Process for preparing a diaryl carbonate
View Patent ↗A process for preparing a diaryl carbonate from a dialkyl carbonate and an aryl alcohol is disclosed. The process takes place in apparatus comprising at least two distillation columns, and at least one of the distillation columns is operated at subatmospheric pressure which is achieved using vacuum equipment.
1. A process for preparing a diaryl carbonate from a dialkyl carbonate and an aryl alcohol comprising:
a first step wherein the dialkyl carbonate reacts with the aryl alcohol in the presence of a transesterification catalyst to provide alkyl aryl carbonate and alkyl alcohol; and
a second step wherein the alkyl aryl carbonate undergoes disproportionation to yield diaryl carbonate and dialkyl carbonate;
wherein the process takes place in apparatus comprising at least two distillation columns, and at least one of the distillation columns is operated at subatmospheric pressure which is achieved using vacuum equipment;
and wherein the at least one distillation column that is operated at subatmospheric pressure has undergone a leak test and the leak test shows an air leakage rate of no greater than 2×10 −3 mbar·L/s.
2. The process according to claim 1 , wherein the dialkyl carbonate is dimethyl carbonate or diethyl carbonate.
3. The process according to claim 1 , wherein the aryl alcohol is phenol and the diaryl carbonate is diphenyl carbonate.
4. The process according to claim 1 , wherein the transesterification catalyst is a homogeneous catalyst of formula TiX 4 wherein X may be the same or different and is selected from alkoxy groups containing from 1 to 6 carbon atoms.
5. The process according to claim 1 , wherein the apparatus comprises at least two reactive distillation columns.
6. The process according to claim 5 , wherein the apparatus comprises three reactive distillation columns.
7. The process according to claim 6 , wherein the pressure at the top of a first reactive distillation column is from 2 to 7 bar, the pressure at the top of a second reactive distillation column is from 0.1 to 3 bar, and the pressure at the top of a third reactive distillation column is from 10 to 600 mbar, and the pressure at the top of the first reactive distillation column is higher than that of the second reactive distillation column which in turn is higher than that of the third reactive distillation column.
8. The process according to claim 1 , wherein there is a connection between at least one distillation column operated at subatmospheric pressure and a line providing gas to or removing gas from the distillation column, and a purge gas is applied at the connection.