Renewable, biodegradable marking wax composition
The present disclosure is directed to marking compositions that are derived from environmentally friendly, biodegradable, and sustainable resources. Such compositions may be formulated in to writing and/or drawing instruments such as crayons. In various embodiments, the marking compositions include one or more of a structural component, a stiffening and/or laydown component, and a colorant. For instance, the structural component may be an ester wax composed of a diol and diacid, such as where the diols and diacids contain about 2 to about 14 carbon atoms each, such as where the structural component is present in an amount of from about 10% by weight to about 90% by weight, such as about 20% to about 80%, including about 60% of the composition. Additionally, the stiffening and/or lay down component may be a bifunctional fatty acid, such as stearic acid, which may be included in the composition, such as a stiffening agent as well as to enhance smoothness of laydown. A typically useful amount that may be used ranges from about 20% or less to about 80% or more, such as about 40% to 60% or more by weight of the composition. Further, in various embodiments, a naturally occurring, organic colorant may be provided as part of the marking composition.
1. A marking composition comprising:
a condensation polymer which is a reaction product of a diol and a dicarboxylic acid, in an amount from about 10% to about 90% by weight of the composition;
one or more fatty acids containing from 10 to 24 carbon atoms, or an ester thereof, in an amount from about 20% to about 80% by weight of the composition; and
a colorant, in an amount from about 1% to about 15% by weight of the composition,
wherein the polymer has a Shore D hardness value from 35 to 65, and
wherein the condensation polymer has a weight average molecular weight of from about 5000 to about 15,000 daltons and is selected from the group consisting of poly(butylene adipate), poly(hexylene succinate), and poly(propylene adipate).
2. The marking composition of claim 1 , wherein the polymer comprises from about 20% to about 80% by eight of the composition.
3. The marking composition of claim 1 , wherein the diol and the dicarboxylic acid each contain 2 to 14 carbon atoms.
4. The marking composition of claim 1 , wherein the polymer has a melting point from about 40 C to about 75 C.
5. The marking composition of claim 1 , wherein the composition comprises one or more fatty acids containing from 14 to 18 carbon atoms, or an ester thereof, in an amount from about 20% to about 80% by weight of the composition.
6. The marking composition of claim 1 , wherein the one or more fatty acids comprise are fully saturated fatty acids.
7. The marking composition of claim 1 , wherein the one or more fatty acids have a weight average molecular weight of from about 100 to about 400 daltons.
8. The marking composition of claim 1 , wherein the colorant is an inorganic pigment.
9. The marking composition of claim 1 , wherein the colorant is a pigment having an average particle size from about 0.1 micron to about 25 microns.
10. The marking composition of claim 1 , wherein the colorant is derived from plants or vegetables.
11. The marking composition of claim 1 , further comprising one or more additives selected from the group consisting of rust preventives, anticorrosive agents, fillers, leveling agents, viscosity modifiers, drying agent, plasticizers, foam inhibitors, mold release agents, and polymer stabilizers.
12. A writing instrument comprising a marking composition,
wherein the writing instrument is selected from the group consisting of crayons, wax pastels, grease pencils, water-soluble crayons, colored ink markers, colored charcoals, and chalks; and
wherein the marking composition comprises
a condensation polymer which is a reaction product of a diol and a dicarboxylic acid, in an amount from about 10% to about 90% by weight of the composition;
one or more fatty acids containing from 10 to 24 carbon atoms, or an ester thereof, in an amount from about 20% to about 80% by weight of the composition; and
a colorant, in an amount from about 1% to about 15% by weight of the composition;
wherein the polymer has a Shore D hardness value from 35 to 65, and
wherein the polymer has a weight average molecular weight of from about 5000 to about 15,000 daltons and is selected from the group consisting of poly(butylene adipate), poly(hexylene succinate), and poly(propylene adipate).
13. The writing instrument of claim 12 , wherein the polymer comprises from about 20% to about 80% by eight of the composition.
14. The writing instrument of claim 12 , wherein the diol and the dicarboxylic acid each contain 2 to 14 carbon atoms.
15. The writing instrument of claim 12 , wherein the polymer has a melting point from about 40 C to about 75 C.
16. The writing instrument of claim 12 , wherein the marking composition comprises one or more fatty acids containing from 14 to 18 carbon atoms, or an ester thereof, in an amount from about 20% to about 80% by weight of the composition.
17. The writing instrument of claim 12 , wherein the one or more fatty acids comprise are fully saturated fatty acids.
18. The writing instrument of claim 12 , wherein the one or more fatty acids have a weight average molecular weight of from about 100 to about 400 daltons.
19. The writing instrument claim 12 , wherein the colorant is an inorganic pigment.
20. The writing instrument of claim 12 , wherein the colorant is a pigment having an average particle size from about 0.1 micron to about 25 microns.
21. The writing instrument of claim 12 , wherein the colorant is derived from plants or vegetables.
22. The writing instrument of claim 12 , wherein the marking composition further comprises one or more additives selected from the group consisting of rust preventives, anticorrosive agents, fillers, leveling agents, viscosity modifiers, drying agent, plasticizers, foam inhibitors, mold release agents, and polymer stabilizers.
23. The writing instrument of claim 12 , wherein the writing instrument is a crayon.