IP Library Granted Patent US 9,920,712
Granted Patent B1
US 9,920,712 · App. 15/786,993 · Granted Mar 20, 2018

Method for forming a plurality of plugs of carbonaceous material

Inventors: Ravi Chandran (Ellicott City, MD); Daniel A. Burciaga (Manchester, MD); Daniel Michael Leo (Baltimore, MD); Shawn Robert Freitas (Corvallis, OR); Dave G. Newport (Cumberland, ME); Justin Kevin Miller (Durham, NC); Kaitlin Emily Harrington (Hillsborough, NC); Brian Christopher Attwood (Cary, NC); Emily Jane Schultheis (Glenwood, MD); Kelly Ann Kishton (Columbia, MD)
Assignee: ThermoChem Recovery International, Inc.
F02M21/029C10B31/00C10B37/00C10B39/00C10B57/00C10G2/00C10J3/723C10J3/82F02M21/0209F02P13/00C10J2200/15C10J2300/0906C10J2300/165C10J2300/1659
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Quick Facts
Patent No.
US 9,920,712
App. No.
15/786,993
Granted
Mar 20, 2018
Kind
B1
Abstract

A feedstock delivery system transfers a carbonaceous material, such as municipal solid waste, into a product gas generation system. The feedstock delivery system includes a splitter for splitting bulk carbonaceous material into a plurality of carbonaceous material streams. Each stream is processed using a weighing system for gauging the quantity of carbonaceous material, a densification system for forming plugs of carbonaceous material, a de-densification system for breaking up the plugs of carbonaceous material, and a gas and carbonaceous material mixing system for forming a carbonaceous material and gas mixture. A pressure of the mixing gas is reduced prior to mixing with the carbonaceous material, and the carbonaceous material to gas weight ratio is monitored. A transport assembly conveys the carbonaceous material and gas mixture to a first reactor where at least the carbonaceous material within the mixture is subject to thermochemical reactions to form the product gas.

Claims (51)

1. A method for forming a new plug of densified carbonaceous material in a cylinder already having a series of previously formed plugs pressed together, and supplying a leading plug of said series of previously formed plugs to a pressurized first reactor,

the cylinder (D 30 ) comprising a first opening (D 19 ) through which carbonaceous material ( 2 D- 01 ) is introduced into the cylinder, and a first output (D 45 ) through which the leading plug is supplied to the pressurized first reactor;

the method comprising:

(a) introducing, via the first opening (D 19 ), a quantity of carbonaceous material having a density of 4 pounds per cubic foot to 50 pounds per cubic foot;

(b) while said plurality of previously formed plugs are prevented from advancing within the cylinder, compressing said carbonaceous material (D+1) against a nearest plug of said plurality of previously formed plugs, to thereby form a new plug against said plurality of previously formed plugs;

(c) advancing the new plug and said series of previously formed plugs such that the leading plug appears at the cylinder's first output (D 45 );

(d) removing the leading plug from the cylinder, thereby leaving behind a new series of previously formed plugs; and

(e) shredding the removed leading plug and introducing the shredded carbonaceous material therefrom into the pressurized first reactor, wherein:

said series of previously formed plugs are sufficiently dense to maintain a pressure difference between the cylinder's first opening and the pressurized first reactor.

2. The method according to claim 1 , wherein:

the series of previously formed plugs creates a pressure difference that ranges from 9 pounds per square inch to 75 pounds per square inch.

3. The method according to claim 1 , wherein:

the series of previously formed plugs includes at least a first plug ( 1 D) and a second plug ( 2 D) each having a length ranging from 10 inches to 15 inches.

4. The method according to claim 1 , wherein:

the series of previously formed plugs includes at least a first plug ( 1 D) and a second plug ( 2 D) each having a diameter ranging from 10 inches to 15 inches.

5. The method according to claim 1 , further comprising:

weighing the carbonaceous material before step (a).

6. The method according to claim 1 , further comprising:

creating a new plug within the cylinder (D 30 ) about every 15 seconds, by repeating steps (a) through (e).

7. The method according to claim 1 , wherein:

each plug within the series of previously formed plugs weighs from about 32 pounds to about 40 pounds.

8. The method according to claim 1 , further comprising:

mixing a gas with the shredded carbonaceous material after step (e) and prior to introducing the shredded carbonaceous material into the pressurized first reactor.

9. The method according to claim 8 , further comprising:

mixing the shredded carbonaceous material with gas at a mass ratio of carbonaceous material to gas that is less than 75 pounds of carbonaceous material per pound of gas.

10. The method according to claim 8 , where the gas is carbon dioxide or an oxygen-containing gas.

11. The method according to claim 10 , wherein the mixing gas is carbon dioxide and the method comprises:

endothermically reacting a portion of the carbonaceous material in the first reactor with a portion of the carbon dioxide.

12. The method according to claim 1 , further comprising:

(f) introducing steam into the first reactor such that a mass ratio of the steam to carbonaceous material in the range of 0.125:1 to 3:1; and

(g) operating the first reactor at a temperature between 570° C. and 900° C. to endothermically react the carbonaceous material with the steam to produce a first reactor product gas.

13. The method according to claim 12 , wherein the first reactor product gas of step (g) further comprises H2, CO, CO2, char, semi-volatile organic compounds (SVOC), and volatile organic compounds (VOC).

14. The method according to claim 13 , further comprising:

(i) providing a second reactor;

(ii) introducing at least a portion of the char into the second reactor;

(iii) reacting the char introduced into the second reactor, with an oxygen-containing gas in the second reactor to produce a second reactor product gas; and

(iv) combining the first reactor product gas with the second reactor product gas to form a combined product gas.

15. The method according to claim 14 , comprising:

operating the first reactor and the second reactor at a superficial fluidization velocity range between 0.5 ft/s to about 25.0 ft/s.

16. The method according to claim 14 , further comprising:

(v) transferring heat from the second reactor to a heat transfer medium via a second reactor heat exchanger in thermal contact with an interior of the second reactor, the heat transfer medium comprising steam; and

(vi) introducing at least a first portion of the steam that has been heated by the second reactor, into the first reactor, to react with the carbonaceous material.

17. The method according to claim 1 , further comprising:

(f) introducing carbon dioxide gas to the first reactor such that a mass ratio of the carbon dioxide gas to carbonaceous material in the range of 0.1 to 1:1; and

(g) operating the first reactor at a temperature between 600° C. and 1000° C. to endothermically react the carbonaceous material with the carbon dioxide to produce a first reactor product gas.

18. The method according to claim 1 , further comprising:

(f) introducing an oxygen-containing gas to the first reactor such that a mass ratio of the oxygen-containing gas to carbonaceous material in the range of 0.1 to 0.5:1; and

(g) operating the first reactor at a temperature between 500° C. and 1400° C. to exothermically react the carbonaceous material with the oxygen-containing gas to produce a first reactor product gas.

19. The method according to claim 1 , further comprising:

combusting a fuel source in a first reactor heat exchanger to form a combustion stream, said combustion stream indirectly heating particulate heat transfer material present in the first reactor.

20. The method according to claim 1 , wherein the first reactor operates at a superficial fluidization velocity range between 0.6 ft/s to about 1.2 ft/s.

Assignments (2)
SECURITY INTEREST Recorded Sep 12, 2023
From: THERMOCHEM RECOVERY INTERNATIONAL, INC.
To: THE ABELL FOUNDATION, INC.
Reel/Frame 064881/0214 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 15, 2019
From: CHANDRAN, RAVI; BURCIAGA, DANIEL A.; LEO, DANIEL MICHAEL; FREITAS, SHAWN ROBERT; NEWPORT, DAVE G.; MILLER, JUSTIN KEVIN; HARRINGTON, KAITLIN EMILY; ATTWOOD, BRIAN CHRISTOPHER; SCHULTHEIS, EMILY JANE; KISHTON, KELLY ANN
To: THERMOCHEM RECOVERY INTERNATIONAL, INC.
Reel/Frame 048013/0325 →
Continuity (1)
Continuation 15251156 · Aug 30, 2016