Flexible vulcanized joint between two electric power cables and process for producing said joint
A process for producing a flexible vulcanized joint between two electric power cables includes the steps of: producing an exposed conductor joint between each end of the two cable ends to be joined; producing an inner semi-conducting layer thereby radially surrounding and covering the exposed conductor joint; winding an insulation tape including an organic peroxide around the inner semi-conducting layer thereby radially surrounding and covering the inner semi-conducting layer; curing the insulation tape to produce an insulation layer; and producing an outer semi-conducting layer thereby radially surrounding and covering the insulation layer. The step of winding the insulation tape around the inner semi-conductor layer is performed under an oxygen-free atmosphere. The present invention also provides a flexible vulcanized joint produced by this process, and an electric power cable including such a joint.
1. A process for producing a flexible vulcanized joint between two electric power cables, each cable having a metal conductor and an electric insulation system radially surrounding the conductor, the electric insulation system having an inner semi-conducting layer, an insulation layer, and an outer semi -conducting layer, the process comprising the following steps:
i) Producing an exposed conductor joint between each end of the two cable ends to be joined;
ii) Producing an inner semi-conducting layer that radially surrounds and covers the exposed conductor joint;
iii) Winding an insulation tape including an organic peroxide around the inner semi-conducting layer thereby radially surrounding and covering the inner semi-conducting layer;
iv) Curing the insulation tape and thereby producing an insulation layer; and
v) Producing an outer semi-conducting layer that radially surrounds and covers the insulation layer;
wherein the step iii) of winding the insulation tape around the inner semi -conductor layer is performed under an oxygen-free atmosphere.
2. The process according to claim 1 , wherein the oxygen -free atmosphere includes at least one of nitrogen, carbon dioxide, or a noble gas.
3. The process according to claim 1 , wherein the step iii) of winding the insulation tape around the inner semi-conducting layer is performed in a glovebox at a gas pressure in excess of an ambient atmospheric pressure.
4. The process according to claim 1 , wherein the insulation tape comprises a polyolefin.
5. The process according to claim 1 , wherein the organic peroxide used in step iii) for producing the insulation layer is selected from one of dicumyl peroxide, bis(t-butylperoxyisopropyl)benzene, t-butyl cumyl peroxide, 2,5-di(t -butylperoxy)-2,5-dimethylhexane, n-butyl-4,4′-di(t-butylperoxy)valerate, 1,1′-di(t -butylperoxy)-3,3,5-trimethylcyclohexane, or mixtures thereof.
6. The process according to claim 1 , wherein the step ii) of producing the inner semi-conducting layer includes the sub-steps of:
ii)a. Winding a semi-conducting film including an organic peroxide around the exposed conductor joint thereby radially surrounding and covering the exposed conductor joint, the organic peroxide being selected from one of bis(t -butylperoxyisopropyl)benzene, t-butyl cumyl peroxide, 2,5-di(t-butylperoxy)-2,5-dimethylhexane, n-butyl-4,4′-di(t-butylperoxy)valerate, 1,1′-di(t-butylperoxy)-3,3,5-trimethylcyclohexane, or mixtures thereof;
ii)b. Curing the semi-conducting film and thereby producing the inner semi -conducting layer.
7. The process according to claim 1 , wherein the step v) of producing the outer semi-conducting layer includes the sub-steps of:
v)a. Winding a semi-conducting film including an organic peroxide around the insulation layer thereby radially surrounding and covering the insulation layer, the organic peroxide being selected from one of bis(t-butylperoxyisopropyl)benzene, t-butyl cumyl peroxide, 2,5-di(t-butylperoxy)-2,5-dimethylhexane, n-butyl-4,4′-di(t -butylperoxy)valerate, 1,1′-di(t-butylperoxy)-3,3,5-trimethylcyclohexane, or mixtures thereof;
v)b. Curing the semi-conducting film and thereby producing the outer semi -conducting layer.
8. The process according to claim 6 , wherein the sub-step ii)a is performed under an oxygen-free atmosphere, wherein the oxygen-free atmosphere includes at least one of nitrogen, carbon dioxide, or a noble gas.
9. The process according to claim 6 , wherein the sub-step ii)a is performed in a glovebox at a gas pressure in excess of an ambient atmospheric pressure.
10. The process according to claim 4 , wherein the polyolefin is LDPE polyethylene.
11. The process according to claim 5 , wherein the organic peroxide is dicumyl peroxide.
12. The process according to claim 7 , wherein the sub-step v)a is performed under an oxygen-free atmosphere, wherein the oxygen-free atmosphere includes at least one of nitrogen, carbon dioxide, or a noble gas.
13. The process according to claim 7 , wherein the sub-step v)a is performed in a glovebox at a gas pressure in excess of an ambient atmospheric pressure.