Pressure-sensitive adhesive composition
The present application relates to a pressure-sensitive adhesive composition, a protective film, an optical element and a display device. The pressure-sensitive adhesive composition of the present application has excellent storage stability, exhibits an appropriate low-speed and high-speed peel forces after the cross-linked structure is formed, and has excellent balance of both. Furthermore, the pressure-sensitive adhesive formed by the pressure-sensitive adhesive composition does not leave contaminants in the adherend after peeling, while exhibiting re-detachability. Accordingly, when the pressure-sensitive adhesive composition is applied to, for example, a protective film, it is also advantageous in terms of high-speed processes by being easily peeled off upon high-speed peeling as well as it exhibits an excellent protective effect, thereby being capable of exhibiting excellent antistatic characteristics.
1. A pressure-sensitive adhesive composition comprising an acrylic polymer and an ionic compound, wherein the ionic compound is included in a ratio of 0.001 to 5 parts by weight relative to 100 parts by weight of said acrylic polymer and comprises an imidazole-based anion and a metal cation,
wherein the imidazole-based anion is represented by Formula 3 below:
wherein, Rf is a trifluromethyl group, and R1 and R2 are each a cyano group, and
wherein the metal cation is a lithium cation.
2. The pressure-sensitive adhesive composition according to claim 1 , wherein the acrylic polymer is a polymer of a monomer mixture comprising an alkyl (meth)acrylate; a first monomer represented by Formula 1 below, where the carbon number contained in an alkylene group of A and B in Formula 1 below is in a range of 1 to 3; a second monomer represented by Formula 1 below, where the carbon number contained in an alkylene group of A and B in Formula 1 below is in a range of 4 to 8; and a compound of Formula 2 below:
wherein, Q is hydrogen or an alkyl group, A and B are each independently an alkylene group, and n is a number in a range of 0 to 10:
wherein, Q is hydrogen or an alkyl group having 1 to 4 carbon atoms, U is an alkylene group having 1 to 4 carbon atoms, Z is hydrogen, an alkyl group or an aryl group, and m is a number of 1 or more.
3. The pressure-sensitive adhesive composition according to claim 1 , further comprising an aliphatic isocyanate cross-linking agent.
4. The pressure-sensitive adhesive composition according to claim 3 , wherein the cross-linking agent comprises at least one selected from the group consisting of an aliphatic cyclic isocyanate compound and an aliphatic acyclic isocyanate compound.
5. The pressure-sensitive adhesive composition according to claim 3 , wherein the cross-linking agent is contained in an amount of 0.01 parts by weight to 15 parts by weight relative to 100 parts by weight of the acrylic polymer.
6. A surface protective film comprising a surface protective base layer; and a pressure-sensitive adhesive layer which is formed on one or both sides of said base layer and comprises the pressure-sensitive adhesive composition according to claim 1 in a cross-linked state.
7. An optical element in which the protective film of claim 6 is attached to a surface so as to be detachable.
8. The optical element according to claim 7 , wherein the surface to which the protective film is attached has a surface energy of 30 mN/m or less.
9. A display device comprising the optical element of claim 7 .