Colored photosensitive resin composition and light shielding spacer prepared therefrom
The present invention relates to a colored photosensitive resin composition capable of forming a cured film that does not generate uneven wrinkles on its surface at the time of its formation, and a light shielding spacer produced therefrom and used for a liquid crystal display, an organic EL display, or the like.
1. A colored photosensitive resin composition, which comprises:
(A) a copolymer comprising an epoxy group;
(B) a photopolymerizable compound comprising a double bond;
(C) a photopolymerization initiator; and
(D) a colorant,
wherein the molar ratio of the double bonds in the photopolymerizable compound (B) to the epoxy groups in the copolymer (A) satisfies the following relationship:
4≤number of moles of double bonds/number of moles of epoxy groups≤35; and
wherein a cured film formed from the colored photosensitive resin composition has an optical density of 1.0/μm to 3.0/μm.
2. The colored photosensitive resin composition according to claim 1 , wherein the colorant comprises a dispersion resin, and the dispersion resin has an amine value of 3 mg KOH/g or less and comprises 30 mole % or less of a maleimide monomer based on the total number of moles of the constituents.
3. The colored photosensitive resin composition according to claim 1 , which further comprises (E) a compound derived from an epoxy resin and having a double bone.
4. The colored photosensitive resin composition according to claim 3 , wherein the molar ratio of the double bonds in the photopolymerizable compound (B) and in the compound derived from an epoxy resin (E) to the epoxy groups in the copolymer (A) satisfies the following relationship:
4≤number of moles of double bonds/number of moles of epoxy groups≤35.
5. The colored photosensitive resin composition according to claim 3 , which further comprises (F) an epoxy compound.
6. The colored photosensitive resin composition according to claim 5 , wherein the molar ratio of the double bonds in the photopolymerizable compound (B) and in the compound derived from an epoxy resin (E) to the epoxy groups in the copolymer (A) and in the epoxy compound (F) satisfies the above relationship:
4≤number of moles of double bonds/number of moles of epoxy groups≤35.
7. The colored photosensitive resin composition according to claim 1 , which further comprises (F) an epoxy compound.
8. The colored photosensitive resin composition according to claim 7 , wherein the molar ratio of the double bonds in the photopolymerizable compound (B) to the epoxy groups in the copolymer (A) and in the epoxy compound (F) satisfies the following relationship:
4≤number of moles of double bonds/number of moles of epoxy groups≤35.
9. A light shielding spacer manufactured from the colored photosensitive resin composition according to claim 1 .