Process for the manufacture of a frozen product

1. A process for the manufacture of frozen gas hydrates, the process comprising passing a liquid aqueous phase over a heat exchanger surface under an atmosphere of a pressurised water-soluble gas, characterised in that the conditions of the process are selected to ensure that there is simultaneous dissolution of the pressurised gas into the liquid aqueous phase, and the formation of a solidified continuous phase from solidification of the liquid aqueous phase in contact with the heat exchanger surface.

2. A process according to claim 1 , wherein the thickness of the liquid aqueous phase is no greater than 0.5 cm.

3. A process according to claim 1 , wherein the heat exchange surface is at a temperature of from −30 C to 0° C.

4. A process according to claim 1 , wherein the pressure of the water-soluble gas is constant over the heat exchange surface.

5. A process according to claim 1 wherein the process is carried out under a pressure of from 1000 kPa to 4000 kPa.

6. A process according to any claim 1 , wherein the gas is carbon dioxide, nitrous oxide or a mixture thereof.

7. A process according to any claim 1 , wherein the liquid aqueous phase is introduced to the heat exchanger surface containing substantially no dissolved water-soluble gas.

8. A process according to any claim 1 , which is a batch process and the solidified continuous phase grows in thickness until a desired thickness is obtained.

9. A process according to claim 8 , which is followed by the step of warming the heat exchanger surface so that the solidified continuous phase that is in contact with the heat exchanger surface melts to facilitate removal of the solidified continuous phase from the heat exchanger surface.

10. A process according to claim 1 , wherein the heat exchanger surface is the inside of a tubular pipe.

11. A process according to any claim 1 , wherein the process conditions are such that a proportion of the liquid aqueous phase remains liquid after passing over and leaves the heat exchanger surface.

12. A process according to claim 11 , wherein the liquid that leaves the heat exchange surface is recirculated to reintroduce the liquid to the heat exchange surface.

13. A process according to claim 1 , followed by the step of taking the solidified continuous phase and comminuting it to form frozen ice particles, gas hydrates or mixtures thereof.

14. A process according to claim 13 wherein the particles are added to a frozen confection.