Packaging bag, and method for storing melt-processable polyvinyl alcohol resin with the use of the packaging bag
A packaging bag for packaging a melt-processable polyvinyl alcohol resin is formed from a film having a methanol vapor transmission rate of 0.5 to 1000 g/m 2 ·day. A method of storing a melt-processable polyvinyl alcohol resin includes the step of sealingly packaging melt-processable polyvinyl alcohol resin particles with the use of the packaging bag formed from the aforementioned film. Where the melt-processable polyvinyl alcohol resin is packaged with the use of the packaging bag, therefore, an organic solvent remaining in the packaged polyvinyl alcohol resin can be released in the form of vapor to the outside through the packaging bag to dissipate, whereby the resulting polyvinyl alcohol resin has a reduced organic solvent concentration after storage thereof in the packaging bag. As a result, the melt-processable polyvinyl alcohol resin is improved in forming stability.
1. A method of storing a melt-processable polyvinyl alcohol resin comprising:
providing a packaging bag comprising a film having
a methanol vapor transmission rate of 0.5 to 1000 g/m 2 ·day measured in conformity with Testing Methods for Determination of Water Vapor Transmission Rate of Moisture-Proof Packaging Materials—Dish Method specified in JIS Z0208,
a water vapor transmission rate of not higher than 1000 g/m 2 ·day measured at 40° C. at 90% RH in conformity with JIS Z0208, and
a thickness of 1 to 500 μm; and
sealingly packaging melt-processable polyvinyl alcohol resin particles in the packaging bag, the melt-processable polyvinyl alcohol resin particles comprising residual organic solvent;
wherein a material for the film is at least one selected from the group consisting of high-density polyethylene, medium-density polyethylene, low-density polyethylene, polypropylene, and polyester, and
wherein the packaging bag is capable of releasing the residual organic solvent evaporated from the melt-processable polyvinyl alcohol resin during its storage in the packaging bag.
2. The method according to claim 1 , wherein the melt-processable polyvinyl alcohol resin is a polyvinyl alcohol resin having a primary hydroxyl group-containing structural unit at its side chain.
3. The method according to claim 1 , wherein the structural unit having the primary hydroxyl group-containing structural unit at the side chain is a structural unit having a 1,2-diol structure at the side chain.
4. The method according to claim 1 , wherein the film has a multilayer structure including
a base layer,
a methanol vapor permeable film layer, and
a protective layer.
5. The method of claim 1 , wherein the packaging bag has a thickness of 10 to 2000 μm.
6. The method of claim 4 , wherein at least one of the base layer and the protective layer is craft paper.
7. The method of claim 1 , wherein the content of organic solvent in the melt-processable polyvinyl alcohol resin particles is 0.1 to 10 wt %.