Oriented perovskite crystals and methods of making the same
An aspect of the present disclosure is a method that includes combining a first organic salt (A 1 X 1 ), a first metal salt (M 1 (X 2 ) 2 ), a second organic salt (A 2 X 3 ), a second metal salt (M 2 Cl 2 ), and a solvent to form a primary solution, where A 1 X 1 and M 1 (X 2 ) 2 are present in the primary solution at a first ratio between about 0.5 to 1.0 and about 1.5 to 1.0, and A 2 X 3 to M 2 Cl 2 are present in the primary solution at a second ratio between about 2.0 to 1.0 and about 4.0 to 1.0. In some embodiments of the present disclosure, at least one of A 1 or A 2 may include at least one of an alkyl ammonium, an alkyl diamine, cesium, and/or rubidium.
1. A device comprising:
a perovskite layer comprising an organic-inorganic perovskite crystal, wherein:
the perovskite layer is positioned substantially parallel with a plane,
the organic-inorganic perovskite crystal has a molar composition defined by FA x MA (1-x) PbI (3-y) Cl y ,
0<x<1.0,
0<y<3.0,
the organic-inorganic perovskite crystal has a length dimension and a width dimension,
the length dimension and the width dimension define an aspect ratio of the length dimension to the width dimension between about 1.5 and about 50, and
the length dimension has an orientation that is substantially perpendicular to the plane.
2. The device of claim 1 , wherein the length dimension is between about 100 nm and about 3000 nm.
3. The device of claim 1 , wherein the width dimension is between about 2 μm and about 5 μm.
4. The device of claim 1 , wherein the orientation is uniaxial along the [−111] direction.
5. The device of claim 4 , wherein the orientation is validated by XRD by the presence of bright spots at 14.0° and 28.2°.