IP Library Granted Patent US 10,626,489
Granted Patent B2
US 10,626,489 · App. 15/792,295 · Granted Apr 21, 2020

Wear-resistant Cu—Ni—Sn coating

Inventors: Fritz C. Grensing (Perrysburg, OH); Robert E. Kusner (Mayfield Heights, OH); David J. Krus (Mayfield Heights, OH); William D. Nielsen (Houston, TX); Karl Ziegler (Mayfield Heights, OH)
Assignee: MATERION CORPORATION
C23C4/08C22C9/06C23C24/04F16C33/121F16C2223/42
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Quick Facts
Patent No.
US 10,626,489
App. No.
15/792,295
Granted
Apr 21, 2020
Kind
B2
Abstract

The present disclosure relates to a method of applying a wear-resistant copper-nickel-tin coating to a substrate using a thermal spray process. Briefly, a copper-nickel-tin alloy feedstock is converted into a powder or droplet form, then sprayed onto a substrate to form a coating thereon.

Claims (37)

1. A method of applying a wear-resistant copper-nickel-tin coating to a substrate using a thermal spray process, the steps comprising:

applying heat to a copper-nickel-tin alloy provided as a feedstock in the shape of a wire;

mixing the heated copper-nickel-tin alloy with a carrier gas to form a copper-nickel-tin alloy mixture; and

spraying the resulting copper-nickel-tin alloy mixture upon a substrate to provide a spinodal outer coating thereon.

2. The coating method of claim 1 , wherein the copper-nickel-tin alloy is about 8 wt % to about 22 wt % nickel, about 4 wt % to about 10 wt % tin, and the remaining balance is copper.

3. The coating method of claim 1 , wherein the thermal spray process is a cold spray, plasma spray, warm spray, detonation spray, high-velocity oxy fuel spray, or arc spray process.

4. The coating method of claim 1 , wherein the spraying occurs at a pressure of about 20 bar to about 40 bar.

5. The coating method of claim 1 , wherein the alloy mixture has a temperature of about 350° C. to about 700° C.

6. The coating method of claim 1 , wherein the coating has a thickness of about 100 micrometers to about 2000 micrometers.

7. The coating method of claim 1 , wherein the alloy mixture is sprayed at a velocity of 50 m/s to 1500 m/s.

8. A method of applying a wear-resistant copper-nickel-tin coating to a substrate using a thermal spray process, the steps comprising:

applying heat to a copper-nickel-tin alloy;

mixing the heated copper-nickel-tin alloy with a carrier gas to form a copper-nickel-tin alloy mixture; and

spraying the resulting copper-nickel-tin alloy mixture upon a substrate to provide a spinodal outer coating thereon, wherein the spraying occurs at a pressure of about 20 bar to about 40 bar.

9. The coating method of claim 8 , wherein the copper-nickel-tin alloy is about 8 wt % to about 22 wt % nickel, about 4 wt % to about 10 wt % tin, and the remaining balance is copper.

10. The coating method of claim 8 , wherein the thermal spray process is a cold spray, plasma spray, warm spray, detonation spray, high-velocity oxy fuel spray, or arc spray process.

11. The coating method of claim 8 , wherein the alloy mixture has a temperature of about 350° C. to about 700° C.

12. The coating method of claim 8 , wherein the coating has a thickness of about 100 micrometers to about 2000 micrometers.

13. The coating method of claim 8 , wherein the alloy mixture is sprayed at a velocity of 50 m/s to 1500 m/s.

14. A method of applying a wear-resistant copper-nickel-tin coating to a substrate using a thermal spray process, the steps comprising:

applying heat to a copper-nickel-tin alloy;

mixing the heated copper-nickel-tin alloy with a carrier gas to form a copper-nickel-tin alloy mixture; and

spraying the resulting copper-nickel-tin alloy mixture upon a substrate to provide a spinodal outer coating thereon, wherein the coating has a thickness of about 100 micrometers to about 2000 micrometers.

15. The coating method of claim 14 , wherein the copper-nickel-tin alloy is about 8 wt % to about 22 wt % nickel, about 4 wt % to about 10 wt % tin, and the remaining balance is copper.

16. The coating method of claim 14 , wherein the thermal spray process is a cold spray, plasma spray, warm spray, detonation spray, high-velocity oxy fuel spray, or arc spray process.

17. The coating method of claim 14 , wherein the spraying occurs at a pressure of about 20 bar to about 40 bar.

18. The coating method of claim 14 , wherein the alloy mixture has a temperature of about 350° C. to about 700° C.

19. The coating method of claim 14 , wherein the alloy mixture is sprayed at a velocity of 50 m/s to 1500 m/s.

20. A method of applying a wear-resistant copper-nickel-tin coating to a substrate using a thermal spray process, the steps comprising:

applying heat to a copper-nickel-tin alloy;

mixing the heated copper-nickel-tin alloy with a carrier gas to form a copper-nickel-tin alloy mixture; and

spraying the resulting copper-nickel-tin alloy mixture upon a substrate to provide a spinodal outer coating thereon, wherein the alloy mixture is sprayed at a velocity of 50 m/s to 1500 m/s.

21. The coating method of claim 20 , wherein the copper-nickel-tin alloy is about 8 wt % to about 22 wt % nickel, about 4 wt % to about 10 wt % tin, and the remaining balance is copper.

22. The coating method of claim 20 , wherein the thermal spray process is a cold spray, plasma spray, warm spray, detonation spray, high-velocity oxy fuel spray, or arc spray process.

23. The coating method of claim 20 , wherein the spraying occurs at a pressure of about 20 bar to about 40 bar.

24. The coating method of claim 20 , wherein the alloy mixture has a temperature of about 350° C. to about 700° C.

25. The coating method of claim 20 , wherein the coating has a thickness of about 100 micrometers to about 2000 micrometers.

Assignments (2)
SECURITY INTEREST Recorded Sep 25, 2019
From: MATERION CORPORATION
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 050493/0809 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 24, 2017
From: GRENSING, FRITZ C.; KRUS, DAVID J.; KUSNER, ROBERT E.; NIELSEN, WILLIAM D.; ZIEGLER, KARL
To: MATERION CORPORATION
Reel/Frame 043939/0070 →
Continuity (2)
Provisional Application 62411828 · Oct 24, 2016
Related Publication 20180112302A1 · Apr 26, 2018