Preparation of blown polymer modified asphalt
View Patent ↗It has been found that numerous benefits can be realized by air blowing asphalt in the presence of at least one highly saturated polymer, such as polyisobutylene, and a reactive polymer having glycidyl groups, such as an ethylene-glycidyl-acrylate. This allows for asphalt streams which would typically not be commercially viable for blowing into industrial asphalt that can be used in roofing products and a wide array of other applications. For instance, this technique can be used to air blow currently available paving grade asphalts into industrial asphalt for roofing products. Other potential benefits include shorter processing time (air blowing time), reduced emissions, and blown coatings with improved weatherability. In one embodiment of this invention asphalt is only partially air blown before adding the polymer to attain a product having desired characteristics for specific applications.
1. A method for preparing an industrial asphalt comprising air blowing an asphalt in the presence of at least one highly saturated polymer and a reactive polymer having glycidyl groups, wherein the air blowing is carried out by sparging an oxygen containing gas through the asphalt at temperature which is within the range of 400° F. to 700° F.
2. The method of claim 1 wherein the reactive polymer has an ethylene backbone which is modified with a glycidyl functional group.
3. The method of claim 2 wherein the reactive polymer is modified with an acrylate functional group.
4. The method of claim 1 wherein the reactive polymer is an ethylene-glycidyl-acrylate.
5. The method of claim 1 wherein the highly saturated polymer is a highly saturated rubbery polymer.
6. The method of claim 5 wherein the highly saturated rubbery polymer contains repeat units of the formula:
7. The method of claim 1 wherein the highly saturated polymer is present at a level which is within the range of about 0.25 weight percent to about 15 weight percent.
8. The method of claim 1 wherein the highly saturated polymer is present at a level which is within the range of about 1 weight percent to about 12 weight percent.
9. The method of claim 1 wherein the highly saturated polymer is present at a level which is within the range of about 2 weight percent to about 10 weight percent.
10. The method of claim 1 wherein the highly saturated polymer is present at a level which is within the range of about 3 weight percent to about 10 weight percent.
11. The method of claim 1 wherein the reactive polymer is present at a level which is within the range of about 0.25 weight percent to 6 weight percent.
12. The method of claim 1 wherein the reactive polymer is present at a level which is within the range of about 0.5 weight percent to 4 weight percent.
13. The method of claim 1 wherein the reactive polymer is present at a level which is within the range of about 1 weight percent to 3 weight percent.
14. The method of claim 1 wherein the industrial asphalt has a softening point which is within the range of 190° F. to 240° F., and wherein the industrial asphalt has a penetration value which is within the range of 15 dmm to 25 dmm.
15. The method of claim 1 wherein the air blowing is carried out by sparging an oxygen containing gas through the asphalt at temperature which is within the range of 450° F. to about 550° F. for a period of time which is within the range of 2 hours to 20 hours.
16. The method of claim 1 wherein asphalt is further comprised of an air blowing catalyst.
17. The method of claim 1 wherein the highly saturated polymer is added to the asphalt prior to air blowing.
18. The method of claim 1 wherein the reactive polymer is added to the asphalt prior to air blowing.
19. The method of claim 1 wherein the air blowing is carried out by sparging an oxygen containing gas through the asphalt at temperature which is within the range of 475° F. to about 550° F. for a period of time which is within the range of 3 hours to 12 hours.
20. The method of claim 15 wherein the air blowing is carried out by sparging an oxygen containing gas through the asphalt for a period of time which is within the range of 4 hours to 12 hours.
21. The method of claim 1 wherein the reactive polymer and the highly saturated polymer are added to the asphalt prior to air blowing.