IP Library Granted Patent US 11,027,266
Granted Patent B2
US 11,027,266 · App. 15/805,372 · Granted Jun 8, 2021

Phosphorous acid P,P′-[5,5′,6,6′-tetramethyl-3,3′-bis(l- methylethyl)[1,1′-biphenyl]-2,2′-diyl] P,P,P′,P'-tetrakis(2,4-dimethylphenyl) ester in hydroformylation

Inventor: Robert Franke (Marl, DE)
Assignee: EVONIK OPERATIONS GMBH
B01J31/0259B01J31/28C07C45/505C07C45/62C07F9/145C07F15/0006C07F15/0073
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Quick Facts
Patent No.
US 11,027,266
App. No.
15/805,372
Granted
Jun 8, 2021
Kind
B2
Abstract

The compound of the formula (1) and its complexes with metal cations are used for catalysis in hydroformylation processes.

Claims (16)

1. A symmetric bidentate metal ligand complex mixture comprising a compound represented by formula (2):

and a metal atom selected from the group consisting of Rh, Ru, Co and Ir, wherein the symmetric bidentate metal ligand complex mixture has a chlorine value according to Wickhold below 10,000 ppm.

2. The bidentate metal ligand complex mixture according to claim 1 , wherein M is Rh.

3. A process for converting an olefin to an aldehyde comprising the process steps of:

a1) initially charging an olefin having 2 to 24 carbon atoms,

b1) adding

the symmetric bidentate metal ligand complex mixture according to claim 1 ,

c1) feeding in H 2 and CO,

d1) heating the reaction mixture, with conversion of the olefin to an aldehyde.

4. The process according to claim 3 , characterized in that the metal atom is Rh.

5. The process according to claim 3 , wherein the olefin having 2 to 24 carbon atoms is selected from ethene, propene butene, 1-butene or 2-butene.

6. The process according to claim 3 , characterized in that, in step a1), wherein the olefin having 2 to 24 carbon atoms is selected from 1-butene or 2-butene.

7. A catalytic hydroformylation process comprising contacting an olefin with

the symmetric bidentate metal ligand complex mixture according to claim 1 .

8. The process according to claim 7 , wherein the hydroformylation process converts the olefin to substituted or unsubstituted aldehydes having 3 to 20 carbon atoms, including substituted or unsubstituted propenals, butanals, pentanals, nonanals, tridecanals, substituted or unsubstituted propenals, butanals or pentanals.

9. The process according to claim 7 , wherein the substituted or unsubstituted aldehydes having 3 to 20 carbon atoms include substituted or unsubstituted propenals, butanals or pentanals.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2024
From: EVONIK OPERATIONS GMBH
To: EVONIK OXENO GMBH & CO. KG
Reel/Frame 066242/0585 →
CHANGE OF NAME Recorded Mar 29, 2020
From: EVONIK DEGUSSA GMBH
To: EVONIK OPERATIONS GMBH
Reel/Frame 052254/0052 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 31, 2018
From: FRANKE, ROBERT
To: EVONIK DEGUSSA GMBH
Reel/Frame 045951/0415 →
Priority Claims (1)
EP 16197717 · Nov 8, 2016 · regional
Continuity (1)
Related Publication 20180126366A1 · May 10, 2018