Rubber mixtures
The invention relates to rubber mixtures, said rubber mixtures comprising (a) at least one rubber, excluding silicone rubber, chloroprene rubber, bromobutyl rubber, fluoro rubber and nitrile rubber, (b) at least one silane of general formula (I), G-Si(—OR) 3 (I), (c) at least one amine compound selected from the list triethanolamine, triisopropanolamine and [HO—CH(phenyl)CH 2 ] 3 N and (d) at least one bifunctional silane. The rubber mixture is produced by mixing the rubber, silane of general formula (I), amine compound and bifunctional silane.
1. A rubber mixture, comprising:
(a) a rubber, excluding silicone rubber, chloroprene rubber, bromobutyl rubber, fluoro rubber and nitrile rubber;
(b) CH 3 CH 2 CH 2 —Si(—O—CH 2 —CH 3 ) 3 as a silane;
(c) at least one amine compound selected from the group consisting of triethanolamine, triisopropanolamine and [HO—CH(phenyl)CH 2 ] 3 N; and
(d) a bifunctional silane,
wherein the silane is present from 0.8 to 4 parts by wt based on 100 parts by wt of the rubber,
the bifunctional silane is present in an amount of from 5 to 9 parts by wt based on 100 parts by wt of the rubber, and
wherein the bifunctional silane is vinyltriethoxysilane, vinyltrimethoxysilane, 3-glycidyloxypropyltriethoxysilane, 3-glycidyloxypropyltrimethoxysilane, 3-methacryloxypropyltriethoxysilane, or methacryloxypropyltrimethoxysilane.
2. The rubber mixture according to claim 1 , further comprising:
a filler; and
optionally additional rubber auxiliaries.
3. The rubber mixture according to claim 1 , wherein the at least one amine compound is present in an amount of from 0.1 to 8 parts by wt based on 100 parts by wt of the rubber.
4. The rubber mixture according to claim 1 ,
wherein the rubber is a diene rubber.
5. The rubber mixture according to claim 1 ,
wherein the at least one amine compound is triethanolamine.
6. The rubber mixture according to claim 1 ,
wherein the at least one amine compound is triisopropanolamine.
7. A process for producing the rubber mixture according to claim 1 , the process comprising:
mixing:
(a) the rubber, excluding silicone rubber, chloroprene rubber, bromobutyl rubber, fluoro rubber and nitrile rubber,
(b) the silane,
(c) the at least one amine compound, and
(d) the bifunctional silane.
8. A production method comprising:
producing moulded articles using the rubber mixture according to claim 1 .
9. The production method according to claim 8 , wherein the moulded articles are selected from the group consisting of pneumatic tires, tire treads, rubber-containing tire components, cable sheathings, hoses, drive belts, conveyor belts, roller coverings, tires, shoe soles, sealing rings and damping elements.
10. A rubber mixture, comprising:
(a) a rubber, excluding silicone rubber, chloroprene rubber, bromobutyl rubber, fluoro rubber and nitrile rubber;
(b) CH 3 CH 2 CH 2 —Si(—O—CH 2 —CH 3 ) 3 as a silane;
(c) [HO—CH(phenyl)CH 2 ] 3 N; and
(d) a bifunctional silane,
wherein the silane is present from 0.8 to 4 parts by wt based on 100 parts by wt of the rubber, and
the bifunctional silane is present in an amount of from 5 to 9 parts by wt based on 100 parts by wt of the rubber.