Glass article and light guide
To provide a highly transmissive glass and a light guide that allow high internal transmittance of plate glass to be maintained and the internal transmittance spectrum of the plate to be flattened without lowering the redox of iron to a value equal to or more than a certain value. This glass article comprises a glass which includes 1 to 80 mass ppm of total iron oxide (t-Fe 2 O 3 ) in terms of Fe 2 O 3 , has a redox of iron of 0 to 50% and includes 0.01 to 4.0 mass ppm of NiO. The glass article and the light guide comprising the glass article are characterized in that an A value of the internal transmittance spectrum flatness is 0.83 or more.
1. A light guide comprising a plate of glass, the glass comprising:
from 1 mass ppm to 40 mass ppm of total iron oxide in terms of Fe 2 O 3 , having a redox of iron of from 0% to 50%; and
from 0.01 mass ppm to 1.0 mass ppm of NiO,
wherein
the redox of iron is a ratio of a content of Fe 2+ in terms of Fe 2 O 3 to a content of total iron in terms of Fe 2 O 3 ,
when an internal transmittance is measured for an optical length of 600 mm within the glass, a minimum of the internal transmittance of the glass within a wavelength range of from 400 to 700 nm is at least 75%, and
the content of NiO is a content in which an A value of an internal transmittance spectrum flatness of the glass defined by formula (1) is larger than an A value of a reference glass which has the same composition as the glass except that the reference glass comprises no NiO:
A =min( X,Y,Z )/max( X,Y,Z ) (1)
wherein X=Σ(S(λ)×x(λ)), Y=Σ(S(λ)×y(λ)) and Z=Σ(S(λ)×z(λ)), provided that x (λ), y (λ) and z (κ) are color matching functions in the XYZ color system described in JIS Z8701, and S (λ) is the internal transmittance.
2. The light guide according to claim 1 , wherein a matrix composition of the glass, which excludes the total iron oxide in terms of Fe 2 O 3 , NiO, CeO 2 and other trace components, a content of each of the other trace components being at most 1,000 ppm, comprises, by mass percentage on an oxide basis, substantially from 60 to 80% of SiO 2 , from 0 to 7% of Al 2 O 3 , from 0 to 10% of MgO, from 0 to 20% of CaO, from 0 to 15% of SrO, from 0 to 15% of BaO, from 3 to 20% of Na 2 O, and from 0 to 10% of K 2 O.
3. The light guide according to claim 1 , wherein a matrix composition of the glass, which excludes the total iron oxide in terms of Fe 2 O 3 , NiO, CeO 2 and other trace components, a content of each of the other trace components being at most 1,000 ppm, comprises, by mass percentage on an oxide basis, substantially from 45 to 80% of SiO 2 , more than 7% and at most 30% of Al 2 O 3 , from 0 to 15% of B 2 O 3 , from 0 to 15% of MgO, from 0 to 6% of CaO, from 0 to 5% of SrO, from 0 to 5% of BaO, from 7 to 20% of Na 2 O, from 0 to 10% of K 2 O, and from 0 to 10% of ZrO 2 .
4. The light guide according to claim 1 , wherein a matrix composition of the glass, which excludes the total iron oxide in terms of Fe 2 O 3 , NiO, CeO 2 and other trace components, a content of each of the other trace components being at most 1,000 ppm, comprises, by mass percentage on an oxide basis, substantially from 45 to 70% of SiO 2 , from 10 to 30% of Al 2 O 3 , from 0 to 15% of B 2 O 3 , from 5 to 30% in total of at least one alkaline earth metal oxide selected from the group consisting of MgO, CaO, SrO and BaO, and from 0% to less than 3% in total of at least one alkali metal oxide selected from the group consisting of Li 2 O, Na 2 O, and K 2 O.
5. The light guide according to claim 1 , wherein a content of NiO by mass ppm on an oxide basis in the glass is within a range between a lower limit of NiO and an upper limit of NiO, each defined by formulae (7) and (8):
Lower limit of NiO=−2.7−0.035 F+ 0.01 R+ 0.0025 FR (7)
Upper limit of NiO=2.4−0.055 F+ 0.01 R+ 0.002 FR (8)
wherein F (mass ppm) is the content of total iron in terms of Fe 2 O 3 , and R (%) is the redox of iron.
6. The light guide according to claim 1 , wherein the glass satisfies formula (9):
0.1≤[NiO]+2[Cr 2 O 3 ]≤5.0 (9)
wherein [NiO] (mass ppm) is a content of NiO on an oxide basis in the glass, and [Cr 2 O 3 ] (mass ppm) is a content of Cr 2 O 3 on an oxide basis in the glass.
7. The light guide according to claim 1 , wherein a content of Cr 2 O 3 in the glass is at most 5 ppm by mass ppm on an oxide basis.
8. The light guide according to claim 1 , wherein a content of Cr 2 O 3 in the glass is at most 1.0 ppm by mass ppm on an oxide basis.
9. The light guide according to claim 1 , wherein a content of MnO 2 in the glass is at most 50 ppm by mass ppm on an oxide basis.
10. The light guide according to claim 1 , wherein a content of MnO 2 in the glass is at most 10 ppm by mass ppm on an oxide basis.
11. The light guide according to claim 1 , wherein a content of CeO 2 in the glass is at most 1,000 ppm by mass ppm on an oxide basis.
12. The light guide according to claim 1 , wherein the content of NiO in the glass is from 0.01 ppm to 0.2 ppm by mass on an oxide basis.
13. The light guide according to claim 12 , wherein a content of Cr 2 O 3 in the glass is at most 1.0 ppm by mass ppm on an oxide basis.
14. The light guide according to claim 13 , wherein the content of total iron oxide in terms of Fe 2 O 3 in the glass is at most 20 ppm by mass on an oxide basis.
15. The light guide according to claim 14 , wherein a content of Cr 2 O 3 in the glass is at most 0.2 ppm by mass on an oxide basis.
16. The light guide according to claim 15 , wherein the glass comprises no CeO 2 .
17. The light guide according to claim 13 , wherein the minimum of the internal transmittance of the glass within a wavelength range of from 400 to 700 nm is at least 86%.
18. The light guide according to claim 17 , wherein the A value of the glass is at least 0.90.
19. The light guide according to claim 17 , wherein the A value of the glass is at least 0.95.
20. The light guide according to claim 1 , wherein a thickness of the plate of the glass is from 0.2 mm to 5 mm.