c(ii)) to obtain glucose.