IP Library Granted Patent US 10,900,592
Granted Patent B2
US 10,900,592 · App. 15/791,597 · Granted Jan 26, 2021

Sprayable and pumpable urea silicate foam for pipe pillows, trench breakers and civil construction applications

Inventors: Frederick Cybulski (Mt. Pleasant, OH); Cody Hildreth (Canonsburg, PA); Peter Shelley Mills (Stamping Ground, KY); Stephen C. Tadolini (Lakewood, CO)
Assignee: MINOVA INTERNATIONAL LIMITED
F16L1/06C08G18/1808C08G18/1816C08G18/1825C08G18/3895C08G18/7664C08J9/0061F16L1/028F16L3/02F16L3/12C08G2101/005C08G2101/0058C08G2101/0083C08J2201/022C08J2205/05C08J2207/00C08J2207/04C08J2375/00C08J2483/12F16L1/026
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Quick Facts
Patent No.
US 10,900,592
App. No.
15/791,597
Granted
Jan 26, 2021
Kind
B2
Abstract

Disclosed is a method and system for supporting a pipeline in a trench. The disclosure is directed to the placement of urea-silicate sprayable or pumpable foams into trenches to provide pipeline pillow supports during placement of the pipeline and to form trench breakers in the trench prior to the trench being backfilled. The pillow supports and trench breakers inhibit erosion of the trench prior to and after being backfilled. The urea-silicate foam material has an open cell content of at least 50% to resist floatation, is non-flammable and electrically conductive. Also disclosed is use of supports for placement between the urea-silicate foam and the bottom of the trench to aid in utilization of the urea-silicate foams in cold weather conditions and in trenches with steeply sloped bottoms. Preferably the supports are biodegradable and electrically conductive when wet.

Claims (26)

1. A method for supporting a pipe in a trench comprising the steps of:

a) providing, separately, a component A and a component B, wherein component A comprises at least 23% by weight of alkali silicate and a catalyst and component B comprises at least 75% by weight of at least one polyisocyanate and a block copolymer according to general formula I, based on the total weight of component A and component B, respectively, wherein formula I comprises

wherein P comprises a polyether having a structure of —((CH 2 ) 2 O) x (CH 2 ) 3 O) y —R

wherein n, m, x and y are integers and R is either a H or an alkyl group;

b) combining component A with component B thereby forming a urea-silicate foam material;

c) placing a support material in the bottom of the trench, the support material being electrically conductive when wet and the support material being biodegradable;

d) depositing the urea-silicate foam material into the trench onto the support material and allowing it to foam and cure thereby forming a urea-silicate foam pillow on the support material, wherein said urea-silicate foam pillow has an open cell content of at least 50%, is electrically conductive and permeable to water; and

e) placing a pipe into the trench with a portion of the pipe in contact with the foam pillow.

2. The method as recited in claim 1 wherein step a) further comprises providing component A and component B, each at a temperature of from 21 to 33° C.

3. The method as recited in claim 1 wherein step a) further comprises providing in component A at least one of water, a polymeric phosphate foam stabilizer, an emulsifier or a mixture thereof and providing in component B at least one of a flame retardant, a foam stabilizer, a viscosity reducer, a catalyst, a finely divided nucleating agent, or a mixture thereof.

4. The method as recited in claim 1 wherein step a) comprises providing as the polyisocyanate in component B, polymeric methylene diphenyl diisocyanate.

5. The method as recited in claim 1 wherein step b) comprises combining component A with component B in a ratio from 1:1+/−10% on a volume basis.

6. The method as recited in claim 1 wherein the support material is formed from a molded pulp material, fiberboard, cardboard or a paperboard material.

7. A method for supporting a pipe in a trench comprising the steps of:

a) providing, separately, a component A and a component B, wherein component A comprises at least 23% by weight of alkali silicate and a catalyst and component B comprises at least 75% by weight of at least one polyisocyanate and a block copolymer according to general formula I, based on the total weight of component A and component B, respectively, wherein formula I comprises

wherein P comprises a polyether having a structure of —((CH 2 ) 2 O) x (CH 2 ) 3 O) y —R

wherein n, m, x and y are integers and R is either a H or an alkyl group;

b) combining component A with component B thereby forming a urea-silicate foam material;

c) placing a support material in the bottom of the trench, the support material being electrically conductive when wet and the support material being biodegradable;

d) placing a pipe into the trench; and

e) depositing the urea-silicate foam material into the trench onto the support material and over a portion of the pipe and allowing it to foam and cure on the support material and around a portion of the pipe thereby forming a urea-silicate foam trench breaker in the trench, wherein said urea-silicate foam trench breaker has an open cell content of at least 50%, is electrically conductive and permeable to water.

8. The method as recited in claim 7 wherein step a) further comprises providing component A and component B, each at a temperature of from 21 to 33° C.

9. The method as recited in claim 7 wherein step a) further comprises providing in component A at least one of water, a polymeric phosphate foam stabilizer, an emulsifier or a mixture thereof and providing in component B at least one of a flame retardant, a foam stabilizer, a viscosity reducer, a catalyst, a finely divided nucleating agent, or a mixture thereof.

10. The method as recited in claim 7 wherein step a) comprises providing as the polyisocyanate in component B, polymeric methylene diphenyl diisocyanate.

11. The method as recited in claim 7 wherein step b) comprises combining component A with component B in a ratio from 1:1+/−10% on a volume basis.

12. The method as recited in claim 7 wherein the support material is formed from a molded pulp material, fiberboard, cardboard or a paperboard material.

Assignments (4)
TERMINATION AND RELEASE OF PATENT SECURITY AGREEMENT RECORDED AT REEL 059115, FRAME 0960 Recorded Feb 18, 2025
From: BZ COMMERCIAL FINANCE DESIGNATED ACTIVITY COMPANY
To: MINOVA INTERNATIONAL LIMITED
Reel/Frame 070251/0849 →
SECURITY INTEREST Recorded Feb 14, 2025
From: MINOVA INTERNATIONAL LIMITED
To: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
Reel/Frame 070223/0196 →
SECURITY INTEREST Recorded Feb 28, 2022
From: MINOVA INTERNATIONAL LIMITED
To: BZ COMMERCIAL FINANCE DESIGNATED ACTIVITY COMPANY
Reel/Frame 059115/0960 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2018
From: CYBULSKI, FREDERICK; HILDRETH, CODY; MILLS, PETER SHELLEY; TADOLINI, STEPHEN C.
To: MINOVA INTERNATIONAL LIMITED
Reel/Frame 045844/0909 →
Continuity (2)
Provisional Application 62412718 · Oct 25, 2016
Related Publication 20180112801A1 · Apr 26, 2018