Phosphorous acid P,P′-[5,5′,6,6′-tetramethyl-3,3′-bis(l- methylethyl)[1,1′-biphenyl]-2,2′-diyl] P,P,P′,P'-tetrakis(2,4-dimethylphenyl) ester in hydroformylation
The compound of the formula (1) and its complexes with metal cations are used for catalysis in hydroformylation processes.
1. A symmetric bidentate metal ligand complex mixture comprising a compound represented by formula (2):
and a metal atom selected from the group consisting of Rh, Ru, Co and Ir, wherein the symmetric bidentate metal ligand complex mixture has a chlorine value according to Wickhold below 10,000 ppm.
2. The bidentate metal ligand complex mixture according to claim 1 , wherein M is Rh.
3. A process for converting an olefin to an aldehyde comprising the process steps of:
a1) initially charging an olefin having 2 to 24 carbon atoms,
b1) adding
the symmetric bidentate metal ligand complex mixture according to claim 1 ,
c1) feeding in H 2 and CO,
d1) heating the reaction mixture, with conversion of the olefin to an aldehyde.
4. The process according to claim 3 , characterized in that the metal atom is Rh.
5. The process according to claim 3 , wherein the olefin having 2 to 24 carbon atoms is selected from ethene, propene butene, 1-butene or 2-butene.
6. The process according to claim 3 , characterized in that, in step a1), wherein the olefin having 2 to 24 carbon atoms is selected from 1-butene or 2-butene.
7. A catalytic hydroformylation process comprising contacting an olefin with
the symmetric bidentate metal ligand complex mixture according to claim 1 .
8. The process according to claim 7 , wherein the hydroformylation process converts the olefin to substituted or unsubstituted aldehydes having 3 to 20 carbon atoms, including substituted or unsubstituted propenals, butanals, pentanals, nonanals, tridecanals, substituted or unsubstituted propenals, butanals or pentanals.
9. The process according to claim 7 , wherein the substituted or unsubstituted aldehydes having 3 to 20 carbon atoms include substituted or unsubstituted propenals, butanals or pentanals.