Nanocellulose nucleating agents for crystallization of polylactides and other polymers
View Patent ↗The invention provides a polymer composition comprising from 50 wt % to 99.9 wt % polymer, from 0.1 wt % to 10 wt % nanocellulose as a first nucleating agent, and from 0.01 wt % to 5 wt % of a second nucleating agent. In some embodiments, the polymer is polylactide, the first nucleating agent is lignin-containing nanocellulose, and the second nucleating agent is a sulfur-containing, oxygenated aromatic molecule. The oxygenated aromatic molecule may be an aromatic sulfonic acid or salt, such as dimethyl 5-sulfoisophthalate. In other embodiments, the sulfur-containing, oxygenated aromatic molecule is lignosulfonic acid. Other variations provide a polymer composition comprising polymer, lignin-containing nanocellulose as a dispersing agent, and additives selected from nucleating agents, compatibilizers, plasticizers, fillers, antioxidants, colorants, or flame retardants. Other variations provide a polymer nucleating agent comprising lignin-containing nanocellulose and a sulfur-containing, oxygenated aromatic molecule. This may be a nucleating agent for polylactide, polycaprolactone, polyhydroxybutyrate, polyethylene, or polypropylene, for example.
1. A polylactide composition comprising from about 50 wt % to about 99.9 wt % polylactide, from about 0.1 wt % to about 0.7 wt % hydrophobic, lignin-containing nanocellulose as a first nucleating agent, and from about 0.01 wt % to about 0.1 wt % of an aromatic sulfonic acid or salt thereof as a second nucleating agent, wherein the weight ratio of said first nucleating agent to said second nucleating agent is greater than 1.
2. The polylactide composition of claim 1 , wherein said first nucleating agent is present from about 0.1 wt % to about 0.5 wt %.
3. The polylactide composition of claim 1 , wherein said second nucleating agent is present from about 0.02 wt % to about 0.05 wt %.
4. The polylactide composition of claim 1 , wherein the total concentration of said first nucleating agent and said second nucleating agent is from about 0.2 wt % to about 0.8 wt %.
5. The polylactide composition of claim 4 , wherein the total concentration of said first nucleating agent and said second nucleating agent is from about 0.3 wt % to about 0.5 wt %.
6. The polylactide composition of claim 1 , wherein the weight ratio of said first nucleating agent to said second nucleating agent is from about 20 to about 2.
7. The polylactide composition of claim 6 , wherein the weight ratio of said first nucleating agent to said second nucleating agent is about 8.
8. The polylactide composition of claim 1 , wherein said an aromatic sulfonic acid or salt thereof is selected from the group consisting of dimethyl 5-sulfoisophthalate, p-toluene sulfonate, dodecylbenzenesulfonic acid, 3-sulfobenzoic acid, phenylphosphonic acid, dimethyl 5-sulfoisophthalate, and combinations thereof.
9. The polylactide composition of claim 8 , wherein said aromatic sulfonic acid or salt thereof is dimethyl 5-sulfoisophthalate in acid or salt form.
10. The polylactide composition of claim 1 , wherein said hydrophobic, lignin-containing nanocellulose is lignin-coated nanocellulose.
11. The polylactide composition of claim 1 , wherein said hydrophobic, lignin-containing nanocellulose includes sulfonated lignin that is chemically and/or physically bonded to said hydrophobic, lignin-containing nanocellulose.
12. The polylactide composition of claim 1 , wherein said polylactide composition includes a co-polymer that is derived from co-polymerization of a non-lactide monomer with lactide.
13. The polylactide composition of claim 1 , wherein said composition further comprises one or more additives selected from the group consisting of compatibilizers, plasticizers, fillers, antioxidants, colorants, flame retardants, and combinations thereof.
14. The polylactide composition of claim 1 , wherein said composition further comprises one or more additives selected from the group consisting of glass fibers, mica, talc, metal powder, silica, calcium carbonate, carbon, wollastonite, stearates, and combinations thereof.
15. The polylactide composition of claim 1 , wherein said composition is in the form of a blend, masterbatch, pellet, extrusion feed, molding feed, extruded part, injection-molded part, blow-molded part, spun fiber, layered sheet, film, foam, container, bag, engineered part, 3D-printing substrate, 3D-printed part, or a combination thereof.
16. A polymer composition comprising from about 50 wt % to about 99.9 wt % polymer, from about 0.1 wt % to about 0.7 wt % hydrophobic, lignin-containing nanocellulose as a dispersing agent, from about 0.01 wt % to about 0.1 wt % of an aromatic sulfonic acid or salt thereof as a nucleating agent, and from about 0.01 wt % to about 20 wt % of one or more additives selected from the group consisting of additional nucleating agents, compatibilizers, plasticizers, fillers, antioxidants, colorants, flame retardants, and combinations thereof, wherein the weight ratio of said hydrophobic, lignin-containing nanocellulose to said aromatic sulfonic acid or salt thereof is 1 or greater.
17. A polymer nucleating agent comprising from about 50 wt % to about 99 wt % hydrophobic, lignin-containing nanocellulose and from about 1 wt % to about 50 wt % of an aromatic sulfonic acid or salt thereof, wherein said aromatic sulfonic acid or salt thereof is selected from the group consisting of dimethyl 5-sulfoisophthalate, p-toluene sulfonate, dodecylbenzenesulfonic acid, 3-sulfobenzoic acid, phenylphosphonic acid, dimethyl 5-sulfoisophthalate, and combinations thereof, and wherein the weight ratio of said hydrophobic, lignin-containing nanocellulose to said aromatic sulfonic acid or salt thereof is greater than 1.