Water-based compositions that resist dirt pick-up
View Patent ↗Water-based compositions containing a low VOC coalescent, a latex or water-dispersible polymer, and a water-insoluble UV-VIS (preferably, ultraviolet) absorber.
1. A water-based composition, comprising:
a latex polymer;
methyl-o-benzoyl benzoate; and
one or more low VOC coalescents having a volatile organic content of 30% or less, or that elute from a GC column at the same time or after methyl palmitate under the same conditions;
wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids.
2. The composition of claim 1 wherein the latex polymer has at least one Tg within a range of −20° C. to 70° C.
3. The composition of claim 1 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers selected from the group of alkyl acrylates, alkoxy acrylates, alkyl methacrylates, alkoxy methacrylates, vinyl esters of saturated carboxylic acids, monoolefins, and conjugated dienes optionally with one or more monomers, selected from the group of styrene, methyl methacrylate, butyl acrylate, 2-ethylhexyl acrylate, vinyl acetate, acrylonitrile, and vinyl chloride.
4. The composition of claim 3 wherein the latex polymer comprises a surfactant and polymer particles comprising a homopolymer or copolymer including at least one of an acrylate or a methacrylate.
5. The composition of claim 1 wherein the water-based composition comprises a sufficient amount of methyl-o-benzoyl benzoate to improve dirt pick-up resistance of the water-based composition by at least 10%, relative to the same water-based composition without methyl-o-benzoyl benzoate, based on a change in ΔE values.
6. The composition of claim 5 wherein the water-based composition comprises a sufficient amount of methyl-o-benzoyl benzoate to improve dirt pick-up resistance by at least 50%, relative to the same water-based composition without methyl-o-benzoyl benzoate, based on a change in ΔE values.
7. The composition of claim 1 wherein the water-based composition comprises at least 0.1 wt-% of methyl-o-benzoyl benzoate, based on the weight of the polymer solids.
8. The composition of claim 1 wherein the water-based composition comprises up to 5.0 wt-% of methyl-o-benzoyl benzoate, based on the weight of the polymer solids.
9. The composition of claim 1 wherein the one or more coalescents are present in a sufficient amount to facilitate the formation of a polymer film of the latex polymer at a temperature of less than 25° C.
10. The composition of claim 1 wherein the one or more coalescents has a volatile organic content of 15% or less.
11. The composition of claim 1 wherein at least one coalescent is selected from the group of bis(2-ethylhexyl) maleate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) azelate, isodecyl benzoate, tri(ethylene glycol)bis(2-ethylhexanoate), tetra(ethylene glycol)bis(2-ethylhexanoate), tributyl citrate, octyl benzoate, di(ethylene glycol)dibenzoate, octadecenoic acid methyl ester, and oleic acid, monoester of propylene glycol.
12. The composition of claim 1 further comprising at least one of a pigment, a thickener, a mildewcide, a biocide, a defoamer, a surfactant, a dispersant, a filler, and combinations thereof.
13. The composition of claim 1 wherein the latex polymer is present in an amount of 10 wt-% to 25 wt-%, based on solids.
14. The composition of claim 1 which is a paint.
15. A water-based composition, comprising:
a latex polymer, having at least one Tg within a range of −20° C. to 70° C.;
methyl-o-benzoyl benzoate in an amount of 0.1 wt-% to 5.0 wt-%, based on the weight of the polymer solids; and
one or more low VOC coalescents that elutes from a GC column at the same time or after methyl palmitate under the same conditions;
wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids.
16. The composition of claim 15 wherein the latex polymer has at least one Tg within a range of −10° C. to 30° C.
17. A water-based composition, comprising:
a latex polymer;
methyl-o-benzoyl benzoate; and
one or more low VOC coalescents selected from the group of bis(2-ethylhexyl) maleate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) azelate, isodecyl benzoate, tri(ethylene glycol)bis(2-ethylhexanoate), tetra(ethylene glycol)bis(2-ethylhexanoate), tributyl citrate, octyl benzoate, di(ethylene glycol)dibenzoate, octadecenoic acid methyl ester, and oleic acid monoester of propylene glycol;
wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids.
18. The composition of claim 17 wherein the latex polymer has at least one Tg within a range of −10° C. to 30° C.
19. The composition of claim 17 wherein the methyl-o-benzoyl benzoate is present in an amount of 0.1 wt-% to 5.0 wt-%, based on the weight of the polymer solids.
20. The composition of claim 17 which is a paint.