Ultra-high strength steel sheet having excellent phosphatability and bendability
Provided is an ultra-high strength steel sheet having excellent phosphatability and bendability. The ultra-high strength steel sheet includes, by weight percentage (wt %), carbon (C): 0.08% to 0.2%, silicon (Si): 0.05% to 1.3%, manganese (Mn): 2.0% to 3.0%, phosphorus (P): 0.001% to 0.10%, sulfur (S): 0.010% or less, aluminum (Al): 0.01% to 0.1%, chromium (Cr): 0.3% to 1.2%, boron (B): 0.0010% to 0.0030%, titanium (Ti): 0.01% to 0.05%, nitrogen (N): 0.001% to 0.01%, a remainder of iron (Fe) and other inevitable impurities, satisfying: 3.4≤Ti/N≤10, 1.0≤Mn/(Si+Cr), and 0.7≤Mn*/(Si*+Cr*)≤Mn/(Si+Cr), where Ti, N, Mn, Si and Cr refer to a weight percentage (wt %), and Mn*, Si* and Cr* refer to an average of values obtained by GDS component analysis from a surface to a 0.1 μm position in a thickness direction.
1. An ultra-high strength steel sheet having excellent phosphatability and bendability, the steel sheet comprising, by weight percentage (wt %), carbon (C): 0.08% to 0.2%, silicon (Si): 0.05% to 1.3%, manganese (Mn): 2.0% to 3.0%, phosphorus (P): 0.001% to 0.10%, sulfur (S): 0.010% or less, aluminum (Al): 0.01% to 0.1%, chromium (Cr): 0.3% to 1.2%, boron (B): 0.0010% to 0.0030%, titanium (Ti): 0.01% to 0.05%, nitrogen (N): 0.001% to 0.01%, a remainder of iron (Fe) and other inevitable impurities,
wherein Ti and N satisfy Relationship 1:
3.4≤Ti/N≤10 [Relationship 1]
where Ti and N refer to a weight percentage (wt %) of the elements Ti and N, respectively,
wherein Mn, Si and Cr satisfy Relationship 2:
1.0≤Mn/(Si+Cr) [Relationship 2]
where Mn, Si and Cr refer to a weight percentage (wt %) of the elements Mn, Si and Cr, respectively, and
wherein amounts of Mn, Si and Cr in a surface layer, ranging from a surface to a 0.1 μm position in a thickness direction, satisfy Relationship 3:
0.7≤Mn*/(Si*+Cr*)≤Mn/(Si+Cr) [Relationship 3]
where Mn, Si and Cr refer to a weight percentage (wt %) of the elements Mn, Si and Cr, respectively, and Mn*, Si* and Cr* refer to an average weight percent (wt %) of the elements Mn, Si and Cr in the surface layer, respectively, and obtained by GDS component analysis.
2. The ultra-high strength steel sheet according to claim 1 , wherein the steel sheet further comprises, by weight percentage (wt %), one or more of niobium (Nb): 0.01% to 0.05%, molybdenum (Mo): 0.01% to 0.20%, vanadium (V): 0.01% to 0.20%, and tungsten (W): 0.01% to 0.20%, and satisfies Relationship 4:
0.01≤Nb+0.2(Mo+V+W)≤0.05 [Relationship 4]
where Nb, Mo, V and W refer to a weight percentage (wt %) of the elements Nb, Mo, V and W, respectively.
3. The ultra-high strength steel sheet according to claim 1 , wherein the steel sheet has a microstructure comprising, by area fraction, 30% to 80% of bainite, 20% to 50% of martensite, less than 5% of retained austenite, and a remainder of ferrite.
4. The ultra-high strength steel sheet according to claim 1 , wherein the steel sheet has (tensile strength (MPa)×elongation (%))/(R/t) value of 5500 or greater where (R/t) refers a bendability, and R refers to a minimum radius of curvature causing no crack when V-bending the steel sheet having a thickness tin millimeters.
5. The ultra-high strength steel sheet according to claim 1 , wherein the steel sheet comprises: a cold-rolled steel sheet.